Controlled 3D Carbon Nanotube Architecture Coated with MoO x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode

Dhara, Arpan; Sarkar, Shaibal K.; Mitra, Sagar

doi:10.1002/admi.201700332

Title: Controlled 3D Carbon Nanotube Architecture Coated with MoO _x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode

Abstract

Due to its high theoretical capacity, energy density, and excellent reversibility with Li/Li ⁺ , molybdenum oxide is one of the vastly studied electrode material in lithium‐ion batteries. However, like most of the oxides, it also suffers from poor cyclic stability because of its low electrical conductivity. In 3D core–shell structure prepared by atomic layer deposition coating, it can provide superiority in nanoscale decoration than other deposition methods because of its extreme conformality and precise thickness control on high aspect ratio surfaces. This report illustrates the electrochemical activity of 3D core–shell type amorphous MoO _x material coated by atomic layer deposition technique on conducting carbon nanotubes (CNT) scaffold which exhibits excellent overall cell capacity. The obtained capacity is manifold higher than its planar 2D counterpart and that can become an advanced nanoscale fabrication methodology of such 3D nanostructures for electrode preparation. Such binder free MoO _x /CNT core–shell electrode structure shows very high and stable electrochemical activity toward Li/Li ⁺ system. An optimal thickness of MoO _x on CNT is also found out in order to attain the most stable cyclic performance of this nanostructure. A stable reversible areal capacity of 645 µAh cm ⁻² with specific capacity of 915more »« less

Authors:

Dhara, Arpan ^[1]; Sarkar, Shaibal K. ^[1]; Mitra, Sagar ^[1]

Department of Energy Science and Engineering Indian Institute of Technology Bombay Mumbai 400076 India

Publication Date:: Wed Jul 12 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1380045

Grant/Contract Number:: DE‐AC36‐08GO28308

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Materials Interfaces

Additional Journal Information:: Journal Name: Advanced Materials Interfaces Journal Volume: 4 Journal Issue: 17; Journal ID: ISSN 2196-7350

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Dhara, Arpan, Sarkar, Shaibal K., and Mitra, Sagar. Controlled 3D Carbon Nanotube Architecture Coated with MoO x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode.  Germany: N. p., 2017. 
Web.  doi:10.1002/admi.201700332.

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                    Dhara, Arpan, Sarkar, Shaibal K., & Mitra, Sagar. Controlled 3D Carbon Nanotube Architecture Coated with MoO x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode.  Germany.  https://doi.org/10.1002/admi.201700332

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                    Dhara, Arpan, Sarkar, Shaibal K., and Mitra, Sagar. Wed .  
"Controlled 3D Carbon Nanotube Architecture Coated with MoO x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode".  Germany.  https://doi.org/10.1002/admi.201700332.

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@article{osti_1380045,

  title        = {Controlled 3D Carbon Nanotube Architecture Coated with MoO x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode},

  author       = {Dhara, Arpan and Sarkar, Shaibal K. and Mitra, Sagar},

  abstractNote = {Due to its high theoretical capacity, energy density, and excellent reversibility with Li/Li + , molybdenum oxide is one of the vastly studied electrode material in lithium‐ion batteries. However, like most of the oxides, it also suffers from poor cyclic stability because of its low electrical conductivity. In 3D core–shell structure prepared by atomic layer deposition coating, it can provide superiority in nanoscale decoration than other deposition methods because of its extreme conformality and precise thickness control on high aspect ratio surfaces. This report illustrates the electrochemical activity of 3D core–shell type amorphous MoO x material coated by atomic layer deposition technique on conducting carbon nanotubes (CNT) scaffold which exhibits excellent overall cell capacity. The obtained capacity is manifold higher than its planar 2D counterpart and that can become an advanced nanoscale fabrication methodology of such 3D nanostructures for electrode preparation. Such binder free MoO x /CNT core–shell electrode structure shows very high and stable electrochemical activity toward Li/Li + system. An optimal thickness of MoO x on CNT is also found out in order to attain the most stable cyclic performance of this nanostructure. A stable reversible areal capacity of 645 µAh cm −2 with specific capacity of 915 mAh g −1 is achieved from optimized MoO x /CNT assembly.},

