High energy density aluminum battery

Title: High energy density aluminum battery

Abstract

Compositions and methods of making are provided for a high energy density lithium-aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a lithium metal oxide. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of lithium at the cathode.

Inventors:: Brown, Gilbert M.; Parans Paranthaman, Mariappan; Dai, Sheng; Sun, Xiao-Guang; Liu, Hansan

Issue Date:: 2018-06-12

Research Org.:: UT-Battelle LLC/ORNL, Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1457415

Patent Number(s):: 9997802

Application Number:: 15/257,455

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0568 - characterised by the solutes
H01M4/38 - of elements or alloys

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T29/49108 - Electric battery cell making

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0569 - characterised by the solvents
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/058 - Construction or manufacture
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/50 - of manganese
H01M4/463 - {Aluminium based}
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M2300/0028 - characterised by the solvent
H01M6/16 - with organic electrolyte

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DOE Contract Number:: FOA-0000207

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Sep 06

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Brown, Gilbert M., Parans Paranthaman, Mariappan, Dai, Sheng, Sun, Xiao-Guang, and Liu, Hansan. High energy density aluminum battery.  United States: N. p., 2018. 
        Web.

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                    Brown, Gilbert M., Parans Paranthaman, Mariappan, Dai, Sheng, Sun, Xiao-Guang, & Liu, Hansan. High energy density aluminum battery.  United States.

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                    Brown, Gilbert M., Parans Paranthaman, Mariappan, Dai, Sheng, Sun, Xiao-Guang, and Liu, Hansan. Tue .  
        "High energy density aluminum battery".  United States.  https://www.osti.gov/servlets/purl/1457415.

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@article{osti_1457415,

  title        = {High energy density aluminum battery},

  author       = {Brown, Gilbert M. and Parans Paranthaman, Mariappan and Dai, Sheng and Sun, Xiao-Guang and Liu, Hansan},

  abstractNote = {Compositions and methods of making are provided for a high energy density lithium-aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a lithium metal oxide. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of lithium at the cathode.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {6}

}

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Structure that encapsulates lithium metal for high energy density battery anode

Patent Cui, Yi; Yan, Kai; Chu, Steven

A battery includes 1) an anode, 2) a cathode, and 3) an electrolyte disposed between the anode and the cathode. The anode includes a current collector and an interfacial layer disposed over the current collector, and the interfacial layer includes an array of interconnected, protruding regions that define spaces.
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Nanoelectrofuel compositions include a plurality of electroactive surface-treated or surface modified nanoparticles dispersed in an electrolyte or self suspended and exhibit fluid characteristics are provided. A Redox flow cell may employ the nanoelectrofuels compositions, wherein the redox flow cell includes a first inlet and a first outlet in fluid communication with a first half-cell body, a second inlet and a second outlet in fluid communication with a second half-cell body, a third cell body, and an ion-conductive membrane separating the first half-cell body from the second half-cell body and defining the second half-cell body.
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Title: High energy density aluminum battery

Abstract

Citation Formats

Rechargeable lithium-aluminum anode patent, January 1977

Intercalated transition metal phosphorus trisulfides patent, September 1977

Aluminum-chlorine thermal battery patent, December 1977

Battery having an electrode comprising mixtures of Al and TiS2 patent, May 1978

Primary cell anode material formed from aluminum base alloys containing zinc, magnesium and iron patent, March 1979

Negative electrodes for non-aqueous secondary batteries composed on conjugated polymer and alkali metal alloying or inserting material patent, May 1987

Battery containing a metal anode and an electrolyte providing high rates of metal electrolysis at near ambient temperatures patent, November 1989

Aluminium batteries patent, July 1990

Preparation of an electrocatalytic cathode for an aluminum-hydrogen peroxide battery patent, March 1994

All-solid-state electrochemical device and method of manufacturing patent, December 2003

Locking device for magazine of staplers patent, June 2007

Conductive lithium storage electrode patent, March 2008

Non-aqueous electrolyte and secondary battery containing same patent, April 2009

High ionic conductivity gel polymer electrolyte for rechargeble polymber secondary battery patent, July 2009

Mesoporous network electrode for electrochemical cell patent-application, July 2004

Lithium ion battery and methods of manufacturing same patent-application, July 2004

Novel onium salt, electrolyte for non-aqueous cell containing the novel onium salt for nonaqueous cell, and method for optimizing negative electrode using elecrolyte containing onium salt patent-application, September 2004

Electrolyte for alkaline battery and alkaline battery employing electrolyte patent-application, September 2004

