skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: SnS{sub 2} nanoflakes decorated multiwalled carbon nanotubes as high performance anode materials for lithium-ion batteries

Journal Article · · Materials Research Bulletin
 [1];  [2];  [1]; ;  [3];  [1]
  1. Beijing National Center for Electron Microscopy, The State Key Laboratory of New Ceramics and Fine Processing, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China)
  2. Nanomaterials Research Group (NRG), Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan)
  3. Laboratory of Advanced Materials, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China)

Graphical abstract: The synthesized SnS{sub 2} nanoflakes decorated multiwalled carbon nanotubes hybrid structures exhibit large reversible capacity, superior cycling performance, and good rate capability as compared to pure SnS{sub 2} nanoflakes. - Highlights: • Synthesis of SnS{sub 2} nanoflakes decorated multiwalled carbon nanotubes hybrid structures. • Simple solution-phase approach. • Morphology feature of SnS{sub 2}. • Enhanced performance as Li-ion batteries. - Abstract: SnS{sub 2} nanoflakes decorated multiwalled carbon nanotubes (MWCNTs) hybrid structures are directly synthesized via a simple solution-phase approach. The as-prepared SnS{sub 2}/MWCNTs structures are investigated as anode materials for Li-ion batteries as compared with SnS{sub 2} nanoflakes. It has been found that the composite structure exhibit excellent lithium storage performance with a large reversible capacity, superior cycling performance, and good rate capability as compared to pure SnS{sub 2} nanoflakes. The first discharge and charge capacities have been found to be 1416 and 518 mA h g{sup −1} for SnS{sub 2}/MWCNTs composite electrodes at a current density of 100 mA g{sup −1} between 5 mV and 1.15 V versus Li/Li{sup +}. A stable reversible capacity of ∼510 mA h g{sup −1} is obtained for 50 cycles. The improved electrochemical performance may be attributed to the flake-morphology feature of SnS{sub 2} and the addition of MWCNTs that can hinder the agglomeration of the active materials and improve the conductivity of the composite electrode simultaneously.

OSTI ID:
22341841
Journal Information:
Materials Research Bulletin, Vol. 49; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English