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Title: Chromium metal organic frameworks and synthesis of metal organic frameworks

Abstract

The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
The Texas A&M University System, College Station, TX (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1436680
Patent Number(s):
9951095
Application Number:
15/307,267
Assignee:
The Texas A&M University System (College Station, TX)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
AR0000073
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 May 11
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Zhou, Hong-Cai, Liu, Tian-Fu, Lian, Xizhen, Zou, Lanfang, and Feng, Dawei. Chromium metal organic frameworks and synthesis of metal organic frameworks. United States: N. p., 2018. Web.
Zhou, Hong-Cai, Liu, Tian-Fu, Lian, Xizhen, Zou, Lanfang, & Feng, Dawei. Chromium metal organic frameworks and synthesis of metal organic frameworks. United States.
Zhou, Hong-Cai, Liu, Tian-Fu, Lian, Xizhen, Zou, Lanfang, and Feng, Dawei. Tue . "Chromium metal organic frameworks and synthesis of metal organic frameworks". United States. https://www.osti.gov/servlets/purl/1436680.
@article{osti_1436680,
title = {Chromium metal organic frameworks and synthesis of metal organic frameworks},
author = {Zhou, Hong-Cai and Liu, Tian-Fu and Lian, Xizhen and Zou, Lanfang and Feng, Dawei},
abstractNote = {The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {4}
}

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Works referenced in this record:

Network Diversity through Decoration of Trigonal-Prismatic Nodes: Two-Step Crystal Engineering of Cationic Metal-Organic Materials
journal, October 2011


The asc Trinodal Platform: Two-Step Assembly of Triangular, Tetrahedral, and Trigonal-Prismatic Molecular Building Blocks
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A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
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247th American Chemical Society National Meeting and Exposition: Part II
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Gas Adsorption Properties of the Chromium-Based Metal Organic Framework MIL-101
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A nearly symmetric trinuclear chromium(III) oxo carboxylate assembly: preparation, molecular and crystal structure, and magnetic properties of [Cr3O(O2CPh)6(MeOH)3](NO3)·2MeOH
journal, August 2004


Synthesis and structure of a trinuclear chromium(III)-nicotinic acid complex
journal, January 1982