Non-Aqueous Electrolyte Secondary Batery patent-application, October 2007

Electrode Active Composite Materials and Methods of Making Thereof patent-application, November 2010

Electrode Materials for Magnesium Batteries patent-application, August 2012

A simple synthesis of [NS]+[AlCl4]– and the insertion reaction with alkylselenium halides: X-ray structure of [N2S2SeCl]+[AlCl4]– journal, January 1989

Basic Research Needs for Electrical Energy Storage. Report of the Basic Energy Sciences Workshop on Electrical Energy Storage, April 2-4, 2007 report, April 2007

Nucleation and Morphology Studies of Aluminum Deposited from an Ambient‐Temperature Chloroaluminate Molten Salt journal, January 1992

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS journal, January 1990

Soft chemistry preparation of layered Al0.3V2O5·5H2O journal, March 2010

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte journal, January 1988

The Aluminum Electrode in AlCl3-Alkali-Halide Melts journal, January 1972

Aluminium alloys for aluminium primary cell journal, September 1985

Preparation of a new crystal form of manganese dioxide: λ-MnO2 journal, September 1981

Non-conventional electrolytes for electrochemical applications journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl3)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids journal, September 2006

Electrodeposition of aluminium from ionic liquids: Part II - studies on the electrodeposition of aluminum from aluminum chloride (AICl3) - trimethylphenylammonium chloride (TMPAC) ionic liquids journal, September 2006

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride journal, July 1988

Intercalation of Polyvalent Cations into V2O5 Aerogels journal, March 1998

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes journal, July 1994

Raman Study of Aluminum Chloride−Dimethylsulfone Solutions journal, January 1996

Aluminum as anode for energy storage and conversion: a review journal, July 2002

Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves journal, June 1999

Electrochemical Studies of Sodium Chloride as a Lewis Buffer for Room Temperature Chloroaluminate Molten Salts journal, January 1990

The effect of cosolvents and additives on the electrochemical properties of [(Me)3PhN][Al2Cl7] melts journal, February 1993

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes journal, May 2008

Bipolar Al/02 battery with planar electrodes in alkaline and acidic electrolytes journal, February 1995

Alkali Metal Reduction Potentials Measured in Chloroaluminate Ambient-Temperature Molten Salts journal, January 1992

Electrochemical Performance of Al ∕ MnO2 Dry Cells: An Alternative to Lechlanche Dry Cells journal, January 2008

Electrochemistry of Room-Temperature Ionic Liquids and Melts book, January 2009

Electrochemistry of Titanium and the Electrodeposition of Al-Ti Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Melt journal, January 2003

Development of non-flammable lithium secondary battery with room-temperature ionic liquid electrolyte: Performance of electroplated Al film negative electrode journal, August 2008

Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes journal, January 1993

Ionic Liquids for Lithium Ion and Related Batteries book, January 2002

Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis journal, August 1999

Lithium Batteries and Cathode Materials journal, October 2004

Design and analysis of aluminum/air battery system for electric vehicles journal, October 2002

Post-synthesis alumination of SBA-15 in aqueous solution: A versatile tool for the preparation of acidic Al-SBA-15 supports journal, November 2005

Novel operation and control of an electric vehicle aluminum/air battery system journal, April 2004

Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries journal, January 2016

Rechargeable lithium-aluminum anode
patent, January 1977

Intercalated transition metal phosphorus trisulfides
patent, September 1977

Aluminum-chlorine thermal battery
patent, December 1977

Battery having an electrode comprising mixtures of Al and TiS₂
patent, May 1978

Primary cell anode material formed from aluminum base alloys containing zinc, magnesium and iron
patent, March 1979

Negative electrodes for non-aqueous secondary batteries composed on conjugated polymer and alkali metal alloying or inserting material
patent, May 1987

Battery containing a metal anode and an electrolyte providing high rates of metal electrolysis at near ambient temperatures
patent, November 1989

Aluminium batteries
patent, July 1990

Preparation of an electrocatalytic cathode for an aluminum-hydrogen peroxide battery
patent, March 1994

All-solid-state electrochemical device and method of manufacturing
patent, December 2003

Locking device for magazine of staplers
patent, June 2007

Conductive lithium storage electrode
patent, March 2008

Non-aqueous electrolyte and secondary battery containing same
patent, April 2009

High ionic conductivity gel polymer electrolyte for rechargeble polymber secondary battery
patent, July 2009

Mesoporous network electrode for electrochemical cell
patent-application, July 2004

