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Title: Chromium metal organic frameworks and synthesis of metal organic frameworks

The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.
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Issue Date:
OSTI Identifier:
The Texas A&M University System (College Station, TX) ARPA-E
Patent Number(s):
Application Number:
Contract Number:
Resource Relation:
Patent File Date: 2015 May 11
Research Org:
The Texas A&M University System, College Station, TX (United States)
Sponsoring Org:
Country of Publication:
United States

Works referenced in this record:

The asc Trinodal Platform: Two-Step Assembly of Triangular, Tetrahedral, and Trigonal-Prismatic Molecular Building Blocks
journal, February 2013
  • Schoedel, Alexander; Cairns, Amy J.; Belmabkhout, Youssef
  • Angewandte Chemie International Edition, Vol. 52, Issue 10, p. 2902-2905
  • DOI: 10.1002/anie.201206042

Network Diversity through Decoration of Trigonal-Prismatic Nodes: Two-Step Crystal Engineering of Cationic Metal-Organic Materials
journal, October 2011
  • Schoedel, Alexander; Wojtas, Lukasz; Kelley, Stephen P.
  • Angewandte Chemie International Edition, Vol. 50, Issue 48, p. 11421-11424
  • DOI: 10.1002/anie.201104688

Synthesis and structure of a trinuclear chromium(III)-nicotinic acid complex
journal, January 1982

A nearly symmetric trinuclear chromium(III) oxo carboxylate assembly: preparation, molecular and crystal structure, and magnetic properties of [Cr3O(O2CPh)6(MeOH)3](NO3)�2MeOH
journal, August 2004
  • Vlachos, Antonis; Psycharis, Vassilios; Raptopoulou, Catherine P.
  • Inorganica Chimica Acta, Vol. 357, Issue 11, p. 3162-3172
  • DOI: 10.1016/j.ica.2004.04.005

Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties
journal, April 2012
  • Bromberg, Lev; Diao, Ying; Wu, Huimeng
  • Chemistry of Materials, Vol. 24, Issue 9, p. 1664-1675
  • DOI: 10.1021/cm2034382

Gas Adsorption Properties of the Chromium-Based Metal Organic Framework MIL-101
journal, March 2009
  • Chowdhury, Pradip; Bikkina, Chaitanya; Gumma, Sasidhar
  • The Journal of Physical Chemistry C, Vol. 113, Issue 16, p. 6616-6621
  • DOI: 10.1021/jp811418r

A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
journal, August 2004
  • F�rey, G�rard; Serre, Christian; Mellot-Draznieks, Caroline
  • Angewandte Chemie, Vol. 116, Issue 46, p. 6456-6461
  • DOI: 10.1002/ange.200460592