Current Thoughts on Reactive Element Effects in Alumina-Forming Systems: In Memory of John Stringer
Abstract
In memory of John Stringer (1934–2014), one of the leaders in studying the reactive element (RE) effects, this paper reviews the current status of understanding of the effect of RE dopants on high-temperature oxidation behavior, with an emphasis on recent research related to deploying alumina-forming alloys and coatings with optimal performance in commercial systems. Additionally, to the well-known interaction between indigenous sulfur and RE additions, effects have been observed with C, N, and O found in commercial alloys and coatings. While there are many similarities between alumina-forming alloys and coatings, the latter bring additional complicating factors such as the effects of O incorporation during thermal spraying MCrAlY coatings, coating roughness, and heat treatments that must be considered in optimizing the beneficial dopant addition. We can see analogies between RE effects in alloys and in the substrates beneath diffusion M–Al coatings. Recently, there has been more interest in the influence of mixed oxidant environments, since these may modify the manifestation of the RE effect. Some thoughts are provided on optimizing the RE benefit and modeling oxidation of RE-doped alloys.
- Authors:
-
- Julich Research Centre (Germany)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office
- OSTI Identifier:
- 1279402
- Grant/Contract Number:
- AC05-00OR22725; NA 615-2
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Oxidation of Metals
- Additional Journal Information:
- Journal Volume: 86; Journal Issue: 1-2; Journal ID: ISSN 0030-770X
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Reactive element effect; alumina forming alloys; coatings; thermal barrier coatings; review; effect of C, N, and O impurities
Citation Formats
Naumenko, D., Pint, B. A., and Quadakkers, W. J. Current Thoughts on Reactive Element Effects in Alumina-Forming Systems: In Memory of John Stringer. United States: N. p., 2016.
Web. doi:10.1007/s11085-016-9625-0.
Naumenko, D., Pint, B. A., & Quadakkers, W. J. Current Thoughts on Reactive Element Effects in Alumina-Forming Systems: In Memory of John Stringer. United States. https://doi.org/10.1007/s11085-016-9625-0
Naumenko, D., Pint, B. A., and Quadakkers, W. J. Fri .
"Current Thoughts on Reactive Element Effects in Alumina-Forming Systems: In Memory of John Stringer". United States. https://doi.org/10.1007/s11085-016-9625-0. https://www.osti.gov/servlets/purl/1279402.
@article{osti_1279402,
title = {Current Thoughts on Reactive Element Effects in Alumina-Forming Systems: In Memory of John Stringer},
author = {Naumenko, D. and Pint, B. A. and Quadakkers, W. J.},
abstractNote = {In memory of John Stringer (1934–2014), one of the leaders in studying the reactive element (RE) effects, this paper reviews the current status of understanding of the effect of RE dopants on high-temperature oxidation behavior, with an emphasis on recent research related to deploying alumina-forming alloys and coatings with optimal performance in commercial systems. Additionally, to the well-known interaction between indigenous sulfur and RE additions, effects have been observed with C, N, and O found in commercial alloys and coatings. While there are many similarities between alumina-forming alloys and coatings, the latter bring additional complicating factors such as the effects of O incorporation during thermal spraying MCrAlY coatings, coating roughness, and heat treatments that must be considered in optimizing the beneficial dopant addition. We can see analogies between RE effects in alloys and in the substrates beneath diffusion M–Al coatings. Recently, there has been more interest in the influence of mixed oxidant environments, since these may modify the manifestation of the RE effect. Some thoughts are provided on optimizing the RE benefit and modeling oxidation of RE-doped alloys.},
doi = {10.1007/s11085-016-9625-0},
journal = {Oxidation of Metals},
number = 1-2,
volume = 86,
place = {United States},
year = {Fri May 06 00:00:00 EDT 2016},
month = {Fri May 06 00:00:00 EDT 2016}
}
Web of Science
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