Lithium ion battery and methods of manufacturing same
patent-application, July 2004

Novel onium salt, electrolyte for non-aqueous cell containing the novel onium salt for nonaqueous cell, and method for optimizing negative electrode using elecrolyte containing onium salt
patent-application, September 2004

Electrolyte for alkaline battery and alkaline battery employing electrolyte
patent-application, September 2004

Non-Aqueous Electrolyte Secondary Batery
patent-application, October 2007

Electrode Active Composite Materials and Methods of Making Thereof
patent-application, November 2010

Electrode Materials for Magnesium Batteries
patent-application, August 2012

A simple synthesis of [NS]⁺[AlCl₄]^– and the insertion reaction with alkylselenium halides: X-ray structure of [N₂S₂SeCl]⁺[AlCl₄]^–
journal, January 1989

Basic Research Needs for Electrical Energy Storage. Report of the Basic Energy Sciences Workshop on Electrical Energy Storage, April 2-4, 2007
report, April 2007

Nucleation and Morphology Studies of Aluminum Deposited from an Ambient‐Temperature Chloroaluminate Molten Salt
journal, January 1992

The structure of halogenometallate complexes dissolved in both basic and acidic room-temperature halogenoaluminate(III) ionic liquids, as determined by EXAFS
journal, January 1990

Soft chemistry preparation of layered Al_0.3V₂O₅·5H₂O
journal, March 2010

An Aluminum/Chlorine Rechargeable Cell Employing a Room Temperature Molten Salt Electrolyte
journal, January 1988

The Aluminum Electrode in AlCl₃-Alkali-Halide Melts
journal, January 1972

Aluminium alloys for aluminium primary cell
journal, September 1985

Preparation of a new crystal form of manganese dioxide: λ-MnO₂
journal, September 1981

Non-conventional electrolytes for electrochemical applications
journal, May 2000

Electrodeposition of aluminium from ionic liquids: Part I—electrodeposition and surface morphology of aluminium from aluminium chloride (AlCl₃)–1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) ionic liquids
journal, September 2006

Electrodeposition of aluminium from ionic liquids: Part II - studies on the electrodeposition of aluminum from aluminum chloride (AICl₃) - trimethylphenylammonium chloride (TMPAC) ionic liquids
journal, September 2006

Electrodeposition of aluminium in aluminium chloride/1-methyl-3-ethylimidazolium chloride
journal, July 1988

Intercalation of Polyvalent Cations into V₂O₅ Aerogels
journal, March 1998

Behaviour of aluminium as anode in dimethylsulfone-based electrolytes
journal, July 1994

Raman Study of Aluminum Chloride−Dimethylsulfone Solutions
journal, January 1996

Aluminum as anode for energy storage and conversion: a review
journal, July 2002

Alumination and Ion Exchange of Mesoporous SBA-15 Molecular Sieves
journal, June 1999

Electrochemical Studies of Sodium Chloride as a Lewis Buffer for Room Temperature Chloroaluminate Molten Salts
journal, January 1990

The effect of cosolvents and additives on the electrochemical properties of [(Me)₃PhN][Al₂Cl₇] melts
journal, February 1993

Investigation of the anodic behavior of Al current collector in room temperature ionic liquid electrolytes
journal, May 2008

Bipolar Al/0₂ battery with planar electrodes in alkaline and acidic electrolytes
journal, February 1995

Alkali Metal Reduction Potentials Measured in Chloroaluminate Ambient-Temperature Molten Salts
journal, January 1992

Electrochemical Performance of Al ∕ MnO₂ Dry Cells: An Alternative to Lechlanche Dry Cells
journal, January 2008

Electrochemistry of Room-Temperature Ionic Liquids and Melts
book, January 2009

Electrochemistry of Titanium and the Electrodeposition of Al-Ti Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Melt
journal, January 2003

Development of non-flammable lithium secondary battery with room-temperature ionic liquid electrolyte: Performance of electroplated Al film negative electrode
journal, August 2008

Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes
journal, January 1993

Ionic Liquids for Lithium Ion and Related Batteries
book, January 2002

Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
journal, August 1999

Lithium Batteries and Cathode Materials
journal, October 2004

Design and analysis of aluminum/air battery system for electric vehicles
journal, October 2002

Post-synthesis alumination of SBA-15 in aqueous solution: A versatile tool for the preparation of acidic Al-SBA-15 supports
journal, November 2005

Novel operation and control of an electric vehicle aluminum/air battery system
journal, April 2004

Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries
journal, January 2016