Cloud droplet activation through oxidation of organic aerosol influenced by temperature and particle phase state: CLOUD ACTIVATION BY AGED ORGANIC AEROSOL
Abstract
Chemical aging of organic aerosol (OA) through multiphase oxidation reactions can alter their cloud condensation nuclei (CCN) activity and hygroscopicity. However, the oxidation kinetics and OA reactivity depend strongly on the particle phase state, potentially influencing the hydrophobic-to-hydrophilic conversion rate of carbonaceous aerosol. Here, amorphous Suwannee River fulvic acid (SRFA) aerosol particles, a surrogate humic-like substance (HULIS) that contributes substantially to global OA mass, are oxidized by OH radicals at different temperatures and phase states. When oxidized at low temperature in a glassy solid state, the hygroscopicity of SRFA particles increased by almost a factor of two, whereas oxidation of liquid-like SRFA particles at higher temperatures did not affect CCN activity. Low-temperature oxidation appears to promote the formation of highly-oxygenated particle-bound fragmentation products with lower molar mass and greater CCN activity, underscoring the importance of chemical aging in the free troposphere and its influence on the CCN activity of OA.
- Authors:
-
- Stony Brook University, Institute for Terrestrial and Planetary Atmospheres, School of Marine and Atmospheric Sciences, Stony Brook NY USA; Now at Purdue University, Department of Chemistry, West Lafayette IN USA
- Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz Germany; University of California, Irvine, Department of Chemistry, Irvine CA USA
- Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz Germany
- Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz Germany; Institute for Environmental and Climate Research, Jinan University, Guangzhou China
- Brookhaven National Laboratory, Environmental and Climate Sciences Department, Upton NY USA
- Stony Brook University, Institute for Terrestrial and Planetary Atmospheres, School of Marine and Atmospheric Sciences, Stony Brook NY USA
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER); National Science Foundation (NSF); European Union (EU); Max Planck Society
- OSTI Identifier:
- 1344233
- Report Number(s):
- BNL-113518-2017-JA
Journal ID: ISSN 0094-8276; R&D Project: 2016-BNL-EE630EECA-Budg; KP1701000
- Grant/Contract Number:
- SC0012704; AGS-0846255; AGS-1446286; AC02098CH10886
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Geophysical Research Letters
- Additional Journal Information:
- Journal Volume: 44; Journal Issue: 3; Journal ID: ISSN 0094-8276
- Publisher:
- American Geophysical Union
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; organic aerosol; chemical aging; viscosity; cloud formation; hygroscopicity; OH oxidation
Citation Formats
Slade, Jonathan H., Shiraiwa, Manabu, Arangio, Andrea, Su, Hang, Pöschl, Ulrich, Wang, Jian, and Knopf, Daniel A. Cloud droplet activation through oxidation of organic aerosol influenced by temperature and particle phase state: CLOUD ACTIVATION BY AGED ORGANIC AEROSOL. United States: N. p., 2017.
Web. doi:10.1002/2016GL072424.
Slade, Jonathan H., Shiraiwa, Manabu, Arangio, Andrea, Su, Hang, Pöschl, Ulrich, Wang, Jian, & Knopf, Daniel A. Cloud droplet activation through oxidation of organic aerosol influenced by temperature and particle phase state: CLOUD ACTIVATION BY AGED ORGANIC AEROSOL. United States. https://doi.org/10.1002/2016GL072424
Slade, Jonathan H., Shiraiwa, Manabu, Arangio, Andrea, Su, Hang, Pöschl, Ulrich, Wang, Jian, and Knopf, Daniel A. Sat .
"Cloud droplet activation through oxidation of organic aerosol influenced by temperature and particle phase state: CLOUD ACTIVATION BY AGED ORGANIC AEROSOL". United States. https://doi.org/10.1002/2016GL072424. https://www.osti.gov/servlets/purl/1344233.
