Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes
Abstract
Herein we report early results on efforts to optimize the electrochemical performance of a cathode composed of a lithium- and manganese-rich “layered-layered-spinel” material for lithium-ion battery applications. Pre-pilot scale synthesis leads to improved particle properties compared with lab-scale efforts, resulting in high capacities (≳200 mAh/g) and good energy densities (>700 Wh/kg) in tests with lithium-ion cells. Subsequent surface modifications give further improvements in rate capabilities and high-voltage stability. These results bode well for advances in the performance of this class of lithium- and manganese-rich cathode materials.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States). Electrochemical Energy Storage Dept.
- Argonne National Lab. (ANL), Argonne, IL (United States). Materials Engineering Research Facility
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1392305
- Alternate Identifier(s):
- OSTI ID: 1397467
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 334; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; battery; cathode; composite; lithium rich; lithium-ion; manganese rich; scale up
Citation Formats
Croy, Jason R., Park, Joong Sun, Shin, Youngho, Yonemoto, Bryan T., Balasubramanian, Mahalingam, Long, Brandon R., Ren, Yang, and Thackeray, Michael M. Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes. United States: N. p., 2016.
Web. doi:10.1016/j.jpowsour.2016.10.015.
Croy, Jason R., Park, Joong Sun, Shin, Youngho, Yonemoto, Bryan T., Balasubramanian, Mahalingam, Long, Brandon R., Ren, Yang, & Thackeray, Michael M. Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes. United States. https://doi.org/10.1016/j.jpowsour.2016.10.015
Croy, Jason R., Park, Joong Sun, Shin, Youngho, Yonemoto, Bryan T., Balasubramanian, Mahalingam, Long, Brandon R., Ren, Yang, and Thackeray, Michael M. Thu .
"Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes". United States. https://doi.org/10.1016/j.jpowsour.2016.10.015. https://www.osti.gov/servlets/purl/1392305.
@article{osti_1392305,
title = {Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes},
author = {Croy, Jason R. and Park, Joong Sun and Shin, Youngho and Yonemoto, Bryan T. and Balasubramanian, Mahalingam and Long, Brandon R. and Ren, Yang and Thackeray, Michael M.},
abstractNote = {Herein we report early results on efforts to optimize the electrochemical performance of a cathode composed of a lithium- and manganese-rich “layered-layered-spinel” material for lithium-ion battery applications. Pre-pilot scale synthesis leads to improved particle properties compared with lab-scale efforts, resulting in high capacities (≳200 mAh/g) and good energy densities (>700 Wh/kg) in tests with lithium-ion cells. Subsequent surface modifications give further improvements in rate capabilities and high-voltage stability. These results bode well for advances in the performance of this class of lithium- and manganese-rich cathode materials.},
doi = {10.1016/j.jpowsour.2016.10.015},
journal = {Journal of Power Sources},
number = C,
volume = 334,
place = {United States},
year = {Thu Oct 13 00:00:00 EDT 2016},
month = {Thu Oct 13 00:00:00 EDT 2016}
}
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Works referenced in this record:
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005
- Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
- Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007
- Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
- Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012
- Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D.
- Energy & Environmental Science, Vol. 5, Issue 7
High-Energy Cathode Materials (Li 2 MnO 3 –LiMO 2 ) for Lithium-Ion Batteries
journal, March 2013
- Yu, Haijun; Zhou, Haoshen
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 8
Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2
journal, June 2006
- Armstrong, A. Robert; Holzapfel, Michael; Novák, Petr
- Journal of the American Chemical Society, Vol. 128, Issue 26
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
journal, January 2014
- Lee, J.; Urban, A.; Li, X.
- Science, Vol. 343, Issue 6170
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016
- Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander
- Nature Chemistry, Vol. 8, Issue 7
Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries
journal, January 2016
- Hy, Sunny; Liu, Haodong; Zhang, Minghao
- Energy & Environmental Science, Vol. 9, Issue 6
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen
journal, March 2016
- Luo, Kun; Roberts, Matthew R.; Hao, Rong
- Nature Chemistry, Vol. 8, Issue 7
Review of the U.S. Department of Energy’s “Deep Dive” Effort to Understand Voltage Fade in Li- and Mn-Rich Cathodes
journal, October 2015
- Croy, Jason R.; Balasubramanian, Mahalingam; Gallagher, Kevin G.
