Metal-organic framework templated synthesis of porous inorganic materials as novel sorbents
Abstract
A novel metal-organic framework (MOF) templated process for the synthesis of highly porous inorganic sorbents for removing radionuclides, actinides, and heavy metals is disclosed. The highly porous nature of the MOFs leads to highly porous inorganic sorbents (such as oxides, phosphates, sulfides, etc) with accessible surface binding sites that are suitable for removing radionuclides from high level nuclear wastes, extracting uranium from acid mine drainage and seawater, and sequestering heavy metals from waste streams. In some cases, MOFs can be directly used for removing these metal ions as MOFs are converted to highly porous inorganic sorbents in situ.
- Inventors:
- Issue Date:
- Research Org.:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1347598
- Patent Number(s):
- 9597658
- Application Number:
- 14/242,087
- Assignee:
- Savannah River Nuclear Solutions, LLC
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- AC09-08SR22470
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Apr 01
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Taylor-Pashow, Kathryn M. L., Lin, Wenbin, and Abney, Carter W. Metal-organic framework templated synthesis of porous inorganic materials as novel sorbents. United States: N. p., 2017.
Web.
Taylor-Pashow, Kathryn M. L., Lin, Wenbin, & Abney, Carter W. Metal-organic framework templated synthesis of porous inorganic materials as novel sorbents. United States.
Taylor-Pashow, Kathryn M. L., Lin, Wenbin, and Abney, Carter W. Tue .
"Metal-organic framework templated synthesis of porous inorganic materials as novel sorbents". United States. https://www.osti.gov/servlets/purl/1347598.
@article{osti_1347598,
title = {Metal-organic framework templated synthesis of porous inorganic materials as novel sorbents},
author = {Taylor-Pashow, Kathryn M. L. and Lin, Wenbin and Abney, Carter W.},
abstractNote = {A novel metal-organic framework (MOF) templated process for the synthesis of highly porous inorganic sorbents for removing radionuclides, actinides, and heavy metals is disclosed. The highly porous nature of the MOFs leads to highly porous inorganic sorbents (such as oxides, phosphates, sulfides, etc) with accessible surface binding sites that are suitable for removing radionuclides from high level nuclear wastes, extracting uranium from acid mine drainage and seawater, and sequestering heavy metals from waste streams. In some cases, MOFs can be directly used for removing these metal ions as MOFs are converted to highly porous inorganic sorbents in situ.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Mar 21 00:00:00 EDT 2017},
month = {Tue Mar 21 00:00:00 EDT 2017}
}
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