High energy density aluminum battery

Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

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Title: High energy density aluminum battery

Abstract

Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.

Inventors:: Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

Issue Date:: Tue Oct 11 00:00:00 EDT 2016

Research Org.:: UT-Battelle LLC/ORNL, Oak Ridge, TN (United States); Board of Regents, The University of Texas System, Austin, TX (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1328682

Patent Number(s):: 9466853

Application Number:: 13/247,417

Assignee:: Board of Regents, The University of Texas System (Austin, TX)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M10/058 - Construction or manufacture
H01M2300/0028 - characterised by the solvent
H01M4/38 - of elements or alloys
H01M4/463 - {Aluminium based}
H01M4/50 - of manganese
H01M6/16 - with organic electrolyte

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T29/49108 - Electric battery cell making

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DOE Contract Number:: FOA-0000207

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 Sep 28

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats


                    Brown, Gilbert M., Paranthaman, Mariappan Parans, Dai, Sheng, Dudney, Nancy J., Manthiram, Arumugan, McIntyre, Timothy J., Sun, Xiao-Guang, and Liu, Hansan. High energy density aluminum battery.  United States: N. p., 2016. 
        Web.

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                    Brown, Gilbert M., Paranthaman, Mariappan Parans, Dai, Sheng, Dudney, Nancy J., Manthiram, Arumugan, McIntyre, Timothy J., Sun, Xiao-Guang, & Liu, Hansan. High energy density aluminum battery.  United States.

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                    Brown, Gilbert M., Paranthaman, Mariappan Parans, Dai, Sheng, Dudney, Nancy J., Manthiram, Arumugan, McIntyre, Timothy J., Sun, Xiao-Guang, and Liu, Hansan. Tue .  
        "High energy density aluminum battery".  United States.  https://www.osti.gov/servlets/purl/1328682.

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@article{osti_1328682,

  title        = {High energy density aluminum battery},

  author       = {Brown, Gilbert M. and Paranthaman, Mariappan Parans and Dai, Sheng and Dudney, Nancy J. and Manthiram, Arumugan and McIntyre, Timothy J. and Sun, Xiao-Guang and Liu, Hansan},

  abstractNote = {Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Oct 11 00:00:00 EDT 2016},

  month        = {Tue Oct 11 00:00:00 EDT 2016}

}

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Similar Records

Title: High energy density aluminum battery

Abstract

Citation Formats

Method for Producing Electrical Energy with Consumable Aluminum Anode patent, June 1975

Rechargeable lithium-aluminum anode patent, January 1977

Intercalated transition metal phosphorus trisulfides patent, September 1977

Aluminum-chlorine thermal battery patent, December 1977

Battery having an electrode comprising mixtures of Al and TiS.sub.2 patent, May 1978

Primary cell anode material formed from aluminum base alloys containing zinc, magnesium and iron patent, March 1979

Secondary batteries containing room-temperature molten 1,2,3-trialkylimidazolium halide non-aqueous electrolyte patent, July 1984

Negative electrodes for non-aqueous secondary batteries composed on conjugated polymer and alkali metal alloying or inserting material patent, May 1987

Non-aqueous electrolyte type secondary cell patent, April 1989

Battery containing a metal anode and an electrolyte providing high rates of metal electrolysis at near ambient temperatures patent, November 1989

Aluminium batteries patent, July 1990

Cell with active metal electrode and molten salt electrolyte patent, December 1992

Preparation of an electrocatalytic cathode for an aluminum-hydrogen peroxide battery patent, March 1994

High-energy, rechargeable, electrochemical cells with non-aqueous electrolytes patent, November 2001

All-solid-state electrochemical device and method of manufacturing patent, December 2003

Cathode for metal-oxygen battery patent, December 2006

Bi-liquid phase replenishment electrolyte management system patent, August 2007

Conductive lithium storage electrode patent, March 2008

Non-aqueous electrolyte and secondary battery containing same patent, April 2009

High ionic conductivity gel polymer electrolyte for rechargeble polymber secondary battery patent, July 2009

Lithium ion battery and methods of manufacturing same patent-application, July 2004

Electrolyte for alkaline battery and alkaline battery employing electrolyte patent-application, September 2004

Electrochemical study of nickel–aluminium–manganese spinel NixAl1−xMn2O4. Electrocatalytical properties for the oxygen evolution reaction and oxygen reduction reaction in alkaline media journal, August 2001

Nucleation and Morphology Studies of Aluminum Deposited from an Ambient‐Temperature Chloroaluminate Molten Salt journal, January 1992

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS journal, January 1990

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte journal, January 1988

Preparation of a new crystal form of manganese dioxide: λ-MnO2 journal, September 1981

Non-conventional electrolytes for electrochemical applications journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl3)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids journal, September 2006

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride journal, July 1988

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes journal, July 1994

Raman Study of Aluminum Chloride−Dimethylsulfone Solutions journal, January 1996

Aluminum as anode for energy storage and conversion: a review journal, July 2002

Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves journal, June 1999

Electrochemical Studies of Sodium Chloride as a Lewis Buffer for Room Temperature Chloroaluminate Molten Salts journal, January 1990

