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Title: Effect of Backbone Chemistry on the Structure of Polyurea Films Deposited by Molecular Layer Deposition

An experimental investigation into the growth of polyurea films by molecular layer deposition was performed by examining trends in the growth rate, crystallinity, and orientation of chains as a function of backbone flexibility. Growth curves obtained for films containing backbones of aliphatic and phenyl groups indicate that an increase in backbone flexibility leads to a reduction in growth rate from 4 to 1 Å/cycle. Crystallinity measurements collected using grazing incidence X-ray diffraction and Fourier transform infrared spectroscopy suggest that some chains form paracrystalline, out-of-plane stacks of polymer segments with packing distances ranging from 4.4 to 3.7 Å depending on the monomer size. Diffraction intensity is largely a function of the homogeneity of the backbone. Near-edge X-ray absorption fine structure measurements for thin and thick samples show an average chain orientation of ~25° relative to the substrate across all samples, suggesting that changes in growth rate are not caused by differences in chain angle but instead may be caused by differences in the frequency of chain terminations. In conclusion, these results suggest a model of molecular layer deposition-based chain growth in which films consist of a mixture of upward growing chains and horizontally aligned layers of paracrystalline polymer segments.
Authors:
ORCiD logo [1] ;  [2] ;  [3] ;  [4] ;  [3] ; ORCiD logo [1]
  1. Stanford Univ., CA (United States). Dept. of Chemical Engineering
  2. Stanford Univ., CA (United States). Dept. of Chemistry
  3. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  4. Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
Publication Date:
Grant/Contract Number:
CHE-1213879; CHE-1607339; AC02-76SF00515
Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 3; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Research Org:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1353178

Bergsman, David S., Closser, Richard G., Tassone, Christopher J., Clemens, Bruce M., Nordlund, Dennis, and Bent, Stacey F.. Effect of Backbone Chemistry on the Structure of Polyurea Films Deposited by Molecular Layer Deposition. United States: N. p., Web. doi:10.1021/acs.chemmater.6b04530.
Bergsman, David S., Closser, Richard G., Tassone, Christopher J., Clemens, Bruce M., Nordlund, Dennis, & Bent, Stacey F.. Effect of Backbone Chemistry on the Structure of Polyurea Films Deposited by Molecular Layer Deposition. United States. doi:10.1021/acs.chemmater.6b04530.
Bergsman, David S., Closser, Richard G., Tassone, Christopher J., Clemens, Bruce M., Nordlund, Dennis, and Bent, Stacey F.. 2017. "Effect of Backbone Chemistry on the Structure of Polyurea Films Deposited by Molecular Layer Deposition". United States. doi:10.1021/acs.chemmater.6b04530. https://www.osti.gov/servlets/purl/1353178.
@article{osti_1353178,
title = {Effect of Backbone Chemistry on the Structure of Polyurea Films Deposited by Molecular Layer Deposition},
author = {Bergsman, David S. and Closser, Richard G. and Tassone, Christopher J. and Clemens, Bruce M. and Nordlund, Dennis and Bent, Stacey F.},
abstractNote = {An experimental investigation into the growth of polyurea films by molecular layer deposition was performed by examining trends in the growth rate, crystallinity, and orientation of chains as a function of backbone flexibility. Growth curves obtained for films containing backbones of aliphatic and phenyl groups indicate that an increase in backbone flexibility leads to a reduction in growth rate from 4 to 1 Å/cycle. Crystallinity measurements collected using grazing incidence X-ray diffraction and Fourier transform infrared spectroscopy suggest that some chains form paracrystalline, out-of-plane stacks of polymer segments with packing distances ranging from 4.4 to 3.7 Å depending on the monomer size. Diffraction intensity is largely a function of the homogeneity of the backbone. Near-edge X-ray absorption fine structure measurements for thin and thick samples show an average chain orientation of ~25° relative to the substrate across all samples, suggesting that changes in growth rate are not caused by differences in chain angle but instead may be caused by differences in the frequency of chain terminations. In conclusion, these results suggest a model of molecular layer deposition-based chain growth in which films consist of a mixture of upward growing chains and horizontally aligned layers of paracrystalline polymer segments.},
doi = {10.1021/acs.chemmater.6b04530},
journal = {Chemistry of Materials},
number = 3,
volume = 29,
place = {United States},
year = {2017},
month = {1}
}