  doi          = {10.1002/admi.201700332},

  journal      = {Advanced Materials Interfaces},

  number       = 17,

  volume       = 4,

  place        = {Germany},

  year         = {Wed Jul 12 00:00:00 EDT 2017},

  month        = {Wed Jul 12 00:00:00 EDT 2017}

}

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Title: Controlled 3D Carbon Nanotube Architecture Coated with MoO x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode

Abstract

Citation Formats

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SnO2 nanocrystals deposited on multiwalled carbon nanotubes with superior stability as anode material for Li-ion batteries journal, October 2011

Carbon nanotube-wired and oxygen-deficient MoO 3 nanobelts with enhanced lithium-storage capability journal, February 2014

Three-Dimensional Ni/TiO 2 Nanowire Network for High Areal Capacity Lithium Ion Microbattery Applications journal, January 2012

Assembled-sheets-like MoO3 anodes with excellent electrochemical performance in Li-ion battery journal, December 2016

Electrochemical Performance of Porous Carbon/Tin Composite Anodes for Sodium-Ion and Lithium-Ion Batteries journal, September 2012

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries journal, September 2000

Atomic Layer Deposition for Lithium-Based Batteries journal, September 2016

α-MoO 3 Nanobelts: A High Performance Cathode Material for Lithium Ion Batteries journal, November 2010

High-performing iron phosphate for enhanced lithium ion solid state batteries as grown by atomic layer deposition journal, January 2013

Graphene nanosheets encapsulated α-MoO 3 nanoribbons with ultrahigh lithium ion storage properties journal, January 2014

Understanding electrochemical potentials of cathode materials in rechargeable batteries journal, March 2016

Single-crystalline MoO3 nanoplates: topochemical synthesis and enhanced ethanol-sensing performance journal, January 2011

Electrochemical Energy Storage for Green Grid journal, May 2011

Combination of characterization techniques for atomic layer deposition MoO 3 coatings: From the amorphous to the orthorhombic α-MoO 3 crystalline phase journal, January 2012

Developments in Nanostructured Cathode Materials for High-Performance Lithium-Ion Batteries journal, June 2008

Transmission electron microscopy (TEM) analysis of two-phase reaction in electrochemical lithium insertion within α-MoO3 journal, November 2000

Hydrothermal synthesis of carbon nanotube/cobalt oxide core-shell one-dimensional nanocomposite and application as an anode material for lithium-ion batteries journal, March 2009

Layered lithium transition metal oxide cathodes towards high energy lithium-ion batteries journal, January 2012

Study of the Photochromic Properties of Amorphous MoO3 Films Using Raman Microscopy journal, November 1995

Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance journal, June 2010

Lithium batteries: Status, prospects and future journal, May 2010

Three-dimensional porous graphene-metal oxide composite microspheres: Preparation and application in Li-ion batteries journal, January 2015

Fabrication of 3D Core–Shell Multiwalled Carbon Nanotube@RuO 2 Lithium-Ion Battery Electrodes through a RuO 2 Atomic Layer Deposition Process journal, December 2014

Atomic Layer Deposition: An Overview journal, January 2010

Atomic layer deposition of molybdenum oxide using bis(tert-butylimido)bis(dimethylamido) molybdenum journal, January 2014

Lithium insertion/extraction reaction on crystalline MoO3 journal, December 1997

Atomic layer deposition of vanadium oxide on carbon nanotubes for high-power supercapacitor electrodes journal, January 2012

Binder-free α-MoO3 nanobelt electrode for lithium-ion batteries utilizing van der Waals forces for film formation and connection with current collector journal, January 2013

Lithium Potential Variations for Metastable Materials: Case Study of Nanocrystalline and Amorphous LiFePO 4 journal, August 2014

Fluorine substituted molybdenum oxide as cathode material for Li-ion battery journal, December 2015

