DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites

Abstract

High precision Sm-Nd isotopic analyses have been completed on a suite of 11 martian basaltic meteorites in order to better constrain the age of silicate differentiation on Mars associated with the formation of their mantle sources. Our data is used to evaluate the merits and disadvantages of various mathematical approaches that have been employed in previous work on this topic. Ages determined from the Sm-Nd isotopic systematics of individual samples are strongly dependent on the assumed Nd isotopic composition of the bulk planet. This assumption is problematic given differences observed between the Nd isotopic composition of Earth and chondritic meteorites and the fact that these materials are both commonly used to represent bulk planetary Nd isotopic compositions. Ages determined from the slope of Sm-146-Nd-142 whole rock isochrons are not dependent on the assumed Nd-142/Nd-144 ratio of the planet, but require the sample suite to be derived from complementary, contemporaneously-formed reservoirs. In this work, we present a mathematical expression that defines the age of formation of the source regions of such a suite of samples that is based solely on the slope of a Nd-143-Nd-142 whole rock isochron and is also independent of any a priori assumptions regarding the bulk isotopicmore » composition of the planet. This expression is also applicable to mineral isochrons and has been used to successfully calculate Nd-143-Nd-142 model crystallization ages of early refractory solids as well as lunar samples. This permits ages to be obtained using only Nd isotopic measurements without the need for Sm-147/Nd-144 isotope dilution determinations. When used in conjunction with high-precision Nd isotopic measurements completed on martian meteorites this expression yields an age of formation of the martian basaltic meteorite source regions of 4504 +/- 6 Ma. Because the Sm-Nd model ages for the formation of martian source regions are commonly interpreted to record the age at which large scale mantle reservoirs formed during planetary differentiation associated with magma ocean solidification, the age determined here implies that magma ocean solidification occurred several tens of millions of years after the beginning of the Solar System. Recent thermal models, however, suggest that Mars-sized bodies cool rapidly in less than similar to 5 Ma after accretion ceases, even in the presence of a thick atmosphere. In assuming these models are correct, an extended period of accretion is necessary to provide a mechanism to keep portions of the martian mantle partially molten until 4504 Ma. Late accretional heating of Mars could either be associated with protracted accretion occurring at a quasi-steady state or alternatively be associated with a late giant impact. If this scenario is correct, then accretion of Mars-sized bodies takes up to 60 Ma and is likely to be contemporaneous with the core formation and possibly the onset of silicate differentiation. This further challenges the concept that isotopic equilibrium is attained during primordial evolution of planets, and may help to account for geochemical evidence implying addition of material into planetary interiors after core formation was completed.« less

Authors:
ORCiD logo [1];  [2];  [3]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Chemical Sciences Division
  2. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Chemical Sciences Division; Univ. of Munster (Germany). Inst. of Planetology
  3. Univ. of Tennessee, Chattanooga, TN (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE; National Aeronautics and Space Administration (NASA)
OSTI Identifier:
1395530
Alternate Identifier(s):
OSTI ID: 1397582
Report Number(s):
LLNL-JRNL-700773
Journal ID: ISSN 0016-7037; PII: S0016703715006948
Grant/Contract Number:  
AC52-07NA27344; NNH12AT84I
Resource Type:
Accepted Manuscript
Journal Name:
Geochimica et Cosmochimica Acta
Additional Journal Information:
Journal Volume: 175; Journal Issue: C; Journal ID: ISSN 0016-7037
Publisher:
The Geochemical Society; The Meteoritical Society
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; 79 ASTRONOMY AND ASTROPHYSICS; SM-146 HALF-LIFE; MAGMA OCEAN; CORE FORMATION; RB-SR; DIFFERENTIATION HISTORY; SOLAR-SYSTEM; FRACTIONAL CRYSTALLIZATION; MANTLE DIFFERENTIATION; HEMISPHERIC DICHOTOMY; SNC METEORITES

