A high-voltage rechargeable magnesium-sodium hybrid battery
Abstract
There is a growing global demand for safe and low-cost energy storage technology which triggers strong interests in novel battery concepts beyond state-of-art Li-ion batteries. We report a high-voltage rechargeable Mg–Na hybrid battery featuring dendrite-free deposition of Mg anode and Na-intercalation cathode as a low-cost and safe alternative to Li-ion batteries for large-scale energy storage. A prototype device using a Na3V2(PO4)3 cathode, a Mg anode, and a Mg–Na dual salt electrolyte exhibits the highest voltage (2.60 V vs. Mg) and best rate performance (86% capacity retention at 10 C rate) among reported hybrid batteries. Synchrotron radiation-based X-ray absorption near edge structure (XANES), atomic-pair distribution function (PDF), and high-resolution X-ray diffraction (HRXRD) studies reveal the chemical environment and structural change of Na3V2(PO4)3 cathode during the Na ion insertion/deinsertion process. XANES study shows a clear reversible shift of vanadium K-edge and HRXRD and PDF studies reveal a reversible two-phase transformation and V–O bond length change during cycling. The energy density of the hybrid cell could be further improved by developing electrolytes with a higher salt concentration and wider electrochemical window. Our work represents a significant step forward for practical safe and low-cost hybrid batteries.
- Authors:
-
- Univ. of Houston, TX (United States). Dept. of Electrical and Computer Engineering. Materials Science and Engineering Program
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Electrochemical Materials and Systems Group. Energy and Environment Directorate
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
- Univ. of Houston, TX (United States). Dept. of Chemistry. Texas Center for Superconductivity
- Univ. of Houston, TX (United States). Dept. of Electrical and Computer Engineering. Materials Science and Engineering Program. Texas Center for Superconductivity
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Univ. of Houston, TX (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Electricity (OE); US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF)
- OSTI Identifier:
- 1344910
- Alternate Identifier(s):
- OSTI ID: 1366533; OSTI ID: 1415688
- Report Number(s):
- PNNL-SA-123660
Journal ID: ISSN 2211-2855; PII: S2211285517300782
- Grant/Contract Number:
- AC05-76RL01830; AC02-06CH11357; 57558; N00014-13-1-0543; CMMI-1400261
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Energy
- Additional Journal Information:
- Journal Volume: 34; Journal ID: ISSN 2211-2855
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; hybrid Mg–Na ion battery; Na3V2(PO4)3; Mg; XANES; pair density function
Citation Formats
Li, Yifei, An, Qinyou, Cheng, Yingwen, Liang, Yanliang, Ren, Yang, Sun, Cheng-Jun, Dong, Hui, Tang, Zhongjia, Li, Guosheng, and Yao, Yan. A high-voltage rechargeable magnesium-sodium hybrid battery. United States: N. p., 2017.
Web. doi:10.1016/j.nanoen.2017.02.012.
Li, Yifei, An, Qinyou, Cheng, Yingwen, Liang, Yanliang, Ren, Yang, Sun, Cheng-Jun, Dong, Hui, Tang, Zhongjia, Li, Guosheng, & Yao, Yan. A high-voltage rechargeable magnesium-sodium hybrid battery. United States. https://doi.org/10.1016/j.nanoen.2017.02.012
Li, Yifei, An, Qinyou, Cheng, Yingwen, Liang, Yanliang, Ren, Yang, Sun, Cheng-Jun, Dong, Hui, Tang, Zhongjia, Li, Guosheng, and Yao, Yan. Mon .
"A high-voltage rechargeable magnesium-sodium hybrid battery". United States. https://doi.org/10.1016/j.nanoen.2017.02.012. https://www.osti.gov/servlets/purl/1344910.
@article{osti_1344910,
title = {A high-voltage rechargeable magnesium-sodium hybrid battery},
author = {Li, Yifei and An, Qinyou and Cheng, Yingwen and Liang, Yanliang and Ren, Yang and Sun, Cheng-Jun and Dong, Hui and Tang, Zhongjia and Li, Guosheng and Yao, Yan},
abstractNote = {There is a growing global demand for safe and low-cost energy storage technology which triggers strong interests in novel battery concepts beyond state-of-art Li-ion batteries. We report a high-voltage rechargeable Mg–Na hybrid battery featuring dendrite-free deposition of Mg anode and Na-intercalation cathode as a low-cost and safe alternative to Li-ion batteries for large-scale energy storage. A prototype device using a Na3V2(PO4)3 cathode, a Mg anode, and a Mg–Na dual salt electrolyte exhibits the highest voltage (2.60 V vs. Mg) and best rate performance (86% capacity retention at 10 C rate) among reported hybrid batteries. Synchrotron radiation-based X-ray absorption near edge structure (XANES), atomic-pair distribution function (PDF), and high-resolution X-ray diffraction (HRXRD) studies reveal the chemical environment and structural change of Na3V2(PO4)3 cathode during the Na ion insertion/deinsertion process. XANES study shows a clear reversible shift of vanadium K-edge and HRXRD and PDF studies reveal a reversible two-phase transformation and V–O bond length change during cycling. The energy density of the hybrid cell could be further improved by developing electrolytes with a higher salt concentration and wider electrochemical window. Our work represents a significant step forward for practical safe and low-cost hybrid batteries.},
doi = {10.1016/j.nanoen.2017.02.012},
journal = {Nano Energy},
number = ,
volume = 34,
place = {United States},
year = {Mon Feb 13 00:00:00 EST 2017},
month = {Mon Feb 13 00:00:00 EST 2017}
}
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