Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries
Abstract
As sensors, wireless communication devices, personal health monitoring systems, and autonomous microelectromechanical systems (MEMS) become distributed and smaller, there is an increasing demand for miniaturized integrated power sources. Although thin-film batteries are well-suited for on-chip integration, their energy and power per unit area are limited. Three-dimensional electrode designs have potential to offer much greater power and energy per unit area; however, efforts to date to realize 3D microbatteries have led to prototypes with solid electrodes (and therefore low power) or mesostructured electrodes not compatible with manufacturing or on-chip integration. Here in this paper, we demonstrate an on-chip compatible method to fabricate high energy density (6.5 μWh cm-2∙μm-1) 3D mesostructured Li-ion microbatteries based on LiMnO2 cathodes, and NiSn anodes that possess supercapacitor-like power (3,600 μW cm(-2)∙μm(-1) peak). The mesostructured electrodes are fabricated by combining 3D holographic lithography with conventional photolithography, enabling deterministic control of both the internal electrode mesostructure and the spatial distribution of the electrodes on the substrate. The resultant full cells exhibit impressive performances, for example a conventional light-emitting diode (LED) is driven with a 500-μA peak current (600-C discharge) from a 10-μm-thick microbattery with an area of 4 mm2 for 200 cycles with only 12% capacity fade. Lastly,more »
- Authors:
-
- Department of Materials Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, IL 61801, and
- Department of Mechanical Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, IL 61801
- Department of Materials Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, IL 61801, and, Department of Mechanical Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, IL 61801
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC). Light-Material Interactions in Energy Conversion (LMI); Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
- Contributing Org.:
- LMI partners with California Institute of Technology (lead); Harvard University; University of Illinois, Urbana-Champaign; Lawrence Berkeley National Laboratory
- OSTI Identifier:
- 1235169
- Alternate Identifier(s):
- OSTI ID: 1210625; OSTI ID: 1875500
- Grant/Contract Number:
- FG02-07ER46471; SC0001293
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 112 Journal Issue: 21; Journal ID: ISSN 0027-8424
- Publisher:
- Proceedings of the National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; solar (photovoltaic); solid state lighting; phonons; thermal conductivity, electrodes - solar; synthesis (self-assembly); synthesis (novel materials); optics; materials and chemistry by design; energy storage; interference lithography; lithium-ion batteries; microelectronics; miniature batteries
Citation Formats
Ning, Hailong, Pikul, James H., Zhang, Runyu, Li, Xuejiao, Xu, Sheng, Wang, Junjie, Rogers, John A., King, William P., and Braun, Paul V. Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries. United States: N. p., 2015.
Web. doi:10.1073/pnas.1423889112.
Ning, Hailong, Pikul, James H., Zhang, Runyu, Li, Xuejiao, Xu, Sheng, Wang, Junjie, Rogers, John A., King, William P., & Braun, Paul V. Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries. United States. https://doi.org/10.1073/pnas.1423889112
Ning, Hailong, Pikul, James H., Zhang, Runyu, Li, Xuejiao, Xu, Sheng, Wang, Junjie, Rogers, John A., King, William P., and Braun, Paul V. Mon .
"Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries". United States. https://doi.org/10.1073/pnas.1423889112.
@article{osti_1235169,
title = {Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries},
author = {Ning, Hailong and Pikul, James H. and Zhang, Runyu and Li, Xuejiao and Xu, Sheng and Wang, Junjie and Rogers, John A. and King, William P. and Braun, Paul V.},
abstractNote = {As sensors, wireless communication devices, personal health monitoring systems, and autonomous microelectromechanical systems (MEMS) become distributed and smaller, there is an increasing demand for miniaturized integrated power sources. Although thin-film batteries are well-suited for on-chip integration, their energy and power per unit area are limited. Three-dimensional electrode designs have potential to offer much greater power and energy per unit area; however, efforts to date to realize 3D microbatteries have led to prototypes with solid electrodes (and therefore low power) or mesostructured electrodes not compatible with manufacturing or on-chip integration. Here in this paper, we demonstrate an on-chip compatible method to fabricate high energy density (6.5 μWh cm-2∙μm-1) 3D mesostructured Li-ion microbatteries based on LiMnO2 cathodes, and NiSn anodes that possess supercapacitor-like power (3,600 μW cm(-2)∙μm(-1) peak). The mesostructured electrodes are fabricated by combining 3D holographic lithography with conventional photolithography, enabling deterministic control of both the internal electrode mesostructure and the spatial distribution of the electrodes on the substrate. The resultant full cells exhibit impressive performances, for example a conventional light-emitting diode (LED) is driven with a 500-μA peak current (600-C discharge) from a 10-μm-thick microbattery with an area of 4 mm2 for 200 cycles with only 12% capacity fade. Lastly, a combined experimental and modeling study where the structural parameters of the battery are modulated illustrates the unique design flexibility enabled by 3D holographic lithography and provides guidance for optimization for a given application.},
doi = {10.1073/pnas.1423889112},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 21,
volume = 112,
place = {United States},
year = {Mon May 11 00:00:00 EDT 2015},
month = {Mon May 11 00:00:00 EDT 2015}
}
https://doi.org/10.1073/pnas.1423889112
Web of Science
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