Citation Formats

Borg, Lars E., Brennecka, Gregory A., and Symes, Steven J. K. Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites. United States: N. p., 2015. Web. doi:10.1016/j.gca.2015.12.002.
Borg, Lars E., Brennecka, Gregory A., & Symes, Steven J. K. Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites. United States. https://doi.org/10.1016/j.gca.2015.12.002
Borg, Lars E., Brennecka, Gregory A., and Symes, Steven J. K. Sat . "Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites". United States. https://doi.org/10.1016/j.gca.2015.12.002. https://www.osti.gov/servlets/purl/1395530.
@article{osti_1395530,
title = {Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites},
author = {Borg, Lars E. and Brennecka, Gregory A. and Symes, Steven J. K.},
abstractNote = {High precision Sm-Nd isotopic analyses have been completed on a suite of 11 martian basaltic meteorites in order to better constrain the age of silicate differentiation on Mars associated with the formation of their mantle sources. Our data is used to evaluate the merits and disadvantages of various mathematical approaches that have been employed in previous work on this topic. Ages determined from the Sm-Nd isotopic systematics of individual samples are strongly dependent on the assumed Nd isotopic composition of the bulk planet. This assumption is problematic given differences observed between the Nd isotopic composition of Earth and chondritic meteorites and the fact that these materials are both commonly used to represent bulk planetary Nd isotopic compositions. Ages determined from the slope of Sm-146-Nd-142 whole rock isochrons are not dependent on the assumed Nd-142/Nd-144 ratio of the planet, but require the sample suite to be derived from complementary, contemporaneously-formed reservoirs. In this work, we present a mathematical expression that defines the age of formation of the source regions of such a suite of samples that is based solely on the slope of a Nd-143-Nd-142 whole rock isochron and is also independent of any a priori assumptions regarding the bulk isotopic composition of the planet. This expression is also applicable to mineral isochrons and has been used to successfully calculate Nd-143-Nd-142 model crystallization ages of early refractory solids as well as lunar samples. This permits ages to be obtained using only Nd isotopic measurements without the need for Sm-147/Nd-144 isotope dilution determinations. When used in conjunction with high-precision Nd isotopic measurements completed on martian meteorites this expression yields an age of formation of the martian basaltic meteorite source regions of 4504 +/- 6 Ma. Because the Sm-Nd model ages for the formation of martian source regions are commonly interpreted to record the age at which large scale mantle reservoirs formed during planetary differentiation associated with magma ocean solidification, the age determined here implies that magma ocean solidification occurred several tens of millions of years after the beginning of the Solar System. Recent thermal models, however, suggest that Mars-sized bodies cool rapidly in less than similar to 5 Ma after accretion ceases, even in the presence of a thick atmosphere. In assuming these models are correct, an extended period of accretion is necessary to provide a mechanism to keep portions of the martian mantle partially molten until 4504 Ma. Late accretional heating of Mars could either be associated with protracted accretion occurring at a quasi-steady state or alternatively be associated with a late giant impact. If this scenario is correct, then accretion of Mars-sized bodies takes up to 60 Ma and is likely to be contemporaneous with the core formation and possibly the onset of silicate differentiation. This further challenges the concept that isotopic equilibrium is attained during primordial evolution of planets, and may help to account for geochemical evidence implying addition of material into planetary interiors after core formation was completed.},
doi = {10.1016/j.gca.2015.12.002},
journal = {Geochimica et Cosmochimica Acta},
number = C,
volume = 175,
place = {United States},
year = {Sat Dec 12 00:00:00 EST 2015},
month = {Sat Dec 12 00:00:00 EST 2015}
}

Journal Article:

Citation Metrics:
Cited by: 58 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Initial strontium isotopic abundances and the resolution of small time differences in the formation of planetary objects
journal, January 1968


Planetary accretion in the inner Solar System
journal, July 2004


Coupled 142Nd–143Nd evidence for a protracted magma ocean in Mars
journal, November 2007

  • Debaille, V.; Brandon, A. D.; Yin, Q. Z.
  • Nature, Vol. 450, Issue 7169
  • DOI: 10.1038/nature06317

Magma ocean fractional crystallization and cumulate overturn in terrestrial planets: Implications for Mars
journal, December 2003


The martian hemispheric dichotomy may be due to a giant impact
journal, May 1984

  • Wilhelms, Don E.; Squyres, Steven W.
  • Nature, Vol. 309, Issue 5964
  • DOI: 10.1038/309138a0

A petrogenetic model for the origin and compositional variation of the martian basaltic meteorites
journal, December 2003


Early martian mantle overturn inferred from isotopic composition of nakhlite meteorites
journal, July 2009