@article{osti_1344233,
title = {Cloud droplet activation through oxidation of organic aerosol influenced by temperature and particle phase state: CLOUD ACTIVATION BY AGED ORGANIC AEROSOL},
author = {Slade, Jonathan H. and Shiraiwa, Manabu and Arangio, Andrea and Su, Hang and Pöschl, Ulrich and Wang, Jian and Knopf, Daniel A.},
abstractNote = {Chemical aging of organic aerosol (OA) through multiphase oxidation reactions can alter their cloud condensation nuclei (CCN) activity and hygroscopicity. However, the oxidation kinetics and OA reactivity depend strongly on the particle phase state, potentially influencing the hydrophobic-to-hydrophilic conversion rate of carbonaceous aerosol. Here, amorphous Suwannee River fulvic acid (SRFA) aerosol particles, a surrogate humic-like substance (HULIS) that contributes substantially to global OA mass, are oxidized by OH radicals at different temperatures and phase states. When oxidized at low temperature in a glassy solid state, the hygroscopicity of SRFA particles increased by almost a factor of two, whereas oxidation of liquid-like SRFA particles at higher temperatures did not affect CCN activity. Low-temperature oxidation appears to promote the formation of highly-oxygenated particle-bound fragmentation products with lower molar mass and greater CCN activity, underscoring the importance of chemical aging in the free troposphere and its influence on the CCN activity of OA.},
doi = {10.1002/2016GL072424},
journal = {Geophysical Research Letters},
number = 3,
volume = 44,
place = {United States},
year = {Sat Feb 04 00:00:00 EST 2017},
month = {Sat Feb 04 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Change in global aerosol composition since preindustrial times
journal, January 2006
- Tsigaridis, K.; Krol, M.; Dentener, F. J.
- Atmospheric Chemistry and Physics, Vol. 6, Issue 12
The deposition ice nucleation and immersion freezing potential of amorphous secondary organic aerosol: Pathways for ice and mixed-phase cloud formation: ICE NUCLEATION BY AMORPHOUS SOA
journal, August 2012
- Wang, Bingbing; Lambe, Andrew T.; Massoli, Paola
- Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D16
Chemical aging of single and multicomponent biomass burning aerosol surrogate particles by OH: implications for cloud condensation nucleus activity
journal, January 2015
- Slade, J. H.; Thalman, R.; Wang, J.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 17
Global distribution of the effective aerosol hygroscopicity parameter for CCN activation
journal, January 2010
- Pringle, K. J.; Tost, H.; Pozzer, A.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 12
Heterogeneous Oxidation of Atmospheric Organic Aerosol: Kinetics of Changes to the Amount and Oxidation State of Particle-Phase Organic Carbon
journal, September 2015
- Kroll, Jesse H.; Lim, Christopher Y.; Kessler, Sean H.
- The Journal of Physical Chemistry A, Vol. 119, Issue 44
Mass-based hygroscopicity parameter interaction model and measurement of atmospheric aerosol water uptake
journal, January 2013
- Mikhailov, E.; Vlasenko, S.; Rose, D.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 2
Cloud droplet number enhanced by co-condensation of organic vapours
journal, May 2013
- Topping, David; Connolly, Paul; McFiggans, Gordon
- Nature Geoscience, Vol. 6, Issue 6
Large contribution of natural aerosols to uncertainty in indirect forcing
journal, November 2013
- Carslaw, K. S.; Lee, L. A.; Reddington, C. L.
- Nature, Vol. 503, Issue 7474
A single parameter representation of hygroscopic growth and cloud condensation nucleus activity
journal, January 2007
- Petters, M. D.; Kreidenweis, S. M.
- Atmospheric Chemistry and Physics, Vol. 7, Issue 8
Volatility and Aging of Atmospheric Organic Aerosol
book, January 2012
- Donahue, Neil M.; Robinson, Allen L.; Trump, Erica R.
- Topics in Current Chemistry
Multiphase OH oxidation kinetics of organic aerosol: The role of particle phase state and relative humidity
journal, July 2014
- Slade, Jonathan H.; Knopf, Daniel A.
- Geophysical Research Letters, Vol. 41, Issue 14
Cloud condensation nuclei in pristine tropical rainforest air of Amazonia: size-resolved measurements and modeling of atmospheric aerosol composition and CCN activity
journal, January 2009
- Gunthe, S. S.; King, S. M.; Rose, D.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 19
Airborne cloud condensation nuclei measurements during the 2006 Texas Air Quality Study
journal, January 2011
- Asa-Awuku, Akua; Moore, Richard H.; Nenes, Athanasios
- Journal of Geophysical Research, Vol. 116, Issue D11
Rethinking the global secondary organic aerosol (SOA) budget: stronger production, faster removal, shorter lifetime
journal, January 2016
- Hodzic, Alma; Kasibhatla, Prasad S.; Jo, Duseong S.
- Atmospheric Chemistry and Physics, Vol. 16, Issue 12
An interfacial mechanism for cloud droplet formation on organic aerosols
journal, March 2016
- Ruehl, C. R.; Davies, J. F.; Wilson, K. R.
