Electrolyte compositions for high voltage lithium-ion batteries

Abraham, Daniel; Zhu, Ye

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Title: Electrolyte compositions for high voltage lithium-ion batteries

Abstract

The present invention provides an electrolyte composition for a lithium-ion battery comprising LiPF₆ in a liquid carrier comprising a carbonate ester and an unsaturated organoboron compound comprising two or three unsaturated hydrocarbon groups, each unsaturated hydrocarbon group being covalently bonded to a boron atom. The unsaturated hydrocarbon groups are independently selected from vinyl, allyl, propargyl, substituted vinyl, substituted allyl, and substituted propargyl. The substituents of the substituted vinyl, allyl and propargyl groups independently comprise one or more of alkyl and phenyl. The alkyl and phenyl groups optionally can bear one or more substituent selected from halogen (e.g., F), hydroxy, amino, alkoxy, and perfluoroalkoxy.

Inventors:: Abraham, Daniel; Zhu, Ye

Issue Date:: 2018-11-06

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1493337

Patent Number(s):: 10122046

Application Number:: 14/506,316

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0567 - characterised by the additives
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M2300/0037 - Mixture of solvents

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Show less

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2014 Oct 03

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Abraham, Daniel, and Zhu, Ye. Electrolyte compositions for high voltage lithium-ion batteries.  United States: N. p., 2018. 
        Web.

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                    Abraham, Daniel, & Zhu, Ye. Electrolyte compositions for high voltage lithium-ion batteries.  United States.

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                    Abraham, Daniel, and Zhu, Ye. Tue .  
        "Electrolyte compositions for high voltage lithium-ion batteries".  United States.  https://www.osti.gov/servlets/purl/1493337.

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@article{osti_1493337,

  title        = {Electrolyte compositions for high voltage lithium-ion batteries},

  author       = {Abraham, Daniel and Zhu, Ye},

  abstractNote = {The present invention provides an electrolyte composition for a lithium-ion battery comprising LiPF6 in a liquid carrier comprising a carbonate ester and an unsaturated organoboron compound comprising two or three unsaturated hydrocarbon groups, each unsaturated hydrocarbon group being covalently bonded to a boron atom. The unsaturated hydrocarbon groups are independently selected from vinyl, allyl, propargyl, substituted vinyl, substituted allyl, and substituted propargyl. The substituents of the substituted vinyl, allyl and propargyl groups independently comprise one or more of alkyl and phenyl. The alkyl and phenyl groups optionally can bear one or more substituent selected from halogen (e.g., F), hydroxy, amino, alkoxy, and perfluoroalkoxy.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {11}

}

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Works referenced in this record:

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Ion Conductive Characteristics of Alkylborane Type and Boric Ester Type Polymer Electrolytes Derived from Mesitylborane
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Generation of Substituted Styrenes via Suzuki Cross-Coupling of Aryl Halides with 2,4,6-Trivinylcyclotriboroxane
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Similar Records

Title: Electrolyte compositions for high voltage lithium-ion batteries

Abstract

Citation Formats

Synthesis and Lewis acidity of triorganosilyl and triorganostannyl esters of orthoboric, metaboric, and arylboronic acids journal, October 1999

Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes journal, May 2003

Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 1. Spectroscopic Observations of Radical Intermediates Generated in One-Electron Reduction of Carbonates journal, September 2013

Additives for improving cycle life of non-aqueous rechargeable lithium batteries patent, April 1999

Ion Conductive Characteristics of Alkylborane Type and Boric Ester Type Polymer Electrolytes Derived from Mesitylborane journal, April 2003

Electrolytes for lithium sulfur cells patent, April 2008

Boron-based anion receptors in lithium-ion and metal-air batteries journal, February 2014

Solid polymer electrolytes which contain tricoordinate boron for enhanced conductivity and transference numbers journal, January 2013

Crystal structure and physical properties of lithium difluoro(oxalato)borate (LiDFOB or LiBF2Ox) journal, November 2011

Generation of Substituted Styrenes via Suzuki Cross-Coupling of Aryl Halides with 2,4,6-Trivinylcyclotriboroxane journal, July 2002

Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 2. Radiolytically Induced Polymerization of Ethylene Carbonate journal, September 2013

High Voltage Stability of Interfacial Reaction at the LiMn[sub 2]O[sub 4] Thin-Film Electrodes/Liquid Electrolytes with Boroxine Compounds journal, January 2010

Influence of Lewis acidic borate ester groups on lithium ionic conduction in polymer electrolytes journal, December 2002

Li + Transference Number Enhancement in Polymer Electrolytes by Incorporation of Anion Trapping Boroxine Rings into the Polymer Host journal, September 1997

Boroxine chemistry and applications: A perspective journal, January 2010

Fluorinated Boroxin-Based Anion Receptors for Lithium Ion Batteries: Fluoride Anion Binding, Ab Initio Calculations, and Ionic Conductivity Studies journal, May 2009

Positive Electrode Passivation by LiDFOB Electrolyte Additive in High-Capacity Lithium-Ion Cells journal, January 2012

Synthesis and Lewis acidity of triorganosilyl and triorganostannyl esters of orthoboric, metaboric, and arylboronic acids
journal, October 1999

Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes
journal, May 2003

Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 1. Spectroscopic Observations of Radical Intermediates Generated in One-Electron Reduction of Carbonates
journal, September 2013

Additives for improving cycle life of non-aqueous rechargeable lithium batteries
patent, April 1999

Ion Conductive Characteristics of Alkylborane Type and Boric Ester Type Polymer Electrolytes Derived from Mesitylborane
journal, April 2003

Electrolytes for lithium sulfur cells
patent, April 2008

Boron-based anion receptors in lithium-ion and metal-air batteries
journal, February 2014

Solid polymer electrolytes which contain tricoordinate boron for enhanced conductivity and transference numbers
journal, January 2013

Crystal structure and physical properties of lithium difluoro(oxalato)borate (LiDFOB or LiBF2Ox)
journal, November 2011

Generation of Substituted Styrenes via Suzuki Cross-Coupling of Aryl Halides with 2,4,6-Trivinylcyclotriboroxane
journal, July 2002

Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 2. Radiolytically Induced Polymerization of Ethylene Carbonate
journal, September 2013

High Voltage Stability of Interfacial Reaction at the LiMn[sub 2]O[sub 4] Thin-Film Electrodes/Liquid Electrolytes with Boroxine Compounds
journal, January 2010

Influence of Lewis acidic borate ester groups on lithium ionic conduction in polymer electrolytes
journal, December 2002

Li ⁺ Transference Number Enhancement in Polymer Electrolytes by Incorporation of Anion Trapping Boroxine Rings into the Polymer Host
journal, September 1997

Boroxine chemistry and applications: A perspective
journal, January 2010

Fluorinated Boroxin-Based Anion Receptors for Lithium Ion Batteries: Fluoride Anion Binding, Ab Initio Calculations, and Ionic Conductivity Studies
journal, May 2009

Positive Electrode Passivation by LiDFOB Electrolyte Additive in High-Capacity Lithium-Ion Cells
journal, January 2012