Additives for high voltage lithium ion batteries

Peebles, Cameron; Shkrob, Ilya A.; Liao, Chen; Abraham, Daniel; Iddir, Hakim; Garcia, Juan

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Title: Additives for high voltage lithium ion batteries

Abstract

This invention relates to an electrolyte composition for a lithium ion battery comprising a lithium salt in a non-aqueous solvent containing an additive comprising a compound of formula R₃SiOP(O)_nF₂; wherein each R independently is a hydrocarbyl group; and n is 0 or 1; and wherein the additive is substantially free from (R₃SiO)₃P(O)_n and (R₃SiO)₂P(O)_nF. Electrochemical cells and batteries also are described.

Inventors:: Peebles, Cameron; Shkrob, Ilya A.; Liao, Chen; Abraham, Daniel; Iddir, Hakim; Garcia, Juan

Issue Date:: 2023-09-12

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 2222313

Patent Number(s):: 11757131

Application Number:: 17/068,066

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0567 - characterised by the additives
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M10/058 - Construction or manufacture
H01M2220/20 - Batteries in motive systems, e.g. vehicle, ship, plane
H01M2300/0037 - Mixture of solvents

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 10/12/2020

Country of Publication:: United States

Language:: English

Citation Formats


                    Peebles, Cameron, Shkrob, Ilya A., Liao, Chen, Abraham, Daniel, Iddir, Hakim, and Garcia, Juan. Additives for high voltage lithium ion batteries.  United States: N. p., 2023. 
        Web.

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                    Peebles, Cameron, Shkrob, Ilya A., Liao, Chen, Abraham, Daniel, Iddir, Hakim, & Garcia, Juan. Additives for high voltage lithium ion batteries.  United States.

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                    Peebles, Cameron, Shkrob, Ilya A., Liao, Chen, Abraham, Daniel, Iddir, Hakim, and Garcia, Juan. Tue .  
        "Additives for high voltage lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/2222313.

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@article{osti_2222313,

  title        = {Additives for high voltage lithium ion batteries},

  author       = {Peebles, Cameron and Shkrob, Ilya A. and Liao, Chen and Abraham, Daniel and Iddir, Hakim and Garcia, Juan},

  abstractNote = {This invention relates to an electrolyte composition for a lithium ion battery comprising a lithium salt in a non-aqueous solvent containing an additive comprising a compound of formula R3SiOP(O)nF2; wherein each R independently is a hydrocarbyl group; and n is 0 or 1; and wherein the additive is substantially free from (R3SiO)3P(O)n and (R3SiO)2P(O)nF. Electrochemical cells and batteries also are described.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {9}

}

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Works referenced in this record:

Nonaqueous electrolyte solution, and lithium ion secondary battery having the same
patent, April 2016

Kaneko, Shinako; Ishikawa, Hitoshi; Hashizume, Yoko
US Patent Document 9,312,073
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Trimethylsily esters of phosphorus acids. II. Reactions of fluoro- and trifluoromethylphosphorus(V) oxides and sulfides with hexamethyldisiloxane and hexamethyldisilthiane and the synthesis of a novel phosphorane
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Cycling Behavior of NCM523/Graphite Lithium-Ion Cells in the 3–4.4 V Range: Diagnostic Studies of Full Cells and Harvested Electrodes
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Gilbert, James A.; Bareño, Javier; Spila, Timothy
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Lifetime limit of tris(trimethylsilyl) phosphite as electrolyte additive for high voltage lithium ion batteries
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Qi, Xin; Tao, Liang; Hahn, Hendrik
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Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016

Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P.
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Trimethylsilyl esters of phosphorus acids. I. Preparation and properties of esters of difluoro- and bis(trifluoromethyl)phosphinic, -thiophosphinic, and -dithiophosphinic acids
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Cavell, R. G.; Leary, R. D.; Tomlinson, A. J.
Inorganic Chemistry, Vol. 11, Issue 11
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Electrolyte and Lithium-ion Secondary Battery
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Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells
journal, January 2016

Long, Brandon R.; Rinaldo, Steven G.; Gallagher, Kevin G.
Journal of The Electrochemical Society, Vol. 163, Issue 14
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Improving the High Voltage Cycling of Li[Ni _0.42 Mn _0.42 Co _0.16 ]O ₂ (NMC442)/Graphite Pouch Cells Using Electrolyte Additives
journal, January 2014