Synthesis and Surface Engineering of Complex Nanostructures by Atomic Layer Deposition journal, November 2007

Uptake of lithium by layered molybdenum oxide and its tin exchanged derivatives: high volumetric capacity materials journal, August 2000

Porous MoO 3 Film as a High-Performance Anode Material for Lithium-Ion Batteries journal, July 2014

Synthesis and Electrochemical Characterization of Vanadium Oxide on Carbon Nanotube Film Substrate for Pseudocapacitor Applications journal, January 2006

Structural evolution of the MoO3(010) surface during lithium intercalation journal, June 2003

Atomic Layer Deposition of Molybdenum Oxide for Solar Cell Application journal, January 2014

Growth of thin films of molybdenum oxide by atomic layer deposition journal, January 2011

Gallium Sulfide-Single-Walled Carbon Nanotube Composites: High-Performance Anodes for Lithium-Ion Batteries journal, July 2014

Title: Controlled 3D Carbon Nanotube Architecture Coated with MoO _x Material by ALD Technique: A High Energy Density Lithium‐Ion Battery Electrode

Graphene-Wrapped Fe₃O₄ Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries
journal, September 2010

Conformal Surface Coatings to Enable High Volume Expansion Li-Ion Anode Materials
journal, May 2010

Tin Oxide with Controlled Morphology and Crystallinity by Atomic Layer Deposition onto Graphene Nanosheets for Enhanced Lithium Storage
journal, February 2012

Atomic Layer Deposition on Biological Macromolecules: Metal Oxide Coating of Tobacco Mosaic Virus and Ferritin
journal, June 2006

Microstructures of Electrochromic MoO ₃ Thin Films Colored by Injection of Different Cations
journal, November 1998

Two-phase reaction mechanism during chemical lithium insertion into α-MoO3
journal, January 2007

In situ synthesis of α-MoO3/graphene composites as anode materials for lithium ion battery
journal, February 2014

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

Three-dimensional thin-film Li-ion microbatteries for autonomous MEMS
journal, October 2005

Atomic layer deposited tungsten nitride thin films as a new lithium-ion battery anode
journal, January 2015

Porous α-MoO ₃ /MWCNT Nanocomposite Synthesized via a Surfactant-Assisted Solvothermal Route as a Lithium-Ion-Battery High-Capacity Anode Material with Excellent Rate Capability and Cyclability
journal, July 2015

High rate and durable, binder free anode based on silicon loaded MoO3 nanoplatelets
journal, May 2015

Intercalation based tungsten disulfide (WS ₂ ) Li-ion battery anode grown by atomic layer deposition
journal, January 2016

Single-crystalline α-MoO3 microbelts derived from a bio-templating method for superior lithium storage application
journal, December 2016

Surface Passivation of MoO ₃ Nanorods by Atomic Layer Deposition toward High Rate Durable Li Ion Battery Anodes
journal, June 2015

Battery materials for ultrafast charging and discharging
journal, March 2009

Carbon-coated MoO3 nanobelts as anode materials for lithium-ion batteries
journal, April 2010

Electrochemical reactivity of ball-milled MoO3−y as anode materials for lithium-ion batteries
journal, March 2009

XPS, time-of-flight-SIMS and polarization modulation IRRAS study of Cr2O3 thin film materials as anode for lithium ion battery
journal, May 2009

Facile synthesis of MoO3/carbon nanobelts as high-performance anode material for lithium ion batteries
journal, October 2015

Electrochemical energy storage in a sustainable modern society
journal, January 2014

SnO2 nanocrystals deposited on multiwalled carbon nanotubes with superior stability as anode material for Li-ion batteries
journal, October 2011

Carbon nanotube-wired and oxygen-deficient MoO 3 nanobelts with enhanced lithium-storage capability
journal, February 2014

Three-Dimensional Ni/TiO ₂ Nanowire Network for High Areal Capacity Lithium Ion Microbattery Applications
journal, January 2012

