skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Method to synthesize lanthanide fluoride materials from lanthanide fluorinated alkoxides

Abstract

Lanthanide fluorinated alkoxide derivatives can be synthesized from the alcoholysis reaction of the lanthanide bis-trimethylsilyl amide and an excess amount of hexafluoro iso-propanol. Nanoparticles can be formed from the lanthanide fluorinated alkoxide derivatives by a solvothermal or solution precipitation process.

Inventors:
Issue Date:
Research Org.:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1455058
Patent Number(s):
9,981,893
Application Number:
15/010,899
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Jan 29
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Boyle, Timothy J. Method to synthesize lanthanide fluoride materials from lanthanide fluorinated alkoxides. United States: N. p., 2018. Web.
Boyle, Timothy J. Method to synthesize lanthanide fluoride materials from lanthanide fluorinated alkoxides. United States.
Boyle, Timothy J. Tue . "Method to synthesize lanthanide fluoride materials from lanthanide fluorinated alkoxides". United States. https://www.osti.gov/servlets/purl/1455058.
@article{osti_1455058,
title = {Method to synthesize lanthanide fluoride materials from lanthanide fluorinated alkoxides},
author = {Boyle, Timothy J.},
abstractNote = {Lanthanide fluorinated alkoxide derivatives can be synthesized from the alcoholysis reaction of the lanthanide bis-trimethylsilyl amide and an excess amount of hexafluoro iso-propanol. Nanoparticles can be formed from the lanthanide fluorinated alkoxide derivatives by a solvothermal or solution precipitation process.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {5}
}

Patent:

Save / Share:

Works referenced in this record:

Synthesizing Biofunctionalized Nanoparticles to Image Cell Signaling Pathways
journal, December 2006

  • Hernandez-Sanchez, Bernadette A.; Boyle, Timothy J.; Lambert, Timothy N.
  • IEEE Transactions on NanoBioscience, Vol. 5, Issue 4, p. 222-230
  • DOI: 10.1109/TNB.2006.886565

Advances in Structurally Characterized Lanthanide Alkoxide, Aryloxide, and Silyloxide Compounds
journal, June 2008

  • Boyle, Timothy J.; Ottley, Leigh Anna M.
  • Chemical Reviews, Vol. 108, Issue 6, p. 1896-1917
  • DOI: 10.1021/cr0401063

Nonstoichiometric fluorides—Solid electrolytes for electrochemical devices: A review
journal, September 2007


Fluoride electrode with LaF3-membrane and simple disjoining solid-state internal contact
journal, September 2001