Open‐Structured V 2 O 5 · n H 2 O Nanoflakes as Highly Reversible Cathode Material for Monovalent and Multivalent Intercalation Batteries
Abstract
The high‐capacity cathode material V 2 O 5 · n H 2 O has attracted considerable attention for metal ion batteries due to the multielectron redox reaction during electrochemical processes. It has an expanded layer structure, which can host large ions or multivalent ions. However, structural instability and poor electronic and ionic conductivities greatly handicap its application. Here, in cell tests, self‐assembly V 2 O 5 · n H 2 O nanoflakes shows excellent electrochemical performance with either monovalent or multivalent cation intercalation. They are directly grown on a 3D conductive stainless steel mesh substrate via a simple and green hydrothermal method. Well‐layered nanoflakes are obtained after heat treatment at 300 °C (V 2 O 5 ·0.3H 2 O). Nanoflakes with ultrathin flower petals deliver a stable capacity of 250 mA h g −1 in a Li‐ion cell, 110 mA h g −1 in a Na‐ion cell, and 80 mA h g −1 in an Al‐ion cell in their respective potential ranges (2.0–4.0 V for Li and Na‐ion batteries and 0.1–2.5 V for Al‐ion battery) after 100 cycles.
- Authors:
-
- Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and Engineering Beijing Institute of Technology Beijing 100081 China
- Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA, Department of Chemistry and Biochemistry Ohio State University 100 West 18th Avenue Columbus OH 43210 USA
- Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and Engineering Beijing Institute of Technology Beijing 100081 China, Collaborative Innovation Center of Electric Vehicles in Beijing Beijing 100081 China
- Chemical Sciences and Engineering Division Argonne National Laboratory 9700 South Cass Avenue Lemont IL 60439 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401540
- Grant/Contract Number:
- DE‐AC02‐06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Name: Advanced Energy Materials Journal Volume: 7 Journal Issue: 14; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Wang, Huali, Bi, Xuanxuan, Bai, Ying, Wu, Chuan, Gu, Sichen, Chen, Shi, Wu, Feng, Amine, Khalil, and Lu, Jun. Open‐Structured V 2 O 5 · n H 2 O Nanoflakes as Highly Reversible Cathode Material for Monovalent and Multivalent Intercalation Batteries. Germany: N. p., 2017.
Web. doi:10.1002/aenm.201602720.
Wang, Huali, Bi, Xuanxuan, Bai, Ying, Wu, Chuan, Gu, Sichen, Chen, Shi, Wu, Feng, Amine, Khalil, & Lu, Jun. Open‐Structured V 2 O 5 · n H 2 O Nanoflakes as Highly Reversible Cathode Material for Monovalent and Multivalent Intercalation Batteries. Germany. https://doi.org/10.1002/aenm.201602720
Wang, Huali, Bi, Xuanxuan, Bai, Ying, Wu, Chuan, Gu, Sichen, Chen, Shi, Wu, Feng, Amine, Khalil, and Lu, Jun. Fri .
"Open‐Structured V 2 O 5 · n H 2 O Nanoflakes as Highly Reversible Cathode Material for Monovalent and Multivalent Intercalation Batteries". Germany. https://doi.org/10.1002/aenm.201602720.
@article{osti_1401540,
title = {Open‐Structured V 2 O 5 · n H 2 O Nanoflakes as Highly Reversible Cathode Material for Monovalent and Multivalent Intercalation Batteries},
author = {Wang, Huali and Bi, Xuanxuan and Bai, Ying and Wu, Chuan and Gu, Sichen and Chen, Shi and Wu, Feng and Amine, Khalil and Lu, Jun},
abstractNote = {The high‐capacity cathode material V 2 O 5 · n H 2 O has attracted considerable attention for metal ion batteries due to the multielectron redox reaction during electrochemical processes. It has an expanded layer structure, which can host large ions or multivalent ions. However, structural instability and poor electronic and ionic conductivities greatly handicap its application. Here, in cell tests, self‐assembly V 2 O 5 · n H 2 O nanoflakes shows excellent electrochemical performance with either monovalent or multivalent cation intercalation. They are directly grown on a 3D conductive stainless steel mesh substrate via a simple and green hydrothermal method. Well‐layered nanoflakes are obtained after heat treatment at 300 °C (V 2 O 5 ·0.3H 2 O). Nanoflakes with ultrathin flower petals deliver a stable capacity of 250 mA h g −1 in a Li‐ion cell, 110 mA h g −1 in a Na‐ion cell, and 80 mA h g −1 in an Al‐ion cell in their respective potential ranges (2.0–4.0 V for Li and Na‐ion batteries and 0.1–2.5 V for Al‐ion battery) after 100 cycles.},
doi = {10.1002/aenm.201602720},
journal = {Advanced Energy Materials},
number = 14,
volume = 7,
place = {Germany},
year = {Fri Apr 21 00:00:00 EDT 2017},
month = {Fri Apr 21 00:00:00 EDT 2017}
}
https://doi.org/10.1002/aenm.201602720
Web of Science
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