The effect of cosolvents and additives on the electrochemical properties of [(Me)3PhN][Al2Cl7] melts journal, February 1993

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes journal, May 2008

Alkali Metal Reduction Potentials Measured in Chloroaluminate Ambient-Temperature Molten Salts journal, January 1992

Electrochemistry of Room-Temperature Ionic Liquids and Melts book, January 2009

Electrochemistry of Titanium and the Electrodeposition of Al-Ti Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Melt journal, January 2003

Development of non-flammable lithium secondary battery with ambient-temperature molten salt electrolyte journal, August 2005

Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes journal, January 1993

Ionic Liquids for Lithium Ion and Related Batteries book, January 2002

Lithium Batteries and Cathode Materials journal, October 2004

Design and analysis of aluminum/air battery system for electric vehicles journal, October 2002

Post-synthesis alumination of SBA-15 in aqueous solution: A versatile tool for the preparation of acidic Al-SBA-15 supports journal, November 2005

Novel operation and control of an electric vehicle aluminum/air battery system journal, April 2004

Method for Producing Electrical Energy with Consumable Aluminum Anode
patent, June 1975

Rechargeable lithium-aluminum anode
patent, January 1977

Intercalated transition metal phosphorus trisulfides
patent, September 1977

Aluminum-chlorine thermal battery
patent, December 1977

Battery having an electrode comprising mixtures of Al and TiS.sub.2
patent, May 1978

Primary cell anode material formed from aluminum base alloys containing zinc, magnesium and iron
patent, March 1979

Secondary batteries containing room-temperature molten 1,2,3-trialkylimidazolium halide non-aqueous electrolyte
patent, July 1984

Negative electrodes for non-aqueous secondary batteries composed on conjugated polymer and alkali metal alloying or inserting material
patent, May 1987

Non-aqueous electrolyte type secondary cell
patent, April 1989

Battery containing a metal anode and an electrolyte providing high rates of metal electrolysis at near ambient temperatures
patent, November 1989

Aluminium batteries
patent, July 1990

Cell with active metal electrode and molten salt electrolyte
patent, December 1992

Preparation of an electrocatalytic cathode for an aluminum-hydrogen peroxide battery
patent, March 1994

High-energy, rechargeable, electrochemical cells with non-aqueous electrolytes
patent, November 2001

All-solid-state electrochemical device and method of manufacturing
patent, December 2003

Cathode for metal-oxygen battery
patent, December 2006

Bi-liquid phase replenishment electrolyte management system
patent, August 2007

Conductive lithium storage electrode
patent, March 2008

Non-aqueous electrolyte and secondary battery containing same
patent, April 2009

High ionic conductivity gel polymer electrolyte for rechargeble polymber secondary battery
patent, July 2009

Lithium ion battery and methods of manufacturing same
patent-application, July 2004

Electrolyte for alkaline battery and alkaline battery employing electrolyte
patent-application, September 2004

Electrochemical study of nickel–aluminium–manganese spinel Ni_xAl_1−xMn₂O₄. Electrocatalytical properties for the oxygen evolution reaction and oxygen reduction reaction in alkaline media
journal, August 2001

Nucleation and Morphology Studies of Aluminum Deposited from an Ambient‐Temperature Chloroaluminate Molten Salt
journal, January 1992

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS
journal, January 1990

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte
journal, January 1988

Preparation of a new crystal form of manganese dioxide: λ-MnO₂
journal, September 1981

Non-conventional electrolytes for electrochemical applications
journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl₃)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids
journal, September 2006

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride
journal, July 1988

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes
journal, July 1994

Raman Study of Aluminum Chloride−Dimethylsulfone Solutions
journal, January 1996

Aluminum as anode for energy storage and conversion: a review
journal, July 2002

Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves
journal, June 1999

Electrochemical Studies of Sodium Chloride as a Lewis Buffer for Room Temperature Chloroaluminate Molten Salts
journal, January 1990

The effect of cosolvents and additives on the electrochemical properties of [(Me)₃PhN][Al₂Cl₇] melts
journal, February 1993

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes
journal, May 2008

Alkali Metal Reduction Potentials Measured in Chloroaluminate Ambient-Temperature Molten Salts
journal, January 1992

Electrochemistry of Room-Temperature Ionic Liquids and Melts
book, January 2009

Electrochemistry of Titanium and the Electrodeposition of Al-Ti Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Melt
journal, January 2003

Development of non-flammable lithium secondary battery with ambient-temperature molten salt electrolyte
journal, August 2005

Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes
journal, January 1993

Ionic Liquids for Lithium Ion and Related Batteries
book, January 2002

Lithium Batteries and Cathode Materials
journal, October 2004

Design and analysis of aluminum/air battery system for electric vehicles
journal, October 2002

Post-synthesis alumination of SBA-15 in aqueous solution: A versatile tool for the preparation of acidic Al-SBA-15 supports
journal, November 2005

Novel operation and control of an electric vehicle aluminum/air battery system
journal, April 2004