  • Debaille, V.; Brandon, A. D.; O’Neill, C.
  • Nature Geoscience, Vol. 2, Issue 8
  • DOI: 10.1038/ngeo579

A highly depleted moon or a non-magma ocean origin for the lunar crust?
journal, October 2007


Thermo-mechanical adjustment after impacts during planetary growth
journal, January 2007

  • Monteux, Julien; Coltice, Nicolas; Dubuffet, Fabien
  • Geophysical Research Letters, Vol. 34, Issue 24
  • DOI: 10.1029/2007GL031635

Core formation in planetesimals triggered by permeable flow
journal, March 2003

  • Yoshino, Takashi; Walter, Michael J.; Katsura, Tomoo
  • Nature, Vol. 422, Issue 6928
  • DOI: 10.1038/nature01459

Super-chondritic Sm/Nd ratios in Mars, the Earth and the Moon
journal, March 2008

  • Caro, Guillaume; Bourdon, Bernard; Halliday, Alex N.
  • Nature, Vol. 452, Issue 7185
  • DOI: 10.1038/nature06760

The Borealis basin and the origin of the martian crustal dichotomy
journal, June 2008

  • Andrews-Hanna, Jeffrey C.; Zuber, Maria T.; Banerdt, W. Bruce
  • Nature, Vol. 453, Issue 7199
  • DOI: 10.1038/nature07011

146Sm-142Nd systematics measured in enstatite chondrites reveals a heterogeneous distribution of 142Nd in the solar nebula
journal, April 2011

  • Gannoun, A.; Boyet, M.; Rizo, H.
  • Proceedings of the National Academy of Sciences, Vol. 108, Issue 19
  • DOI: 10.1073/pnas.1017332108

Oxygen fugacity and geochemical variations in the martian basalts: implications for martian basalt petrogenesis and the oxidation state of the upper mantle of Mars
journal, June 2002


U–Pb chronology of the Solar System's oldest solids with variable 238U/235U
journal, December 2010

  • Amelin, Yuri; Kaltenbach, Angela; Iizuka, Tsuyoshi
  • Earth and Planetary Science Letters, Vol. 300, Issue 3-4
  • DOI: 10.1016/j.epsl.2010.10.015

Rapid accretion and early differentiation of Mars indicated by 142Nd/144Nd in SNC meteorites
journal, January 1995


Chronology and petrogenesis of young achondrites, Shergotty, Zagami, and ALHA77005: late magmatism on a geologically active planet
journal, November 1982


Solar Nebula Heterogeneity in p-Process Samarium and Neodymium Isotopes
journal, November 2006


Thermal evolution of an early magma ocean in interaction with the atmosphere: MAGMA OCEAN AND ATMOSPHERE EVOLUTION
journal, June 2013

  • Lebrun, T.; Massol, H.; Chassefière, E.
  • Journal of Geophysical Research: Planets, Vol. 118, Issue 6
  • DOI: 10.1002/jgre.20068

The early differentiation history of Mars from 182W-142Nd isotope systematics in the SNC meteorites
journal, September 2005

  • Foley, C. Nicole; Wadhwa, M.; Borg, L. E.
  • Geochimica et Cosmochimica Acta, Vol. 69, Issue 18
  • DOI: 10.1016/j.gca.2005.05.009

Constraints on the petrogenesis of Martian meteorites from the Rb-Sr and Sm-Nd isotopic systematics of the lherzolitic shergottites ALH77005 and LEW88516
journal, June 2002


Magma ocean formation due to giant impacts
journal, March 1993

  • Tonks, W. Brian; Melosh, H. Jay
  • Journal of Geophysical Research: Planets, Vol. 98, Issue E3
  • DOI: 10.1029/92JE02726

Martian mantle mineralogy investigated by the 176Lu–176Hf and 147Sm–143Nd systematics of shergottites
journal, May 2008

  • Debaille, V.; Yin, Q. -Z.; Brandon, A. D.
  • Earth and Planetary Science Letters, Vol. 269, Issue 1-2
  • DOI: 10.1016/j.epsl.2008.02.008

Implications of an impact origin for the martian hemispheric dichotomy
journal, June 2008

  • Nimmo, F.; Hart, S. D.; Korycansky, D. G.
  • Nature, Vol. 453, Issue 7199
  • DOI: 10.1038/nature07025

