Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes
Abstract
Herein we report early results on efforts to optimize the electrochemical performance of a cathode composed of a lithium- and manganese-rich “layered-layered-spinel” material for lithium-ion battery applications. Pre-pilot scale synthesis leads to improved particle properties compared with lab-scale efforts, resulting in high capacities (≳200 mAh/g) and good energy densities (>700 Wh/kg) in tests with lithium-ion cells. Subsequent surface modifications give further improvements in rate capabilities and high-voltage stability. These results bode well for advances in the performance of this class of lithium- and manganese-rich cathode materials.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States). Electrochemical Energy Storage Dept.
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Engineering Research Facility
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1392305
- Alternate Identifier(s):
- OSTI ID: 1397467
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 334; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; battery; cathode; composite; lithium rich; lithium-ion; manganese rich; scale up
Citation Formats
Croy, Jason R., Park, Joong Sun, Shin, Youngho, Yonemoto, Bryan T., Balasubramanian, Mahalingam, Long, Brandon R., Ren, Yang, and Thackeray, Michael M. Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes. United States: N. p., 2016.
Web. doi:10.1016/j.jpowsour.2016.10.015.
Croy, Jason R., Park, Joong Sun, Shin, Youngho, Yonemoto, Bryan T., Balasubramanian, Mahalingam, Long, Brandon R., Ren, Yang, & Thackeray, Michael M. Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes. United States. https://doi.org/10.1016/j.jpowsour.2016.10.015
Croy, Jason R., Park, Joong Sun, Shin, Youngho, Yonemoto, Bryan T., Balasubramanian, Mahalingam, Long, Brandon R., Ren, Yang, and Thackeray, Michael M. Thu .
"Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes". United States. https://doi.org/10.1016/j.jpowsour.2016.10.015. https://www.osti.gov/servlets/purl/1392305.
@article{osti_1392305,
title = {Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes},
author = {Croy, Jason R. and Park, Joong Sun and Shin, Youngho and Yonemoto, Bryan T. and Balasubramanian, Mahalingam and Long, Brandon R. and Ren, Yang and Thackeray, Michael M.},
abstractNote = {Herein we report early results on efforts to optimize the electrochemical performance of a cathode composed of a lithium- and manganese-rich “layered-layered-spinel” material for lithium-ion battery applications. Pre-pilot scale synthesis leads to improved particle properties compared with lab-scale efforts, resulting in high capacities (≳200 mAh/g) and good energy densities (>700 Wh/kg) in tests with lithium-ion cells. Subsequent surface modifications give further improvements in rate capabilities and high-voltage stability. These results bode well for advances in the performance of this class of lithium- and manganese-rich cathode materials.},
doi = {10.1016/j.jpowsour.2016.10.015},
journal = {Journal of Power Sources},
number = C,
volume = 334,
place = {United States},
year = {Thu Oct 13 00:00:00 EDT 2016},
month = {Thu Oct 13 00:00:00 EDT 2016}
}
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