Electrolyte additives for lithium-ion batteries under high-voltage operation
Abstract
A non-aqueous electrolyte for a lithium-ion battery comprises a lithium salt and an additive in an organic solvent. The additive comprises a di-substituted malonate silyl ester compound, in which the hydrogens of the malonate methylene group are replaced by substituents R1 (e.g., alkyl) and X (e.g., halogen). Each of the carboxylic acid groups of the malonate are esterified by a monovalent silyl group such as —Si(R4)3; or the two carboxylic acid groups are esterified by a single divalent silylene group such as —Si(R5)2— to form a ring therewith. Each R4 and R5 independently is alkyl, phenyl, or alkoxy; and each substituted-alkyl comprises an alkyl moiety substituted with one or more group selected from alkenyl, alkynyl, hydroxy, halogen, alkoxy, carboxylic acid, carboxylic ester, carboxylic amide, phenyl, sulfonic acid, and phosphonic acid.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1600235
- Patent Number(s):
- 10461364
- Application Number:
- 15/492,260
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 04/20/2017
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Liao, Chen, Peebles, Cameron, Abraham, Daniel, and Zhang, Zhengcheng. Electrolyte additives for lithium-ion batteries under high-voltage operation. United States: N. p., 2019.
Web.
Liao, Chen, Peebles, Cameron, Abraham, Daniel, & Zhang, Zhengcheng. Electrolyte additives for lithium-ion batteries under high-voltage operation. United States.
Liao, Chen, Peebles, Cameron, Abraham, Daniel, and Zhang, Zhengcheng. Tue .
"Electrolyte additives for lithium-ion batteries under high-voltage operation". United States. https://www.osti.gov/servlets/purl/1600235.
@article{osti_1600235,
title = {Electrolyte additives for lithium-ion batteries under high-voltage operation},
author = {Liao, Chen and Peebles, Cameron and Abraham, Daniel and Zhang, Zhengcheng},
abstractNote = {A non-aqueous electrolyte for a lithium-ion battery comprises a lithium salt and an additive in an organic solvent. The additive comprises a di-substituted malonate silyl ester compound, in which the hydrogens of the malonate methylene group are replaced by substituents R1 (e.g., alkyl) and X (e.g., halogen). Each of the carboxylic acid groups of the malonate are esterified by a monovalent silyl group such as —Si(R4)3; or the two carboxylic acid groups are esterified by a single divalent silylene group such as —Si(R5)2— to form a ring therewith. Each R4 and R5 independently is alkyl, phenyl, or alkoxy; and each substituted-alkyl comprises an alkyl moiety substituted with one or more group selected from alkenyl, alkynyl, hydroxy, halogen, alkoxy, carboxylic acid, carboxylic ester, carboxylic amide, phenyl, sulfonic acid, and phosphonic acid.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 29 00:00:00 EDT 2019},
month = {Tue Oct 29 00:00:00 EDT 2019}
}
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Works referenced in this record:
New promising lithium malonatoborate salts for high voltage lithium ion batteries
journal, January 2017
- Sun, Xiao-Guang; Wan, Shun; Guang, Hong Yu
- Journal of Materials Chemistry A, Vol. 5, Issue 3
Improving the High Voltage Cycling of Li[Ni 0.42 Mn 0.42 Co 0.16 ]O 2 (NMC442)/Graphite Pouch Cells Using Electrolyte Additives
journal, January 2014
- Ma, Lin; Xia, Jian; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 161, Issue 14
Electrolyte compositions for lithium ion batteries
patent, March 2016
- Sun, Xiao-Guang; Dai, Sheng; Liao, Chen
- US Patent Document 9,300,009
Electrode Active Material for Power Storage Device, and Power Storage Device
patent-application, October 2015
- Otsuka, Yu; Hojo, Nobuhiko; Yoshida, Jun-ichi
- US Patent Application 14/439972; 20150295244
Electrolyte Compositions for Lithium Ion Batteries
patent-application, April 2014
- Sun, Xiao-Guang; Dai, Sheng; Liao, Chen
- US Patent Application 13/657304; 20140113202
Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
journal, December 2014
- Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
A stable fluorinated and alkylated lithium malonatoborate salt for lithium ion battery application
journal, January 2015
- Wan, Shun; Jiang, Xueguang; Guo, Bingkun
- Chemical Communications, Vol. 51, Issue 48
Electrolyte for rechargeable lithium battery and rechargeable lithium battery including the same
patent, October 2016
- Yokotsuji, Hokuto; Takase, Hironari
- US Patent Document 9,478,828
Why is tris(trimethylsilyl) phosphite effective as an additive for high-voltage lithium-ion batteries?
journal, January 2015
- Han, Young-Kyu; Yoo, Jaeik; Yim, Taeeun
- Journal of Materials Chemistry A, Vol. 3, Issue 20