Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom
Abstract
Metal oxide superconductor powder precursors are prepared in an aerosol pyrolysis process. A solution of the metal cations is introduced into a furnace at 600.degree.-1000.degree. C. for 0.1 to 60 seconds. The process produces micron to submicron size powders without the usual loss of the lead stabilizer. The resulting powders have a narrow particle size distribution, a small grain size, and are readily converted to a superconducting composition upon subsequent heat treatment. The precursors are placed in a metal body deformed to form a wire or tape and heated to form a superconducting article. The fine powders permit a substantial reduction in heat treatment time, thus enabling a continuous processing of the powders into superconducting wire, tape or multifilamentary articles by the powder-in-tube process.
- Inventors:
-
- Knoxville, TN
- Oak Ridge, TN
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- OSTI Identifier:
- 869778
- Patent Number(s):
- 5395821
- Assignee:
- Martin Marietta Energy Systems, Inc. (Oak Ridge, TN)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC05-84OR21400
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- method; producing; pb-stabilized; superconductor; precursors; articles; therefrom; metal; oxide; powder; prepared; aerosol; pyrolysis; process; solution; cations; introduced; furnace; 600; degree; -1000; 60; produces; micron; submicron; size; powders; loss; lead; stabilizer; resulting; narrow; particle; distribution; grain; readily; converted; superconducting; composition; subsequent; heat; treatment; placed; deformed; form; wire; tape; heated; article; fine; permit; substantial; reduction; time; enabling; continuous; processing; multifilamentary; powder-in-tube; subsequent heat; articles therefrom; continuous processing; submicron size; pyrolysis process; superconductor precursor; metal cations; size distribution; metal oxide; particle size; grain size; heat treatment; superconducting wire; continuous process; process produces; oxide superconductor; substantial reduction; fine powder; readily converted; superconductor powder; superconducting article; micron size; fine powders; metal cation; powder precursors; powder precursor; conducting wire; /505/252/423/
Citation Formats
Kroeger, Donald M, Hsu, Huey S, and Brynestad, Jorulf. Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom. United States: N. p., 1995.
Web.
Kroeger, Donald M, Hsu, Huey S, & Brynestad, Jorulf. Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom. United States.
Kroeger, Donald M, Hsu, Huey S, and Brynestad, Jorulf. Sun .
"Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom". United States. https://www.osti.gov/servlets/purl/869778.
@article{osti_869778,
title = {Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom},
author = {Kroeger, Donald M and Hsu, Huey S and Brynestad, Jorulf},
abstractNote = {Metal oxide superconductor powder precursors are prepared in an aerosol pyrolysis process. A solution of the metal cations is introduced into a furnace at 600.degree.-1000.degree. C. for 0.1 to 60 seconds. The process produces micron to submicron size powders without the usual loss of the lead stabilizer. The resulting powders have a narrow particle size distribution, a small grain size, and are readily converted to a superconducting composition upon subsequent heat treatment. The precursors are placed in a metal body deformed to form a wire or tape and heated to form a superconducting article. The fine powders permit a substantial reduction in heat treatment time, thus enabling a continuous processing of the powders into superconducting wire, tape or multifilamentary articles by the powder-in-tube process.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1995},
month = {Sun Jan 01 00:00:00 EST 1995}
}
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