Breaking the paradigm: Record quindecim charged magnetic ionic liquids

Prodius, D.; Smetana, V.; Steinberg, S.; Wilk-Kozubek, M.; Mudryk, Y.; Pecharsky, V. K.; Mudring, A. -V.

doi:10.1039/C6MH00468G

Title: Breaking the paradigm: Record quindecim charged magnetic ionic liquids

Journal Article · Wed Dec 07 23:00:00 EST 2016 · Materials Horizons

DOI: https://doi.org/10.1039/C6MH00468G · OSTI ID:1357792

^[1]; Smetana, V. ^[1]; Steinberg, S. ^[1]; Wilk-Kozubek, M. ^[2]; Mudryk, Y. ^[1]; Pecharsky, V. K. ^[2];

^[2]

Ames Lab., Ames, IA (United States)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

A family of bis(trifluoromethanesulfonyl)amide-based ionic liquids of composition [RE₅(C₂H₅-C₃H₃N₂-CH₂COO)₁₆(H₂O)₈](Tf₂N)₁₅ (RE = Er, Ho, Tm; C₃H₃N₂ ≡ imidazolium moiety) featuring the cationic, record quindecim {15+} charged pentanuclear rare earth (RE)-containing ion [RE₅(C₂H₅-C₃H₃N₂-CH₂COO)₁₆(H₂O)₈]¹⁵⁺ has been synthesized and characterized. In addition, due to the presence of rare earth ions, these ionic liquids show a response to magnetic fields with the highest effective magnetic moment observed so far for an ionic liquid and are rare examples of ionic liquids showing luminescence in the near-infrared. As a result, these ionic liquids also were successfully employed in a three-component synthesis of 2-pyrrolo-3'-yloxindole with an extremely low (<0.035 mol%) catalyst loading rate.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1357792

Report Number(s):: IS-J--9311

Journal Information:: Materials Horizons, Journal Name: Materials Horizons Journal Issue: 2 Vol. 4; ISSN 2051-6347; ISSN MHAOAL

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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