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Title: Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys

Abstract

The concept of high entropy alloy (HEA) opens a vast unexplored composition range for alloy design. As a well-studied system, Al-Co-Cr-Fe-Ni has attracted tremendous amount of attention to develop new-generation low-density structural materials for automobile and aerospace applications. In spite of intensive investigations in the past few years, the phase stability within this HEA system is still poorly understood and needs to be clarified, which poses obstacles to the discovery of promising Al-Co-Cr-Fe-Ni HEAs. In the present work, the CALPHAD approach is employed to understand the phase stability and explore the phase transformation within the Al-Co-Cr-Fe-Ni system. As a result, the phase-stability mapping coupled with density contours is then constructed within the composition - temperature space, which provides useful guidelines for the design of low-density Al-Co-Cr-Fe-Ni HEAs with desirable properties.

Authors:
 [1];  [1];  [2];  [3];  [2];  [4];  [2]
  1. CompuTherm LLC, Middleton, WI (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States)
  3. National Energy Technology Lab. (NETL), Albany, OR (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1287040
Alternate Identifier(s):
OSTI ID: 1359529
Grant/Contract Number:  
AC05-00OR22725; FE-0008855; FE-0024054
Resource Type:
Accepted Manuscript
Journal Name:
Materials & Design
Additional Journal Information:
Journal Volume: 109; Journal Issue: C; Journal ID: ISSN 0264-1275
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; high-entropy alloy; phase stability; CALPHAD; phase diagram; atom probe tomography (APT)

Citation Formats

Zhang, Chuan, Zhang, Fan, Diao, Haoyan, Gao, Michael C., Tang, Zhi, Poplawsky, Jonathan D., and Liaw, Peter K. Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys. United States: N. p., 2016. Web. doi:10.1016/j.matdes.2016.07.073.
Zhang, Chuan, Zhang, Fan, Diao, Haoyan, Gao, Michael C., Tang, Zhi, Poplawsky, Jonathan D., & Liaw, Peter K. Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys. United States. doi:10.1016/j.matdes.2016.07.073.
Zhang, Chuan, Zhang, Fan, Diao, Haoyan, Gao, Michael C., Tang, Zhi, Poplawsky, Jonathan D., and Liaw, Peter K. Tue . "Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys". United States. doi:10.1016/j.matdes.2016.07.073. https://www.osti.gov/servlets/purl/1287040.
@article{osti_1287040,
title = {Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys},
author = {Zhang, Chuan and Zhang, Fan and Diao, Haoyan and Gao, Michael C. and Tang, Zhi and Poplawsky, Jonathan D. and Liaw, Peter K.},
abstractNote = {The concept of high entropy alloy (HEA) opens a vast unexplored composition range for alloy design. As a well-studied system, Al-Co-Cr-Fe-Ni has attracted tremendous amount of attention to develop new-generation low-density structural materials for automobile and aerospace applications. In spite of intensive investigations in the past few years, the phase stability within this HEA system is still poorly understood and needs to be clarified, which poses obstacles to the discovery of promising Al-Co-Cr-Fe-Ni HEAs. In the present work, the CALPHAD approach is employed to understand the phase stability and explore the phase transformation within the Al-Co-Cr-Fe-Ni system. As a result, the phase-stability mapping coupled with density contours is then constructed within the composition - temperature space, which provides useful guidelines for the design of low-density Al-Co-Cr-Fe-Ni HEAs with desirable properties.},
doi = {10.1016/j.matdes.2016.07.073},
journal = {Materials & Design},
number = C,
volume = 109,
place = {United States},
year = {2016},
month = {7}
}

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Works referencing / citing this record:

Effects of Mn and Al addition on structural and magnetic properties of FeCoNi-based high entropy alloys
journal, August 2018


High-Entropy Alloys: Potential Candidates for High-Temperature Applications - An Overview
journal, October 2017

  • Praveen, Sathiyamoorthi; Kim, Hyoung Seop
  • Advanced Engineering Materials, Vol. 20, Issue 1
  • DOI: 10.1002/adem.201700645

Effects of Mn and Al addition on structural and magnetic properties of FeCoNi-based high entropy alloys
journal, August 2018