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Title: Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries

Abstract

Nano-sized structured dense and spherical layered positive active materials provide high energy density and high rate capability electrodes in lithium-ion batteries. Such materials are spherical second particles made from agglomerated primary particles that are Li.sub.1+.alpha.(Ni.sub.xCo.sub.yMn.sub.z).sub.1-tM.sub.tO.sub.2-dR.sub.d- , where M is selected from can be Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, Zr, or a mixture of any two or more thereof, R is selected from F, Cl, Br, I, H, S, N, or a mixture of any two or more thereof, and 0.ltoreq..alpha..ltoreq.0.50; 0<x.ltoreq.1; 0.ltoreq.y.ltoreq.1; 0<z.ltoreq.1; 0.ltoreq.t.ltoreq.1; and 0.ltoreq.d.ltoreq.0.5. Methods of preparing such materials and their use in electrochemical devices are also described.

Inventors:
; ;
Issue Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1079407
Patent Number(s):
8277683
Application Number:
12/454,748
Assignee:
Uchicago Argonne, LLC (Chicago, IL)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
W-31-109-ENG-38
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Deng, Haixia, Belharouak, Ilias, and Amine, Khalil. Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries. United States: N. p., 2012. Web.
Deng, Haixia, Belharouak, Ilias, & Amine, Khalil. Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries. United States.
Deng, Haixia, Belharouak, Ilias, and Amine, Khalil. Tue . "Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries". United States. https://www.osti.gov/servlets/purl/1079407.
@article{osti_1079407,
title = {Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries},
author = {Deng, Haixia and Belharouak, Ilias and Amine, Khalil},
abstractNote = {Nano-sized structured dense and spherical layered positive active materials provide high energy density and high rate capability electrodes in lithium-ion batteries. Such materials are spherical second particles made from agglomerated primary particles that are Li.sub.1+.alpha.(Ni.sub.xCo.sub.yMn.sub.z).sub.1-tM.sub.tO.sub.2-dR.sub.d- , where M is selected from can be Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, Zr, or a mixture of any two or more thereof, R is selected from F, Cl, Br, I, H, S, N, or a mixture of any two or more thereof, and 0.ltoreq..alpha..ltoreq.0.50; 0<x.ltoreq.1; 0.ltoreq.y.ltoreq.1; 0<z.ltoreq.1; 0.ltoreq.t.ltoreq.1; and 0.ltoreq.d.ltoreq.0.5. Methods of preparing such materials and their use in electrochemical devices are also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2012},
month = {10}
}

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Works referenced in this record:

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