Breaking the paradigm: Record quindecim charged magnetic ionic liquids
Abstract
A family of bis(trifluoromethanesulfonyl)amide-based ionic liquids of composition [RE5(C2H5-C3H3N2-CH2COO)16(H2O)8](Tf2N)15 (RE = Er, Ho, Tm; C3H3N2 ≡ imidazolium moiety) featuring the cationic, record quindecim {15+} charged pentanuclear rare earth (RE)-containing ion [RE5(C2H5-C3H3N2-CH2COO)16(H2O)8]15+ has been synthesized and characterized. In addition, due to the presence of rare earth ions, these ionic liquids show a response to magnetic fields with the highest effective magnetic moment observed so far for an ionic liquid and are rare examples of ionic liquids showing luminescence in the near-infrared. As a result, these ionic liquids also were successfully employed in a three-component synthesis of 2-pyrrolo-3'-yloxindole with an extremely low (<0.035 mol%) catalyst loading rate.
- Authors:
-
[1];
[2]
- Ames Lab., Ames, IA (United States)
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1357792
- Report Number(s):
- IS-J-9311
Journal ID: ISSN 2051-6347; MHAOAL; TRN: US1702303
- Grant/Contract Number:
- CHE-1465071; AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Materials Horizons
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 2; Journal ID: ISSN 2051-6347
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Prodius, D., Smetana, V., Steinberg, S., Wilk-Kozubek, M., Mudryk, Y., Pecharsky, V. K., and Mudring, A. -V. Breaking the paradigm: Record quindecim charged magnetic ionic liquids. United States: N. p., 2016.
Web. doi:10.1039/C6MH00468G.
Prodius, D., Smetana, V., Steinberg, S., Wilk-Kozubek, M., Mudryk, Y., Pecharsky, V. K., & Mudring, A. -V. Breaking the paradigm: Record quindecim charged magnetic ionic liquids. United States. https://doi.org/10.1039/C6MH00468G
Prodius, D., Smetana, V., Steinberg, S., Wilk-Kozubek, M., Mudryk, Y., Pecharsky, V. K., and Mudring, A. -V. Thu .
"Breaking the paradigm: Record quindecim charged magnetic ionic liquids". United States. https://doi.org/10.1039/C6MH00468G. https://www.osti.gov/servlets/purl/1357792.
@article{osti_1357792,
title = {Breaking the paradigm: Record quindecim charged magnetic ionic liquids},
author = {Prodius, D. and Smetana, V. and Steinberg, S. and Wilk-Kozubek, M. and Mudryk, Y. and Pecharsky, V. K. and Mudring, A. -V.},
abstractNote = {A family of bis(trifluoromethanesulfonyl)amide-based ionic liquids of composition [RE5(C2H5-C3H3N2-CH2COO)16(H2O)8](Tf2N)15 (RE = Er, Ho, Tm; C3H3N2 ≡ imidazolium moiety) featuring the cationic, record quindecim {15+} charged pentanuclear rare earth (RE)-containing ion [RE5(C2H5-C3H3N2-CH2COO)16(H2O)8]15+ has been synthesized and characterized. In addition, due to the presence of rare earth ions, these ionic liquids show a response to magnetic fields with the highest effective magnetic moment observed so far for an ionic liquid and are rare examples of ionic liquids showing luminescence in the near-infrared. As a result, these ionic liquids also were successfully employed in a three-component synthesis of 2-pyrrolo-3'-yloxindole with an extremely low (<0.035 mol%) catalyst loading rate.},
doi = {10.1039/C6MH00468G},
journal = {Materials Horizons},
number = 2,
volume = 4,
place = {United States},
year = {Thu Dec 08 00:00:00 EST 2016},
month = {Thu Dec 08 00:00:00 EST 2016}
}
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Figures / Tables:
Figure 1: Images of ionic liquids after a two month crystallization term: {Er5} (1, middle), {Ho5} (2, left) and {Tm5} (3, right) and their TG (solid line)/DSC (dotted line) curves (for crystalline 1; for 2 and 3 in a liquid state).
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