Ma, Lin; Xia, Jian; Dahn, J. R.
Journal of The Electrochemical Society, Vol. 161, Issue 14
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Materials for battery electrolytes and methods for use
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Bhat, Vinay; Cheng, Gang; Kaye, Steven
US Patent Document 8,308,971
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Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
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Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning
ACS Applied Materials & Interfaces, Vol. 6, Issue 24
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Trimethylsilyl esters of phosphorus acids. III. Esters of difluoro- and bis(trifluoromethyl)phosphinous and thiophosphinous acids
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Cavell, R. G.; Leary, R. D.; Sanger, A. R.
Inorganic Chemistry, Vol. 12, Issue 6
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Synthesis and characterisation of trimethylsilyl phosphorohalidates: Me3SiOP(O)FX (X = Cl, Br) and (Me3SiO)2P2O3F2
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Journal of Fluorine Chemistry, Vol. 125, Issue 1
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US Patent Application 14/423592; 20160028111
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Similar Records

Title: Additives for high voltage lithium ion batteries

Abstract

Citation Formats

Nonaqueous electrolyte solution, and lithium ion secondary battery having the same patent, April 2016

Trimethylsily esters of phosphorus acids. II. Reactions of fluoro- and trifluoromethylphosphorus(V) oxides and sulfides with hexamethyldisiloxane and hexamethyldisilthiane and the synthesis of a novel phosphorane journal, November 1972

Cycling Behavior of NCM523/Graphite Lithium-Ion Cells in the 3–4.4 V Range: Diagnostic Studies of Full Cells and Harvested Electrodes journal, September 2016

Lifetime limit of tris(trimethylsilyl) phosphite as electrolyte additive for high voltage lithium ion batteries journal, January 2016

Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells journal, December 2016

Trimethylsilyl esters of phosphorus acids. I. Preparation and properties of esters of difluoro- and bis(trifluoromethyl)phosphinic, -thiophosphinic, and -dithiophosphinic acids journal, November 1972

Electrolyte and Lithium-ion Secondary Battery patent-application, August 2016

Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells journal, January 2016

Improving the High Voltage Cycling of Li[Ni 0.42 Mn 0.42 Co 0.16 ]O 2 (NMC442)/Graphite Pouch Cells Using Electrolyte Additives journal, January 2014

Materials for battery electrolytes and methods for use patent, November 2012

Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy journal, December 2014

Trimethylsilyl esters of phosphorus acids. III. Esters of difluoro- and bis(trifluoromethyl)phosphinous and thiophosphinous acids journal, June 1973

Synthesis and characterisation of trimethylsilyl phosphorohalidates: Me3SiOP(O)FX (X = Cl, Br) and (Me3SiO)2P2O3F2 journal, January 2004

A multifunctional phosphite-containing electrolyte for 5 V-class LiNi 0.5 Mn 1.5 O 4 cathodes with superior electrochemical performance journal, January 2014

Gel Polymer Electrolyte and Electrochemical Device Including the Same patent-application, January 2016

Nonaqueous electrolyte solution, and lithium ion secondary battery having the same
patent, April 2016

Trimethylsily esters of phosphorus acids. II. Reactions of fluoro- and trifluoromethylphosphorus(V) oxides and sulfides with hexamethyldisiloxane and hexamethyldisilthiane and the synthesis of a novel phosphorane
journal, November 1972

Cycling Behavior of NCM523/Graphite Lithium-Ion Cells in the 3–4.4 V Range: Diagnostic Studies of Full Cells and Harvested Electrodes
journal, September 2016

Lifetime limit of tris(trimethylsilyl) phosphite as electrolyte additive for high voltage lithium ion batteries
journal, January 2016

Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016

Trimethylsilyl esters of phosphorus acids. I. Preparation and properties of esters of difluoro- and bis(trifluoromethyl)phosphinic, -thiophosphinic, and -dithiophosphinic acids
journal, November 1972

Electrolyte and Lithium-ion Secondary Battery
patent-application, August 2016

Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells
journal, January 2016

Improving the High Voltage Cycling of Li[Ni _0.42 Mn _0.42 Co _0.16 ]O ₂ (NMC442)/Graphite Pouch Cells Using Electrolyte Additives
journal, January 2014

Materials for battery electrolytes and methods for use
patent, November 2012

Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
journal, December 2014

Trimethylsilyl esters of phosphorus acids. III. Esters of difluoro- and bis(trifluoromethyl)phosphinous and thiophosphinous acids
journal, June 1973

Synthesis and characterisation of trimethylsilyl phosphorohalidates: Me3SiOP(O)FX (X = Cl, Br) and (Me3SiO)2P2O3F2
journal, January 2004

A multifunctional phosphite-containing electrolyte for 5 V-class LiNi _0.5 Mn _1.5 O ₄ cathodes with superior electrochemical performance
journal, January 2014

Gel Polymer Electrolyte and Electrochemical Device Including the Same
patent-application, January 2016