Resonant tunnelling in a quantum oxide superlattice
Abstract
Resonant tunneling is a quantum mechanical process that has long been attracting both scientific and technological attention owing to its intriguing underlying physics and unique applications for high-speed electronics. The materials system exhibiting resonant tunneling, however, has been largely limited to the conventional semiconductors, partially due to their excellent crystalline quality. Here we show that a deliberately designed transition metal oxide superlattice exhibits a resonant tunneling behaviour with a clear negative differential resistance. The tunneling occurred through an atomically thin, lanthanum δ- doped SrTiO3 layer, and the negative differential resistance was realized on top of the bi-polar resistance switching typically observed for perovskite oxide junctions. This combined process resulted in an extremely large resistance ratio (~105) between the high and low resistance states. Lastly, the unprecedentedly large control found in atomically thin δ-doped oxide superlattices can open a door to novel oxide-based high-frequency logic devices.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Sungkyunkwan Univ., Suwon (Republic of Korea). Dept. of Physics
- Sungkyunkwan Univ., Suwon (Republic of Korea). Dept. of Physics; Sungkyunkwan Univ., Suwon (Republic of Korea). Institute of Basic Science
- Southern Methodist Univ., Dallas, TX (United States). Department of Mechanical Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Korea Inst. of Science and Technology, Seoul (Korea)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1190747
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Choi, Woo Seok, Lee, Sang A., You, Jeong Ho, Lee, Suyoun, and Lee, Ho Nyung. Resonant tunnelling in a quantum oxide superlattice. United States: N. p., 2015.
Web. doi:10.1038/ncomms8424.
Choi, Woo Seok, Lee, Sang A., You, Jeong Ho, Lee, Suyoun, & Lee, Ho Nyung. Resonant tunnelling in a quantum oxide superlattice. United States. https://doi.org/10.1038/ncomms8424
Choi, Woo Seok, Lee, Sang A., You, Jeong Ho, Lee, Suyoun, and Lee, Ho Nyung. Wed .
"Resonant tunnelling in a quantum oxide superlattice". United States. https://doi.org/10.1038/ncomms8424. https://www.osti.gov/servlets/purl/1190747.
@article{osti_1190747,
title = {Resonant tunnelling in a quantum oxide superlattice},
author = {Choi, Woo Seok and Lee, Sang A. and You, Jeong Ho and Lee, Suyoun and Lee, Ho Nyung},
abstractNote = {Resonant tunneling is a quantum mechanical process that has long been attracting both scientific and technological attention owing to its intriguing underlying physics and unique applications for high-speed electronics. The materials system exhibiting resonant tunneling, however, has been largely limited to the conventional semiconductors, partially due to their excellent crystalline quality. Here we show that a deliberately designed transition metal oxide superlattice exhibits a resonant tunneling behaviour with a clear negative differential resistance. The tunneling occurred through an atomically thin, lanthanum δ- doped SrTiO3 layer, and the negative differential resistance was realized on top of the bi-polar resistance switching typically observed for perovskite oxide junctions. This combined process resulted in an extremely large resistance ratio (~105) between the high and low resistance states. Lastly, the unprecedentedly large control found in atomically thin δ-doped oxide superlattices can open a door to novel oxide-based high-frequency logic devices.},
doi = {10.1038/ncomms8424},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {Wed Jun 24 00:00:00 EDT 2015},
month = {Wed Jun 24 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Resonant tunneling in semiconductor double barriers
journal, June 1974
- Chang, L. L.; Esaki, L.; Tsu, R.
- Applied Physics Letters, Vol. 24, Issue 12
Quantum States of Confined Carriers in Very Thin -GaAs- Heterostructures
journal, September 1974
- Dingle, R.; Wiegmann, W.; Henry, C. H.
- Physical Review Letters, Vol. 33, Issue 14
Resonant tunneling diodes: models and properties
journal, April 1998
- Sun, Jian Ping; Haddad, G. I.; Mazumder, P.
- Proceedings of the IEEE, Vol. 86, Issue 4, p. 641-660
Resonant tunneling characteristics in SiO2/Si double-barrier structures in a wide range of applied voltage
journal, August 2003
- Ikeda, Hiroya; Iwasaki, Masanori; Ishikawa, Yasuhiko
- Applied Physics Letters, Vol. 83, Issue 7
Transport processes via localized states in thin a -Si tunnel barriers
journal, July 1985
- Bending, S. J.; Beasley, M. R.
- Physical Review Letters, Vol. 55, Issue 3
Strong polarization enhancement in asymmetric three-component ferroelectric superlattices
journal, January 2005
- Lee, Ho Nyung; Christen, Hans M.; Chisholm, Matthew F.
- Nature, Vol. 433, Issue 7024
Exploiting dimensionality and defect mitigation to create tunable microwave dielectrics
journal, October 2013
- Lee, Che-Hui; Orloff, Nathan D.; Birol, Turan
- Nature, Vol. 502, Issue 7472
Fractionally δ-Doped Oxide Superlattices for Higher Carrier Mobilities
journal, January 2012
- Choi, Woo Seok; Lee, Suyoun; Cooper, Valentino R.