- Science, Vol. 351, Issue 6280
A review on the human health impact of airborne particulate matter
journal, January 2015
- Kim, Ki-Hyun; Kabir, Ehsanul; Kabir, Shamin
- Environment International, Vol. 74
Hygroscopic Properties of Two Model Humic-like Substances and Their Mixtures with Inorganics of Atmospheric Importance
journal, November 2003
- Chan, Man Nin; Chan, Chak K.
- Environmental Science & Technology, Vol. 37, Issue 22
Hygroscopicity of Water-Soluble Organic Compounds in Atmospheric Aerosols: Amino Acids and Biomass Burning Derived Organic Species
journal, March 2005
- Chan, Man Nin; Choi, Man Yee; Ng, Nga Lee
- Environmental Science & Technology, Vol. 39, Issue 6
The importance of phase in the radical-initiated oxidation of model organic aerosols: reactions of solid and liquid brassidic acid particles
journal, January 2009
- Renbaum, Lindsay H.; Smith, Geoffrey D.
- Physical Chemistry Chemical Physics, Vol. 11, Issue 14
On the competition among aerosol number, size and composition in predicting CCN variability: a multi-annual field study in an urbanized desert
journal, January 2015
- Crosbie, E.; Youn, J. -S.; Balch, B.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 12
The density of humic acids and humic like substances (HULIS) from fresh and aged wood burning and pollution aerosol particles
journal, January 2006
- Dinar, E.; Mentel, T. F.; Rudich, Y.
- Atmospheric Chemistry and Physics, Vol. 6, Issue 12
Kinetic multi-layer model of gas-particle interactions in aerosols and clouds (KM-GAP): linking condensation, evaporation and chemical reactions of organics, oxidants and water
journal, January 2012
- Shiraiwa, M.; Pfrang, C.; Koop, T.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 5
Atmospheric Processes and Their Controlling Influence on Cloud Condensation Nuclei Activity
journal, February 2015
- Farmer, Delphine K.; Cappa, Christopher D.; Kreidenweis, Sonia M.
- Chemical Reviews, Vol. 115, Issue 10
Heterogeneous OH oxidation of biomass burning organic aerosol surrogate compounds: assessment of volatilisation products and the role of OH concentration on the reactive uptake kinetics
journal, January 2013
- Slade, Jonathan H.; Knopf, Daniel A.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 16
Quantifying water diffusion in high-viscosity and glassy aqueous solutions using a Raman isotope tracer method
journal, January 2014
- Price, H. C.; Murray, B. J.; Mattsson, J.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 8
The magnitude and causes of uncertainty in global model simulations of cloud condensation nuclei
journal, January 2013
- Lee, L. A.; Pringle, K. J.; Reddington, C. L.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 17
A statistical description of the evolution of cloud condensation nuclei activity during the heterogeneous oxidation of squalane and bis(2-ethylhexyl) sebacate aerosol by hydroxyl radicals
journal, January 2013
- Harmon, Christopher W.; Ruehl, Christopher R.; Cappa, Christopher D.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 24
Influence of Functional Groups on Organic Aerosol Cloud Condensation Nucleus Activity
journal, August 2014
- Suda, Sarah R.; Petters, Markus D.; Yeh, Geoffrey K.
- Environmental Science & Technology, Vol. 48, Issue 17
Aerosol- and updraft-limited regimes of cloud droplet formation: influence of particle number, size and hygroscopicity on the activation of cloud condensation nuclei (CCN)
journal, January 2009
- Reutter, P.; Su, H.; Trentmann, J.
- Atmospheric Chemistry and Physics, Vol. 9, Issue 18
Smoking Rain Clouds over the Amazon
journal, February 2004
- Andreae, M. O.
- Science, Vol. 303, Issue 5662
Global cloud condensation nuclei influenced by carbonaceous combustion aerosol
journal, January 2011
- Spracklen, D. V.; Carslaw, K. S.; Pöschl, U.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 17
Biomass burning aerosol emissions from vegetation fires: particle number and mass emission factors and size distributions
journal, January 2010
- Janhäll, S.; Andreae, M. O.; Pöschl, U.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 3
Gas uptake and chemical aging of semisolid organic aerosol particles
journal, June 2011
- Shiraiwa, M.; Ammann, M.; Koop, T.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 27
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere
journal, January 2011
- Koop, Thomas; Bookhold, Johannes; Shiraiwa, Manabu
- Physical Chemistry Chemical Physics, Vol. 13, Issue 43
Multiphase Chemistry at the Atmosphere–Biosphere Interface Influencing Climate and Public Health in the Anthropocene
journal, February 2015
- Pöschl, Ulrich; Shiraiwa, Manabu
- Chemical Reviews, Vol. 115, Issue 10
Heterogeneous ice nucleation on particles composed of humic-like substances impacted by O 3
journal, January 2011
- Wang, Bingbing; Knopf, Daniel A.