- Accounts of Chemical Research, Vol. 48, Issue 11
First-charge instabilities of layered-layered lithium-ion-battery materials
journal, January 2015
- Croy, Jason R.; Iddir, Hakim; Gallagher, Kevin
- Physical Chemistry Chemical Physics, Vol. 17, Issue 37
Solid State NMR Studies of Li 2 MnO 3 and Li-Rich Cathode Materials: Proton Insertion, Local Structure, and Voltage Fade
journal, November 2014
- Dogan, Fulya; Croy, Jason R.; Balasubramanian, Mahalingam
- Journal of The Electrochemical Society, Vol. 162, Issue 1
Neutron Diffraction and Magnetic Susceptibility Studies on a High-Voltage Li 1.2 Mn 0.55 Ni 0.15 Co 0.10 O 2 Lithium Ion Battery Cathode: Insight into the Crystal Structure
journal, September 2013
- Mohanty, Debasish; Huq, Ashfia; Payzant, E. Andrew
- Chemistry of Materials, Vol. 25, Issue 20
Investigating phase transformation in the Li1.2Co0.1Mn0.55Ni0.15O2 lithium-ion battery cathode during high-voltage hold (4.5 V) via magnetic, X-ray diffraction and electron microscopy studies
journal, January 2013
- Mohanty, Debasish; Sefat, Athena S.; Kalnaus, Sergiy
- Journal of Materials Chemistry A, Vol. 1, Issue 20
Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study
journal, January 2013
- Mohanty, Debasish; Sefat, Athena S.; Li, Jianlin
- Physical Chemistry Chemical Physics, Vol. 15, Issue 44
Unraveling the Voltage-Fade Mechanism in High-Energy-Density Lithium-Ion Batteries: Origin of the Tetrahedral Cations for Spinel Conversion
journal, October 2014
- Mohanty, Debasish; Li, Jianlin; Abraham, Daniel P.
- Chemistry of Materials, Vol. 26, Issue 21
Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013
- Bettge, Martin; Li, Yan; Gallagher, Kevin
- Journal of The Electrochemical Society, Vol. 160, Issue 11
Countering the Voltage Decay in High Capacity xLi 2 MnO 3 •(1–x)LiMO 2 Electrodes (M=Mn, Ni, Co) for Li + -Ion Batteries
journal, January 2012
- Croy, Jason R.; Kim, Donghan; Balasubramanian, Mahalingam
- Journal of The Electrochemical Society, Vol. 159, Issue 6
High-capacity lithium insertion materials of lithium nickel manganese oxides for advanced lithium-ion batteries: toward rechargeable capacity more than 300 mA h g−1
journal, January 2011
- Ohzuku, Tsutomu; Nagayama, Masatoshi; Tsuji, Kyoji
- Journal of Materials Chemistry, Vol. 21, Issue 27
Effect of interface modifications on voltage fade in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathode materials
journal, March 2014
- Bloom, Ira; Trahey, Lynn; Abouimrane, Ali
- Journal of Power Sources, Vol. 249
Aluminum and Gallium Substitution into 0.5Li 2 MnO 3 ·0.5Li(Ni 0.375 Mn 0.375 Co 0.25 )O 2 Layered Composite and the Voltage Fade Effect
journal, December 2014
- Lee, Eungje; Koritala, Rachel; Miller, Dean J.
- Journal of The Electrochemical Society, Vol. 162, Issue 3
Re-entrant Lithium Local Environments and Defect Driven Electrochemistry of Li- and Mn-Rich Li-Ion Battery Cathodes
journal, February 2015
- Dogan, Fulya; Long, Brandon R.; Croy, Jason R.
- Journal of the American Chemical Society, Vol. 137, Issue 6
Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014
- Long, Brandon R.; Croy, Jason R.; Park, Joong Sun
- Journal of The Electrochemical Society, Vol. 161, Issue 14, p. A2160-A2167
Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries
journal, November 2012
- Kim, Donghan; Sandi, Giselle; Croy, Jason R.
- Journal of The Electrochemical Society, Vol. 160, Issue 1, p. A31-A38
Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007
- Park, S.; Kang, S.; Johnson, C.
- Electrochemistry Communications, Vol. 9, Issue 2, p. 262-268
Manganese oxides for lithium batteries
journal, January 1997
- Thackeray, Michael M.