- Nano Letters, Vol. 12, Issue 9
Theory of Tunneling Spectroscopy of -Wave Superconductors
journal, April 1995
- Tanaka, Yukio; Kashiwaya, Satoshi
- Physical Review Letters, Vol. 74, Issue 17
Spin-Polarized Intergrain Tunneling in
journal, September 1996
- Hwang, H. Y.; Cheong, S-W.; Ong, N. P.
- Physical Review Letters, Vol. 77, Issue 10
Role of Metal-Oxide Interface in Determining the Spin Polarization of Magnetic Tunnel Junctions
journal, October 1999
- De Teresa, Jose Maria; Barthélémy, Agnès; Fert, Albert
- Science, Vol. 286, Issue 5439
APPLIED PHYSICS: Tunneling Across a Ferroelectric
journal, July 2006
- Tsymbal, E. Y.
- Science, Vol. 313, Issue 5784
Tunneling Electroresistance Induced by Interfacial Phase Transitions in Ultrathin Oxide Heterostructures
journal, November 2013
- Jiang, Lu; Choi, Woo Seok; Jeen, Hyoungjeen
- Nano Letters, Vol. 13, Issue 12
Tunnel junctions with multiferroic barriers
journal, March 2007
- Gajek, Martin; Bibes, Manuel; Fusil, Stéphane
- Nature Materials, Vol. 6, Issue 4
Origin of Negative Differential Resistance Observed on Bipolar Resistance Switching Device with Ti/Pr 0.7 Ca 0.3 MnO 3 /Pt Structure
journal, April 2008
- Shono, Keiji; Kawano, Hiroyasu; Yokota, Takeshi
- Applied Physics Express, Vol. 1
Negative differential resistance induced by Mn substitution at Schottky interfaces
journal, May 2008
- Hikita, Yasuyuki; Kourkoutis, Lena Fitting; Susaki, Tomofumi
- Physical Review B, Vol. 77, Issue 20
Negative differential resistance in La0.67Ca0.33MnO3−δ∕Nb–SrTiO3 p-n junction
journal, January 2007
- Xiao, Y. S.; Zhang, X. P.; Zhao, Y. G.
- Applied Physics Letters, Vol. 90, Issue 1
Symmetrical Negative Differential Resistance Behavior of a Resistive Switching Device
journal, February 2012
- Du, Yuanmin; Pan, Hui; Wang, Shijie
- ACS Nano, Vol. 6, Issue 3
Nanoionics-based resistive switching memories
journal, November 2007
- Waser, Rainer; Aono, Masakazu
- Nature Materials, Vol. 6, Issue 11, p. 833-840
Resistive switching in transition metal oxides
journal, June 2008
- Sawa, Akihito
- Materials Today, Vol. 11, Issue 6
Memristive devices for computing
journal, January 2013
- Yang, J. Joshua; Strukov, Dmitri B.; Stewart, Duncan R.
- Nature Nanotechnology, Vol. 8, Issue 1, p. 13-24
Atomic Layer Engineering of Perovskite Oxides for Chemically Sharp Heterointerfaces
journal, October 2012
- Choi, Woo Seok; Rouleau, Christopher M.; Seo, Sung Seok A.
- Advanced Materials, Vol. 24, Issue 48
Artificial charge-modulationin atomic-scale perovskite titanate superlattices
journal, September 2002
- Ohtomo, A.; Muller, D. A.; Grazul, J. L.
- Nature, Vol. 419, Issue 6905
Optical Study of the Free-Carrier Response of Superlattices
journal, December 2007
- Seo, S. S. A.; Choi, W. S.; Lee, H. N.
- Physical Review Letters, Vol. 99, Issue 26
Nonlinear Hall effect and multichannel conduction in superlattices
journal, November 2010
- Kim, J. S.; Seo, S. S. A.; Chisholm, M. F.
- Physical Review B, Vol. 82, Issue 20
Transparent conducting oxides: A δ-doped superlattice approach
journal, August 2014
- Cooper, Valentino R.; Seo, Sung S. Ambrose; Lee, Suyoun
- Scientific Reports, Vol. 4, Issue 1
Transport properties of LaTiO3/SrTiO3 heterostructures
journal, May 2010
- Ohtsuka, R.; Matvejeff, M.; Nishio, K.
- Applied Physics Letters, Vol. 96, Issue 19
Two-dimensional superconductivity at a Mott insulator/band insulator interface LaTiO3/SrTiO3
journal, October 2010
- Biscaras, J.; Bergeal, N.; Kushwaha, A.
- Nature Communications, Vol. 1, Issue 1
Built-in and induced polarization across LaAlO3/SrTiO3 heterojunctions
journal, October 2010
- Singh-Bhalla, Guneeta; Bell, Christopher; Ravichandran, Jayakanth
- Nature Physics, Vol. 7, Issue 1
Nonvolatile Memory with Multilevel Switching: A Basic Model
journal, April 2004
- Rozenberg, M. J.; Inoue, I. H.; Sánchez, M. J.