Evolution of the martian mantle inferred from the 187Re–187Os isotope and highly siderophile element abundance systematics of shergottite meteorites
journal, January 2012

  • Brandon, Alan D.; Puchtel, Igor S.; Walker, Richard J.
  • Geochimica et Cosmochimica Acta, Vol. 76
  • DOI: 10.1016/j.gca.2011.09.047

Rb-Sr age of the Shergotty achondrite and implications for metamorphic resetting of isochron ages
journal, July 1979


Core Formation and Mantle Differentiation on Mars
journal, October 2012

  • Mezger, Klaus; Debaille, Vinciane; Kleine, Thorsten
  • Space Science Reviews, Vol. 174, Issue 1-4
  • DOI: 10.1007/s11214-012-9935-8

Half-life and ?-ray energy of146Sm
journal, June 1987

  • Meissner, F.; Schmidt-Ott, W. -D.; Ziegeler, L.
  • Zeitschrift f�r Physik A Atomic Nuclei, Vol. 327, Issue 2
  • DOI: 10.1007/BF01292406

The Absolute Chronology and Thermal Processing of Solids in the Solar Protoplanetary Disk
journal, November 2012


Hf–W–Th evidence for rapid growth of Mars and its status as a planetary embryo
journal, May 2011


Constraints on Martian differentiation processes from RbSr and SmNd isotopic analyses of the basaltic shergottite QUE 94201
journal, November 1997


Neodymium Isotope Evidence for a Chondritic Composition of the Moon
journal, June 2006


Mega-impact formation of the Mars hemispheric dichotomy
journal, June 2008

  • Marinova, Margarita M.; Aharonson, Oded; Asphaug, Erik
  • Nature, Vol. 453, Issue 7199
  • DOI: 10.1038/nature07070

Could giant impacts cripple core dynamos of small terrestrial planets?
journal, April 2011


Lunar neutron stratigraphy
journal, June 1972


The age of the martian meteorite Northwest Africa 1195 and the differentiation history of the shergottites
journal, March 2008

  • Symes, Steven J. K.; Borg, Lars E.; Shearer, Charles K.
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 6
  • DOI: 10.1016/j.gca.2007.12.022

The Lu–Hf isotope geochemistry of shergottites and the evolution of the Martian mantle–crust system
journal, November 1999

  • Blichert-Toft, Janne; Gleason, James D.; Télouk, Philippe
  • Earth and Planetary Science Letters, Vol. 173, Issue 1-2
  • DOI: 10.1016/S0012-821X(99)00222-8

Thermal and chemical evolution of the terrestrial magma ocean
journal, March 1997


How rapidly did Mars accrete? Uncertainties in the Hf–W timing of core formation
journal, November 2007


Chronological evidence that the Moon is either young or did not have a global magma ocean
journal, August 2011

  • Borg, Lars E.; Connelly, James N.; Boyet, Maud
  • Nature, Vol. 477, Issue 7362
  • DOI: 10.1038/nature10328

Hf–W chronology of the accretion and early evolution of asteroids and terrestrial planets
journal, September 2009

  • Kleine, Thorsten; Touboul, Mathieu; Bourdon, Bernard
  • Geochimica et Cosmochimica Acta, Vol. 73, Issue 17
  • DOI: 10.1016/j.gca.2008.11.047

A Shorter 146Sm Half-Life Measured and Implications for 146Sm-142Nd Chronology in the Solar System
journal, March 2012


A chemical model for generating the sources of mare basalts: Combined equilibrium and fractional crystallization of the lunar magmasphere
journal, October 1992

  • Snyder, Gregory A.; Taylor, Lawrence A.; Neal, Clive R.
  • Geochimica et Cosmochimica Acta, Vol. 56, Issue 10
  • DOI: 10.1016/0016-7037(92)90172-F

Constraints on the U-Pb isotopic systematics of Mars inferred from a combined U-Pb, Rb-Sr, and Sm-Nd isotopic study of the Martian meteorite Zagami
journal, December 2005

  • Borg, Lars E.; Edmunson, Jennifer E.; Asmerom, Yemane
  • Geochimica et Cosmochimica Acta, Vol. 69, Issue 24
  • DOI: 10.1016/j.gca.2005.08.007

Old Sm–Nd ages for cumulate eucrites and redetermination of the solar system initial 146Sm/144Sm ratio
journal, March 2010

