Ab initio optimization of phonon drag effect for lower-temperature thermoelectric energy conversion
Abstract
Although the thermoelectric figure of merit zT above 300 K has seen significant improvement recently, the progress at lower temperatures has been slow, mainly limited by the relatively low Seebeck coefficient and high thermal conductivity. We report, for the first time to our knowledge, success in first-principles computation of the phonon drag effect—a coupling phenomenon between electrons and nonequilibrium phonons—in heavily doped region and its optimization to enhance the Seebeck coefficient while reducing the phonon thermal conductivity by nanostructuring. Our simulation quantitatively identifies the major phonons contributing to the phonon drag, which are spectrally distinct from those carrying heat, and further reveals that although the phonon drag is reduced in heavily doped samples, a significant contribution to Seebeck coefficient still exists. An ideal phonon filter is proposed to enhance zT of silicon at room temperature by a factor of 20 to ~0.25, and the enhancement can reach 70 times at 100 K. This work opens up a new venue toward better thermoelectrics by harnessing nonequilibrium phonons.
- Authors:
-
- Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139,
- Department of Mechanical and Aerospace Engineering, Rutgers University, Piscataway, NJ 08854,, Institute for Advanced Materials, Devices and Nanotechnology, Rutgers University, Piscataway, NJ 08854,
- Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, MA 02139,, Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
- Publication Date:
- Research Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Energy Frontier Research Centers (EFRC) (United States). Solid-State Solar-Thermal Energy Conversion Center (S3TEC)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1235174
- Alternate Identifier(s):
- OSTI ID: 1370969
- Grant/Contract Number:
- SC0001299/DE-FG02-09ER46577; SC0001299; FG02-09ER46577
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 112 Journal Issue: 48; Journal ID: ISSN 0027-8424
- Publisher:
- Proceedings of the National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; phonon drag; nonequilibrium phonon; electron phonon interaction; thermoelectrics; nanocluster scattering
Citation Formats
Zhou, Jiawei, Liao, Bolin, Qiu, Bo, Huberman, Samuel, Esfarjani, Keivan, Dresselhaus, Mildred S., and Chen, Gang. Ab initio optimization of phonon drag effect for lower-temperature thermoelectric energy conversion. United States: N. p., 2015.
Web. doi:10.1073/pnas.1512328112.
Zhou, Jiawei, Liao, Bolin, Qiu, Bo, Huberman, Samuel, Esfarjani, Keivan, Dresselhaus, Mildred S., & Chen, Gang. Ab initio optimization of phonon drag effect for lower-temperature thermoelectric energy conversion. United States. https://doi.org/10.1073/pnas.1512328112
Zhou, Jiawei, Liao, Bolin, Qiu, Bo, Huberman, Samuel, Esfarjani, Keivan, Dresselhaus, Mildred S., and Chen, Gang. Mon .
"Ab initio optimization of phonon drag effect for lower-temperature thermoelectric energy conversion". United States. https://doi.org/10.1073/pnas.1512328112.
@article{osti_1235174,
title = {Ab initio optimization of phonon drag effect for lower-temperature thermoelectric energy conversion},
author = {Zhou, Jiawei and Liao, Bolin and Qiu, Bo and Huberman, Samuel and Esfarjani, Keivan and Dresselhaus, Mildred S. and Chen, Gang},
abstractNote = {Although the thermoelectric figure of merit zT above 300 K has seen significant improvement recently, the progress at lower temperatures has been slow, mainly limited by the relatively low Seebeck coefficient and high thermal conductivity. We report, for the first time to our knowledge, success in first-principles computation of the phonon drag effect—a coupling phenomenon between electrons and nonequilibrium phonons—in heavily doped region and its optimization to enhance the Seebeck coefficient while reducing the phonon thermal conductivity by nanostructuring. Our simulation quantitatively identifies the major phonons contributing to the phonon drag, which are spectrally distinct from those carrying heat, and further reveals that although the phonon drag is reduced in heavily doped samples, a significant contribution to Seebeck coefficient still exists. An ideal phonon filter is proposed to enhance zT of silicon at room temperature by a factor of 20 to ~0.25, and the enhancement can reach 70 times at 100 K. This work opens up a new venue toward better thermoelectrics by harnessing nonequilibrium phonons.},
doi = {10.1073/pnas.1512328112},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 48,
volume = 112,
place = {United States},
year = {Mon Nov 16 00:00:00 EST 2015},
month = {Mon Nov 16 00:00:00 EST 2015}
}
https://doi.org/10.1073/pnas.1512328112
Web of Science
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