- Physical Review Letters, Vol. 92, Issue 17
Hysteretic current–voltage characteristics and resistance switching at an epitaxial oxide Schottky junction SrRuO3∕SrTi0.99Nb0.01O3
journal, January 2005
- Fujii, T.; Kawasaki, M.; Sawa, A.
- Applied Physics Letters, Vol. 86, Issue 1
Comprehensive study of the resistance switching in SrTiO3 and Nb-doped SrTiO3
journal, March 2011
- Chen, X. G.; Ma, X. B.; Yang, Y. B.
- Applied Physics Letters, Vol. 98, Issue 12
Electrode-dependent electrical properties of metal/Nb-doped SrTiO3 junctions
journal, March 2008
- Park, C.; Seo, Y.; Jung, J.
- Journal of Applied Physics, Vol. 103, Issue 5
Electrical properties and colossal electroresistance of heteroepitaxial Schottky junctions
journal, April 2007
- Fujii, T.; Kawasaki, M.; Sawa, A.
- Physical Review B, Vol. 75, Issue 16
Resistive switching and resonant tunneling in epitaxial perovskite tunnel barriers
journal, July 2009
- Son, Junwoo; Stemmer, Susanne
- Physical Review B, Vol. 80, Issue 3
Theory of resonant tunneling in heterostructures
journal, July 1988
- Price, Peter J.
- Physical Review B, Vol. 38, Issue 3
A Comparative Study on Methods for Convergence Acceleration of Iterative Vector Sequences
journal, March 1996
- Eyert, V.
- Journal of Computational Physics, Vol. 124, Issue 2
Enhanced effective mass in doped SrTiO3 and related perovskites
journal, August 2009
- Wunderlich, Wilfried; Ohta, Hiromichi; Koumoto, Kunihito
- Physica B: Condensed Matter, Vol. 404, Issue 16
Works referencing / citing this record:
Ferroelectric Tunnel Junctions: Modulations on the Potential Barrier
journal, October 2019
- Wen, Zheng; Wu, Di
- Advanced Materials
Nonequilibrium Synthesis of Highly Porous Single-Crystalline Oxide Nanostructures
journal, January 2017
- Lee, Dongkyu; Gao, Xiang; Fan, Lisha
- Advanced Materials Interfaces, Vol. 4, Issue 3
ZnO composite nanolayer with mobility edge quantization for multi-value logic transistors
journal, April 2019
- Lee, Lynn; Hwang, Jeongwoon; Jung, Jin Won
- Nature Communications, Vol. 10, Issue 1
Tuning the charge flow between Marcus regimes in an organic thin-film device
journal, May 2019
- Atxabal, A.; Arnold, T.; Parui, S.
- Nature Communications, Vol. 10, Issue 1
Growth control of oxygen stoichiometry in homoepitaxial SrTiO3 films by pulsed laser epitaxy in high vacuum
journal, January 2016
- Lee, Ho Nyung; Ambrose Seo, Sung S.; Choi, Woo Seok
- Scientific Reports, Vol. 6, Issue 1
A multiple negative differential resistance heterojunction device and its circuit application to ternary static random access memory
journal, January 2020
- Kim, Kwan-Ho; Park, Hyung-Youl; Shim, Jaewoo
- Nanoscale Horizons, Vol. 5, Issue 4
In-plane rotation and transition from rectification to bipolar resistive switching in ZnO/SrTiO 3 :Nb heterojunctions by substrate pretreatment
journal, January 2019
- Zhang, Ying; Li, Jiachen; Yin, Yanfeng
- RSC Advances, Vol. 9, Issue 64
Force and light tuning vertical tunneling current in the atomic layered MoS 2
journal, May 2018
- Li, Feng; Lu, Zhixing; Lan, Yann-Wen
- Nanotechnology, Vol. 29, Issue 27
Tuning the charge flow between Marcus regimes in an organic thin-film device
text, January 2019
- Atxabal, Ainhoa; Arnold, Thorsten; Parui, Subir
- Technische Universität Dortmund
Growth control of oxygen stoichiometry in homoepitaxial SrTiO3 films by pulsed laser epitaxy in high vacuum
text, January 2016
- Lee, Ho Nyung; Seo, Sung S. Ambrose; Choi, Woo Seok
- arXiv
Phase Instability amid Dimensional Crossover in Artificial Oxide Crystal
text, January 2019
- Jeong, Seung Gyo; Min, Taewon; Woo, Sungmin
- arXiv
ZnO composite nanolayer with mobility edge quantization for multi-value logic transistors
journal, April 2019
- Lee, Lynn; Hwang, Jeongwoon; Jung, Jin Won
- Nature Communications, Vol. 10, Issue 1
Tuning the charge flow between Marcus regimes in an organic thin-film device
journal, May 2019
- Atxabal, A.; Arnold, T.; Parui, S.
- Nature Communications, Vol. 10, Issue 1
Growth control of oxygen stoichiometry in homoepitaxial SrTiO3 films by pulsed laser epitaxy in high vacuum
journal, January 2016
- Lee, Ho Nyung; Ambrose Seo, Sung S.; Choi, Woo Seok
- Scientific Reports, Vol. 6, Issue 1