Polyfluorinated carbonate electrolyte for high-voltage lithium batteries

Zhang, Zhengcheng; Tornheim, Adam P.; He, Meinan; Croy, Jason R.

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Title: Polyfluorinated carbonate electrolyte for high-voltage lithium batteries

Abstract

A non-aqueous solvent composition for a lithium battery comprises a fluorinated solvent mixture that consists essentially of a 1,2-difluoroethylene carbonate and a fluoro-substituted dialkyl carbonate in a respective weight ratio of about 1:3 to about 1:1, and optionally up to about 30 wt % of an additional organic solvent. An electrolyte for a lithium ion battery comprises a lithium salt dissolved in a non-aqueous solvent composition comprising the fluorinated solvent mixture.

Inventors:: Zhang, Zhengcheng; Tornheim, Adam P.; He, Meinan; Croy, Jason R.

Issue Date:: 2021-09-21

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1840478

Patent Number(s):: 11127979

Application Number:: 15/923,687

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M2004/027 - {Negative electrodes}
H01M2004/028 - {Positive electrodes}
H01M2300/0034 - Fluorinated solvents
H01M2300/0037 - Mixture of solvents
H01M2300/004 - Three solvents
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 03/16/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Zhang, Zhengcheng, Tornheim, Adam P., He, Meinan, and Croy, Jason R. Polyfluorinated carbonate electrolyte for high-voltage lithium batteries.  United States: N. p., 2021. 
        Web.

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                    Zhang, Zhengcheng, Tornheim, Adam P., He, Meinan, & Croy, Jason R. Polyfluorinated carbonate electrolyte for high-voltage lithium batteries.  United States.

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                    Zhang, Zhengcheng, Tornheim, Adam P., He, Meinan, and Croy, Jason R. Tue .  
        "Polyfluorinated carbonate electrolyte for high-voltage lithium batteries".  United States.  https://www.osti.gov/servlets/purl/1840478.

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@article{osti_1840478,

  title        = {Polyfluorinated carbonate electrolyte for high-voltage lithium batteries},

  author       = {Zhang, Zhengcheng and Tornheim, Adam P. and He, Meinan and Croy, Jason R.},

  abstractNote = {A non-aqueous solvent composition for a lithium battery comprises a fluorinated solvent mixture that consists essentially of a 1,2-difluoroethylene carbonate and a fluoro-substituted dialkyl carbonate in a respective weight ratio of about 1:3 to about 1:1, and optionally up to about 30 wt % of an additional organic solvent. An electrolyte for a lithium ion battery comprises a lithium salt dissolved in a non-aqueous solvent composition comprising the fluorinated solvent mixture.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2021},

  month        = {9}

}

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Works referenced in this record:

Development of direct fluorination technology for application to materials for lithium battery
journal, April 2003

Kobayashi, Masafumi; Inoguchi, Tetsuya; Iida, Takashi
Journal of Fluorine Chemistry, Vol. 120, Issue 2
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Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells
journal, January 2016

Long, Brandon R.; Rinaldo, Steven G.; Gallagher, Kevin G.
Journal of The Electrochemical Society, Vol. 163, Issue 14
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Advances in Stabilizing ‘Layered-Layered’ xLi₂MnO₃·(1-x)LiMO₂(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014

Long, Brandon R.; Croy, Jason R.; Park, Joong Sun
Journal of The Electrochemical Society, Vol. 161, Issue 14, p. A2160-A2167
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Electrolyte for lithium ion rechargeable battery and lithium rechargeable battery including the same
patent, November 2010

Kim, Jinsung; Kim, Yongshik; Kim, Jinbum
US Patent Document 7,842,417
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Solvent including 1,2-dialkyl-1,2-difluoroethylene carbonate for non-aqueous electrolytic solution of lithium secondary battery
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Koh, Meiten; Sakata, Hideo; Nakazawa, Hitomi
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Composition of a Fluorinated Organic Carbonate and a Lewis Acid
patent-application, July 2012

Olschimke, Jens; Bomkamp, Martin; Grossmann, Andreas
US Patent Application 13/497333; 20120177987
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Nonaqueous Electrolyte Solution and Method for Producing Nonaqueous Electrolyte Secondary Battery
patent-application, August 2018

Kawai, Toshiyuki; Asano, Hiroto; Yamazaki, Shigeaki
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Battery having an electrolytic solution containing difluoroethylene carbonate
patent, February 2013

Wakita, Shinya; Okae, Izaya; Yamaguchi, Hiroyuki
US Patent Document 8,377,598
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Lithium Air Battery Cell
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Some Fluorinated Carbonates as Electrolyte Additives for Li(Ni _0.4 Mn _0.4 Co _0.2 )O ₂ /Graphite Pouch Cells
journal, January 2016

Xia, Jian; Petibon, Remi; Xiao, A.
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Similar Records

Title: Polyfluorinated carbonate electrolyte for high-voltage lithium batteries

Abstract

Citation Formats

Development of direct fluorination technology for application to materials for lithium battery journal, April 2003

Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells journal, January 2016

Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component journal, January 2014

Electrolyte for lithium ion rechargeable battery and lithium rechargeable battery including the same patent, November 2010

Solvent including 1,2-dialkyl-1,2-difluoroethylene carbonate for non-aqueous electrolytic solution of lithium secondary battery patent, January 2016

Composition of a Fluorinated Organic Carbonate and a Lewis Acid patent-application, July 2012

Nonaqueous Electrolyte Solution and Method for Producing Nonaqueous Electrolyte Secondary Battery patent-application, August 2018

Battery having an electrolytic solution containing difluoroethylene carbonate patent, February 2013

Lithium Air Battery Cell patent-application, February 2014

Nonaqueous Electrolytes and Advances in Additives book, January 2014

Electrolytic Solution for Non-aqueous Secondary Battery, and Non-Aqueous Electrolytic Solution Secondary Battery patent-application, August 2015

Some Fluorinated Carbonates as Electrolyte Additives for Li(Ni 0.4 Mn 0.4 Co 0.2 )O 2 /Graphite Pouch Cells journal, January 2016

Development of direct fluorination technology for application to materials for lithium battery
journal, April 2003

Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells
journal, January 2016

Advances in Stabilizing ‘Layered-Layered’ xLi₂MnO₃·(1-x)LiMO₂(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014

Electrolyte for lithium ion rechargeable battery and lithium rechargeable battery including the same
patent, November 2010

Solvent including 1,2-dialkyl-1,2-difluoroethylene carbonate for non-aqueous electrolytic solution of lithium secondary battery
patent, January 2016

Composition of a Fluorinated Organic Carbonate and a Lewis Acid
patent-application, July 2012

Nonaqueous Electrolyte Solution and Method for Producing Nonaqueous Electrolyte Secondary Battery
patent-application, August 2018

Battery having an electrolytic solution containing difluoroethylene carbonate
patent, February 2013

Lithium Air Battery Cell
patent-application, February 2014

Nonaqueous Electrolytes and Advances in Additives
book, January 2014

Electrolytic Solution for Non-aqueous Secondary Battery, and Non-Aqueous Electrolytic Solution Secondary Battery
patent-application, August 2015

Some Fluorinated Carbonates as Electrolyte Additives for Li(Ni _0.4 Mn _0.4 Co _0.2 )O ₂ /Graphite Pouch Cells
journal, January 2016