- Progress in Solid State Chemistry, Vol. 25, Issue 1-2
Lithium-cobalt-nickel-oxide cathode materials prepared at 400°C for rechargeable lithium batteries
journal, July 1992
- Gummow, R. J.; Thackeray, M. M.
- Solid State Ionics, Vol. 53-56, p. 681-687
Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C
journal, March 1992
- Gummow, R. J.; Thackeray, M. M.; David, W. I. F.
- Materials Research Bulletin, Vol. 27, Issue 3, p. 327-337
Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C
journal, March 1993
- Gummow, R. J.; Liles, D. C.; Thackeray, M. M.
- Materials Research Bulletin, Vol. 28, Issue 3, p. 235-246
Lithium–manganese oxide electrodes with layered–spinel composite structures xLi2MnO3·(1−x)Li1+yMn2−yO4 (0<x<1, 0⩽y⩽0.33) for lithium batteries
journal, May 2005
- Johnson, C. S.; Li, N.; Vaughey, J. T.
- Electrochemistry Communications, Vol. 7, Issue 5, p. 528-536
Li2MnO3-based composite cathodes for lithium batteries: A novel synthesis approach and new structures
journal, October 2011
- Croy, J. R.; Kang, S.-H.; Balasubramanian, M.
- Electrochemistry Communications, Vol. 13, Issue 10, p. 1063-1066
Quantifying Hysteresis and Voltage Fade in xLi 2 MnO 3 ● (1-x)LiMn 0.5 Ni 0.5 O 2 Electrodes as a Function of Li 2 MnO 3 Content
journal, December 2013
- Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam
- Journal of The Electrochemical Society, Vol. 161, Issue 3
Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009
- Kang, Sun-Ho; Thackeray, Michael M.
- Electrochemistry Communications, Vol. 11, Issue 4, p. 748-751
Structural and Electrochemical Study of Al 2 O 3 and TiO 2 Coated Li 1.2 Ni 0.13 Mn 0.54 Co 0.13 O 2 Cathode Material Using ALD
journal, June 2013
- Zhang, Xiaofeng; Belharouak, Ilias; Li, Li
- Advanced Energy Materials, Vol. 3, Issue 10
Effect of lithium content on spinel phase evolution in the composite material LixNi0.25Co0.10Mn0.65O(3.4+x)/2 (0.8≤x≤1.6) for Li-ion batteries
journal, October 2016
- Choi, Byungjin; Song, Jayhyok; Yeon, Donghee
- Solid State Ionics, Vol. 293
Amorphous Metal Fluoride Passivation Coatings Prepared by Atomic Layer Deposition on LiCoO 2 for Li-Ion Batteries
journal, March 2015
- Park, Joong Sun; Mane, Anil U.; Elam, Jeffrey W.
- Chemistry of Materials, Vol. 27, Issue 6
First-Principles Calculations, Electrochemical and X-ray Absorption Studies of Li-Ni-PO 4 Surface-Treated x Li 2 MnO 3 ·(1− x )LiMO 2 (M = Mn, Ni, Co) Electrodes for Li-Ion Batteries
journal, January 2011
- Shin, D.; Wolverton, C.; Croy, J. R.
- Journal of The Electrochemical Society, Vol. 159, Issue 2
Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy
journal, December 2011
- Croy, Jason R.; Balasubramanian, Mahalingam; Kim, Donghan
- Chemistry of Materials, Vol. 23, Issue 24, p. 5415-5424
Works referencing / citing this record:
Improvement of the electrochemical performance of a nickel rich LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode material by reduced graphene oxide/SiO 2 nanoparticle double-layer coating
journal, January 2019
- Razmjoo Khollari, Mohammad Amin; Paknahad, Pouyan; Ghorbanzadeh, Milad
- New Journal of Chemistry, Vol. 43, Issue 6
Separator modified by Y2O3 nanoparticles-Ketjen Black hybrid and its application in lithium-sulfur battery
journal, June 2017
- Wang, Shanwen; Qian, Xinye; Jin, Lina
- Journal of Solid State Electrochemistry, Vol. 21, Issue 11
Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries
journal, June 2017
- Li, Jianlin; Du, Zhijia; Ruther, Rose E.
- JOM, Vol. 69, Issue 9