Assembled-sheets-like MoO3 anodes with excellent electrochemical performance in Li-ion battery
journal, December 2016

Electrochemical Performance of Porous Carbon/Tin Composite Anodes for Sodium-Ion and Lithium-Ion Batteries
journal, September 2012

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

Atomic Layer Deposition for Lithium-Based Batteries
journal, September 2016

α-MoO ₃ Nanobelts: A High Performance Cathode Material for Lithium Ion Batteries
journal, November 2010

High-performing iron phosphate for enhanced lithium ion solid state batteries as grown by atomic layer deposition
journal, January 2013

Graphene nanosheets encapsulated α-MoO ₃ nanoribbons with ultrahigh lithium ion storage properties
journal, January 2014

Understanding electrochemical potentials of cathode materials in rechargeable batteries
journal, March 2016

Single-crystalline MoO3 nanoplates: topochemical synthesis and enhanced ethanol-sensing performance
journal, January 2011

Electrochemical Energy Storage for Green Grid
journal, May 2011

Combination of characterization techniques for atomic layer deposition MoO ₃ coatings: From the amorphous to the orthorhombic α-MoO ₃ crystalline phase
journal, January 2012

Developments in Nanostructured Cathode Materials for High-Performance Lithium-Ion Batteries
journal, June 2008

Transmission electron microscopy (TEM) analysis of two-phase reaction in electrochemical lithium insertion within α-MoO3
journal, November 2000

Hydrothermal synthesis of carbon nanotube/cobalt oxide core-shell one-dimensional nanocomposite and application as an anode material for lithium-ion batteries
journal, March 2009

Layered lithium transition metal oxide cathodes towards high energy lithium-ion batteries
journal, January 2012

Study of the Photochromic Properties of Amorphous MoO3 Films Using Raman Microscopy
journal, November 1995

Graphene Anchored with Co₃O₄ Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance
journal, June 2010

Lithium batteries: Status, prospects and future
journal, May 2010

Three-dimensional porous graphene-metal oxide composite microspheres: Preparation and application in Li-ion batteries
journal, January 2015

Fabrication of 3D Core–Shell Multiwalled Carbon Nanotube@RuO ₂ Lithium-Ion Battery Electrodes through a RuO ₂ Atomic Layer Deposition Process
journal, December 2014

Atomic Layer Deposition: An Overview
journal, January 2010

Atomic layer deposition of molybdenum oxide using bis(tert-butylimido)bis(dimethylamido) molybdenum
journal, January 2014

Lithium insertion/extraction reaction on crystalline MoO3
journal, December 1997

Atomic layer deposition of vanadium oxide on carbon nanotubes for high-power supercapacitor electrodes
journal, January 2012

Binder-free α-MoO3 nanobelt electrode for lithium-ion batteries utilizing van der Waals forces for film formation and connection with current collector
journal, January 2013

Lithium Potential Variations for Metastable Materials: Case Study of Nanocrystalline and Amorphous LiFePO ₄
journal, August 2014

Fluorine substituted molybdenum oxide as cathode material for Li-ion battery
journal, December 2015

Synthesis and Surface Engineering of Complex Nanostructures by Atomic Layer Deposition
journal, November 2007

Uptake of lithium by layered molybdenum oxide and its tin exchanged derivatives: high volumetric capacity materials
journal, August 2000

Porous MoO ₃ Film as a High-Performance Anode Material for Lithium-Ion Batteries
journal, July 2014

Synthesis and Electrochemical Characterization of Vanadium Oxide on Carbon Nanotube Film Substrate for Pseudocapacitor Applications
journal, January 2006

Structural evolution of the MoO3(010) surface during lithium intercalation
journal, June 2003

Atomic Layer Deposition of Molybdenum Oxide for Solar Cell Application
journal, January 2014

Growth of thin films of molybdenum oxide by atomic layer deposition
journal, January 2011

Gallium Sulfide-Single-Walled Carbon Nanotube Composites: High-Performance Anodes for Lithium-Ion Batteries
journal, July 2014