  • Boyet, Maud; Carlson, Richard W.; Horan, Mary
  • Earth and Planetary Science Letters, Vol. 291, Issue 1-4
  • DOI: 10.1016/j.epsl.2010.01.010

Samarium–neodymium chronology and rubidium–strontium systematics of an Allende calcium–aluminum-rich inclusion with implications for 146Sm half-life
journal, November 2014


A review of meteorite evidence for the timing of magmatism and of surface or near-surface liquid water on Mars
journal, January 2005


The age of Dar al Gani 476 and the differentiation history of the martian meteorites inferred from their radiogenic isotopic systematics
journal, September 2003


Insights into the Martian mantle: The age and isotopics of the meteorite fall Tissint
journal, March 2014

  • Brennecka, G. A.; Borg, L. E.; Wadhwa, M.
  • Meteoritics & Planetary Science, Vol. 49, Issue 3
  • DOI: 10.1111/maps.12258

Linked magma ocean solidification and atmospheric growth for Earth and Mars
journal, July 2008


Re-evaluating 142Nd/144Nd in lunar mare basalts with implications for the early evolution and bulk Sm/Nd of the Moon
journal, October 2009

  • Brandon, Alan D.; Lapen, Thomas J.; Debaille, Vinciane
  • Geochimica et Cosmochimica Acta, Vol. 73, Issue 20
  • DOI: 10.1016/j.gca.2009.07.015

Petrology and chemistry of the new shergottite Dar al Gani 476
journal, January 2000


Alpha Decay Half Lives of 148Gd 150Gd and 146Sm
journal, January 1966


Works referencing / citing this record:

The potential science and engineering value of samples delivered to Earth by Mars sample return
journal, March 2019

  • Beaty, D. W.; Grady, M. M.; McSween, H. Y.
  • Meteoritics & Planetary Science, Vol. 54, Issue 3
  • DOI: 10.1111/maps.13232

Magma oceans as a critical stage in the tectonic development of rocky planets
journal, October 2018

  • Schaefer, Laura; Elkins-Tanton, Linda T.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 376, Issue 2132
  • DOI: 10.1098/rsta.2018.0109

A colossal impact enriched Mars' mantle with noble metals
text, January 2017


Evidence for extremely rapid magma ocean crystallization and crust formation on Mars
journal, June 2018


A colossal impact enriched Mars' mantle with noble metals: Late Accretion on Mars
journal, June 2017

  • Brasser, R.; Mojzsis, S. J.
  • Geophysical Research Letters, Vol. 44, Issue 12
  • DOI: 10.1002/2017gl074002

Martian magmatism from plume metasomatized mantle
journal, November 2018


Evidence for extremely rapid magma ocean crystallization and crust formation on Mars
journal, June 2018


In search of the Earth-forming reservoir: Mineralogical, chemical, and isotopic characterizations of the ungrouped achondrite NWA 5363/NWA 5400 and selected chondrites
journal, March 2017

  • Burkhardt, Christoph; Dauphas, Nicolas; Tang, Haolan
  • Meteoritics & Planetary Science, Vol. 52, Issue 5
  • DOI: 10.1111/maps.12834

A new type of isotopic anomaly in shergottite sulfides
journal, November 2019

  • Franz, Heather B.; Wu, Nanping; Farquhar, James
  • Meteoritics & Planetary Science, Vol. 54, Issue 12
  • DOI: 10.1111/maps.13404

The potential science and engineering value of samples delivered to Earth by Mars sample return
text, January 2019

  • (Imost), International MSR Objectives And Samples Team; Beaty, David W.; Grady, Monica M.
  • ETH Zurich
  • DOI: 10.3929/ethz-b-000332454

Isotopic evolution of the protoplanetary disk and the building blocks of Earth and the Moon
journal, March 2018

  • Schiller, Martin; Bizzarro, Martin; Fernandes, Vera Assis
  • Nature, Vol. 555, Issue 7697
  • DOI: 10.1038/nature25990

The potential science and engineering value of samples delivered to Earth by Mars sample return: International MSR Objectives and Samples Team (iMOST)
journal, March 2019

  • Beaty, D. W.; Grady, M. M.; McSween, H. Y.
  • Meteoritics & Planetary Science, Vol. 54
  • DOI: 10.1111/maps.13242