DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys

Abstract

The concept of high entropy alloy (HEA) opens a vast unexplored composition range for alloy design. As a well-studied system, Al-Co-Cr-Fe-Ni has attracted tremendous amount of attention to develop new-generation low-density structural materials for automobile and aerospace applications. In spite of intensive investigations in the past few years, the phase stability within this HEA system is still poorly understood and needs to be clarified, which poses obstacles to the discovery of promising Al-Co-Cr-Fe-Ni HEAs. In the present work, the CALPHAD approach is employed to understand the phase stability and explore the phase transformation within the Al-Co-Cr-Fe-Ni system. As a result, the phase-stability mapping coupled with density contours is then constructed within the composition - temperature space, which provides useful guidelines for the design of low-density Al-Co-Cr-Fe-Ni HEAs with desirable properties.

Authors:
 [1];  [1];  [2];  [3];  [2];  [4];  [2]
  1. CompuTherm LLC, Middleton, WI (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States)
  3. National Energy Technology Lab. (NETL), Albany, OR (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1287040
Alternate Identifier(s):
OSTI ID: 1359529
Grant/Contract Number:  
AC05-00OR22725; FE-0008855; FE-0024054
Resource Type:
Accepted Manuscript
Journal Name:
Materials & Design
Additional Journal Information:
Journal Volume: 109; Journal Issue: C; Journal ID: ISSN 0264-1275
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; high-entropy alloy; phase stability; CALPHAD; phase diagram; atom probe tomography (APT)

Citation Formats

Zhang, Chuan, Zhang, Fan, Diao, Haoyan, Gao, Michael C., Tang, Zhi, Poplawsky, Jonathan D., and Liaw, Peter K. Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys. United States: N. p., 2016. Web. doi:10.1016/j.matdes.2016.07.073.
Zhang, Chuan, Zhang, Fan, Diao, Haoyan, Gao, Michael C., Tang, Zhi, Poplawsky, Jonathan D., & Liaw, Peter K. Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys. United States. https://doi.org/10.1016/j.matdes.2016.07.073
Zhang, Chuan, Zhang, Fan, Diao, Haoyan, Gao, Michael C., Tang, Zhi, Poplawsky, Jonathan D., and Liaw, Peter K. Tue . "Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys". United States. https://doi.org/10.1016/j.matdes.2016.07.073. https://www.osti.gov/servlets/purl/1287040.
@article{osti_1287040,
title = {Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys},
author = {Zhang, Chuan and Zhang, Fan and Diao, Haoyan and Gao, Michael C. and Tang, Zhi and Poplawsky, Jonathan D. and Liaw, Peter K.},
abstractNote = {The concept of high entropy alloy (HEA) opens a vast unexplored composition range for alloy design. As a well-studied system, Al-Co-Cr-Fe-Ni has attracted tremendous amount of attention to develop new-generation low-density structural materials for automobile and aerospace applications. In spite of intensive investigations in the past few years, the phase stability within this HEA system is still poorly understood and needs to be clarified, which poses obstacles to the discovery of promising Al-Co-Cr-Fe-Ni HEAs. In the present work, the CALPHAD approach is employed to understand the phase stability and explore the phase transformation within the Al-Co-Cr-Fe-Ni system. As a result, the phase-stability mapping coupled with density contours is then constructed within the composition - temperature space, which provides useful guidelines for the design of low-density Al-Co-Cr-Fe-Ni HEAs with desirable properties.},
doi = {10.1016/j.matdes.2016.07.073},
journal = {Materials & Design},
number = C,
volume = 109,
place = {United States},
year = {Tue Jul 19 00:00:00 EDT 2016},
month = {Tue Jul 19 00:00:00 EDT 2016}
}

Journal Article:

Citation Metrics:
Cited by: 171 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004

  • Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
  • Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
  • DOI: 10.1002/adem.200300567

Microstructure and mechanical property of as-cast, -homogenized, and -deformed AlxCoCrFeNi (0≤x≤2) high-entropy alloys
journal, November 2009


Microstructure, thermophysical and electrical properties in AlxCoCrFeNi (0≤x≤2) high-entropy alloys
journal, July 2009

  • Chou, Hsuan-Ping; Chang, Yee-Shyi; Chen, Swe-Kai
  • Materials Science and Engineering: B, Vol. 163, Issue 3
  • DOI: 10.1016/j.mseb.2009.05.024

Microstructure and tensile behaviors of FCC Al0.3CoCrFeNi high entropy alloy
journal, June 2009


Cooling Rate and Size Effect on the Microstructure and Mechanical Properties of AlCoCrFeNi High Entropy Alloy
journal, May 2009

  • Wang, F. J.; Zhang, Y.; Chen, G. L.
  • Journal of Engineering Materials and Technology, Vol. 131, Issue 3
  • DOI: 10.1115/1.3120387

Evolution of microstructure, hardness, and corrosion properties of high-entropy Al0.5CoCrFeNi alloy
journal, March 2011