- Journal of Geophysical Research, Vol. 116, Issue D3
Multiphase Chemical Kinetics of OH Radical Uptake by Molecular Organic Markers of Biomass Burning Aerosols: Humidity and Temperature Dependence, Surface Reaction, and Bulk Diffusion
journal, November 2014
- Arangio, Andrea M.; Slade, Jonathan H.; Berkemeier, Thomas
- The Journal of Physical Chemistry A, Vol. 119, Issue 19
OH-Initiated Heterogeneous Aging of Highly Oxidized Organic Aerosol
journal, February 2012
- Kessler, Sean H.; Nah, Theodora; Daumit, Kelly E.
- The Journal of Physical Chemistry A, Vol. 116, Issue 24
Modification of cloud condensation nucleus activity of organic aerosols by hydroxyl radical heterogeneous oxidation
journal, October 2009
- George, I. J.; Chang, R. Y. -W.; Danov, V.
- Atmospheric Environment, Vol. 43, Issue 32
Chemistry and the Linkages between Air Quality and Climate Change
journal, February 2015
- von Schneidemesser, Erika; Monks, Paul S.; Allan, James D.
- Chemical Reviews, Vol. 115, Issue 10
Global cloud condensation nuclei influenced by carbonaceous combustion aerosol
journal, January 2011
- Spracklen, D. V.; Carslaw, K. S.; Pöschl, U.
- Atmospheric Chemistry and Physics Discussions, Vol. 11, Issue 3
The magnitude and causes of uncertainty in global model simulations of cloud condensation nuclei
journal, January 2013
- Lee, L. A.; Pringle, K. J.; Reddington, C. L.
- Atmospheric Chemistry and Physics Discussions, Vol. 13, Issue 3
Biomass burning aerosol emissions from vegetation fires: particle number and mass emission factors and size distributions
journal, January 2009
- Janhäll, S.; Andreae, M. O.; Pöschl, U.
- Atmospheric Chemistry and Physics Discussions, Vol. 9, Issue 4
On the competition among aerosol number, size and composition in predicting CCN variability: a multi-annual field study in an urbanized desert
journal, February 2015
- Crosbie, E.; Youn, J. -S.; Balch, B.
- Atmospheric Chemistry and Physics Discussions
Rethinking the global secondary organic aerosol (SOA) budget: stronger production, faster removal, shorter lifetime
journal, January 2015
- Hodzic, A.; Kasibhatla, P. S.; Jo, D. S.
- Atmospheric Chemistry and Physics Discussions, Vol. 15, Issue 22
A single parameter representation of hygroscopic growth and cloud condensation nucleus activity
journal, January 2006
- Petters, M. D.; Kreidenweis, S. M.
- Atmospheric Chemistry and Physics Discussions, Vol. 6, Issue 5
Works referencing / citing this record:
Second inflection point of water surface tension in the deeply supercooled regime revealed by entropy anomaly and surface structure using molecular dynamics simulations
journal, January 2019
- Wang, Xiaoxiang; Binder, Kurt; Chen, Chuchu
- Physical Chemistry Chemical Physics, Vol. 21, Issue 6
Compositional evolution of particle-phase reaction products and water in the heterogeneous OH oxidation of model aqueous organic aerosols
journal, January 2017
- Chim, Man Mei; Cheng, Chiu Tung; Davies, James F.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 23
Influence of relative humidity on the heterogeneous oxidation of secondary organic aerosol
journal, January 2018
- Li, Ziyue; Smith, Katherine A.; Cappa, Christopher D.
- Atmospheric Chemistry and Physics, Vol. 18, Issue 19
Isotopic constraints on the atmospheric sources and formation of nitrogenous species in clouds influenced by biomass burning
journal, January 2019
- Chang, Yunhua; Zhang, Yan-Lin; Li, Jiarong
- Atmospheric Chemistry and Physics, Vol. 19, Issue 19
Photomineralization mechanism changes the ability of dissolved organic matter to activate cloud droplets and to nucleate ice crystals
journal, January 2019
- Borduas-Dedekind, Nadine; Ossola, Rachele; David, Robert O.
- Atmospheric Chemistry and Physics, Vol. 19, Issue 19
Effects of inorganic salts on the heterogeneous OH oxidation of organic compounds: insights from methylglutaric acid–ammonium sulfate
journal, January 2019
- Lam, Hoi Ki; Shum, Sze Man; Davies, James F.
- Atmospheric Chemistry and Physics, Vol. 19, Issue 14