Electrical, magnetic, and Hall properties of AlxCoCrFeNi high-entropy alloys
journal, February 2011


Alloying behavior, microstructure and mechanical properties in a FeNiCrCo0.3Al0.7 high entropy alloy
journal, October 2013


Phases, microstructure and mechanical properties of AlxCoCrFeNi high-entropy alloys at elevated temperatures
journal, March 2014


Comparative study of the microstructures and mechanical properties of direct laser fabricated and arc-melted Al x CoCrFeNi high entropy alloys
journal, May 2015


Effect of Al/Ni ratio, heat treatment on phase transformations and microstructure of AlxFeCoCrNi2−x (x=0.3, 1) high entropy alloys
journal, September 2015


Effects of AL addition on microstructure and mechanical properties of AlxCoCrFeNi High-entropy alloy
journal, November 2015


Microstructure and mechanical properties of Al20−xCr20+0.5xFe20Co20Ni20+0.5x high entropy alloys
journal, February 2016


Relative crystal stability of AlxFeNiCrCo high entropy alloys from XRD analysis and formation energy calculation
journal, November 2015


The influence of Al elements on the structure and the creep behavior of Al x CoCrFeNi high entropy alloys
journal, February 2016


Aluminum Alloying Effects on Lattice Types, Microstructures, and Mechanical Behavior of High-Entropy Alloys Systems
journal, October 2013


High strain-rate compressive deformation behavior of the Al0.1CrFeCoNi high entropy alloy
journal, December 2015


The effect of grain size on the annealing-induced phase transformation in an Al0·3CoCrFeNi high entropy alloy
journal, September 2016


Irradiation Resistance in Al x CoCrFeNi High Entropy Alloys
journal, August 2015


Phase diagram calculation: past, present and future
journal, January 2004


Phase diagram calculations in teaching, research, and industry
journal, February 2006


Computational Thermodynamics Aided High-Entropy Alloy Design
journal, June 2012


Searching for Next Single-Phase High-Entropy Alloy Compositions
journal, October 2013


Exploration and Development of High Entropy Alloys for Structural Applications
journal, January 2014

  • Miracle, Daniel; Miller, Jonathan; Senkov, Oleg
  • Entropy, Vol. 16, Issue 1
  • DOI: 10.3390/e16010494

An understanding of high entropy alloys from phase diagram calculations
journal, June 2014


Phase stability of non-equiatomic CoCrFeMnNi high entropy alloys
journal, October 2015


Tensile ductility of an AlCoCrFeNi multi-phase high-entropy alloy through hot isostatic pressing (HIP) and homogenization
journal, October 2015


Deviation from high-entropy configurations in the atomic distributions of a multi-principal-element alloy
journal, January 2015

  • Santodonato, Louis J.; Zhang, Yang; Feygenson, Mikhail
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms6964

Assessments of molar volume and thermal expansion for selected bcc, fcc and hcp metallic elements
journal, March 2005


Algebraic Representation of Thermodynamic Properties and the Classification of Solutions
journal, February 1948

  • Redlich, Otto; Kister, A. T.
  • Industrial & Engineering Chemistry, Vol. 40, Issue 2
  • DOI: 10.1021/ie50458a036

Works referencing / citing this record:

Effects of Mn and Al addition on structural and magnetic properties of FeCoNi-based high entropy alloys
journal, August 2018


Science and technology in high-entropy alloys
journal, January 2018


Design of Light-Weight High-Entropy Alloys
journal, September 2016

  • Feng, Rui; Gao, Michael; Lee, Chanho
  • Entropy, Vol. 18, Issue 9
  • DOI: 10.3390/e18090333

A Novel Low-Activation VCrFeTaxWx (x = 0.1, 0.2, 0.3, 0.4, and 1) High-Entropy Alloys with Excellent Heat-Softening Resistance
journal, December 2018

  • Zhang, Weiran; Liaw, Peter; Zhang, Yong
  • Entropy, Vol. 20, Issue 12
  • DOI: 10.3390/e20120951

Microstructures and properties of high-entropy alloy films and coatings: a review
journal, February 2018


A cobalt-rich eutectic high-entropy alloy in the system Al–Co–Cr–Fe–Ni
journal, October 2019


Corrosion-Resistant High-Entropy Alloys: A Review
journal, February 2017


High-Entropy Alloys: Potential Candidates for High-Temperature Applications - An Overview
journal, October 2017

  • Praveen, Sathiyamoorthi; Kim, Hyoung Seop
  • Advanced Engineering Materials, Vol. 20, Issue 1
  • DOI: 10.1002/adem.201700645

Effect of Cold Rolling on the Phase Transformation Kinetics of an Al0.5CoCrFeNi High-Entropy Alloy
journal, November 2018

  • Wang, Jun; Yang, Haoxue; Guo, Tong
  • Entropy, Vol. 20, Issue 12
  • DOI: 10.3390/e20120917

Predictive multiphase evolution in Al-containing high-entropy alloys
journal, October 2018