Method embodiments for making lanthanide metal complexes from lanthanide metal oxides and separating the same from heavy lanthanide metal oxides, actinide oxides, and non-lanthanide rare earth element oxides
Abstract
The present disclosure is directed to method embodiments for making anhydrous lanthanide halide complexes. At least some embodiments comprise making a lanthanide halide complex by reacting a lanthanide metal oxide with an oxygen scavenger and catalyst in the presence of a donor solvent. The method is selective toward light lanthanide metal oxides and thus further provides a method for separating light lanthanide metal oxides from heavy lanthanide metal oxides, actinide oxides, and non-lanthanide rare earth element oxides.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1998396
- Patent Number(s):
- 11654424
- Application Number:
- 16/898,253
- Assignee:
- Triad National Security, LLC (Los Alamos, NM)
- DOE Contract Number:
- 89233218CNA000001
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 06/10/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Kiplinger, Jaqueline Loetsch, Silks, Louis A., and Beattie, Ross James. Method embodiments for making lanthanide metal complexes from lanthanide metal oxides and separating the same from heavy lanthanide metal oxides, actinide oxides, and non-lanthanide rare earth element oxides. United States: N. p., 2023.
Web.
Kiplinger, Jaqueline Loetsch, Silks, Louis A., & Beattie, Ross James. Method embodiments for making lanthanide metal complexes from lanthanide metal oxides and separating the same from heavy lanthanide metal oxides, actinide oxides, and non-lanthanide rare earth element oxides. United States.
Kiplinger, Jaqueline Loetsch, Silks, Louis A., and Beattie, Ross James. Tue .
"Method embodiments for making lanthanide metal complexes from lanthanide metal oxides and separating the same from heavy lanthanide metal oxides, actinide oxides, and non-lanthanide rare earth element oxides". United States. https://www.osti.gov/servlets/purl/1998396.
@article{osti_1998396,
title = {Method embodiments for making lanthanide metal complexes from lanthanide metal oxides and separating the same from heavy lanthanide metal oxides, actinide oxides, and non-lanthanide rare earth element oxides},
author = {Kiplinger, Jaqueline Loetsch and Silks, Louis A. and Beattie, Ross James},
abstractNote = {The present disclosure is directed to method embodiments for making anhydrous lanthanide halide complexes. At least some embodiments comprise making a lanthanide halide complex by reacting a lanthanide metal oxide with an oxygen scavenger and catalyst in the presence of a donor solvent. The method is selective toward light lanthanide metal oxides and thus further provides a method for separating light lanthanide metal oxides from heavy lanthanide metal oxides, actinide oxides, and non-lanthanide rare earth element oxides.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 23 00:00:00 EDT 2023},
month = {Tue May 23 00:00:00 EDT 2023}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Synthese und Kristallstruktur von bis‐1, 3‐Dimethoxyethan‐trichloro‐samarium(III) und tris‐N, N‐Diisopropylcarbamato‐samarium(III)
journal, January 2003
- Baisch, Ulrich; Schnick, Wolfgang
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 629, Issue 12-13
Synthesis of anhydrous lanthanidechloride complexes from oxides and the crystal structure of[GdCl3(thf )2(tmeda)]
journal, December 1998
- Petriček, S.; Demšar, A.; Golič, L.
- Polyhedron, Vol. 18, Issue 3-4
Syntheses of lanthanide bromide complexes from oxides and the crystal structures of [LnBr3(DME)2] (Ln=Pr, Nd, Sm, Eu), [LnBr3(THF)4] (Ln=Pr, Sm) and [EuBr2(THF)5][EuBr4(THF)2]
journal, September 2004
- Petriček, S.
- Polyhedron, Vol. 23, Issue 14
Permanent magnet materials based on the rare earth-iron-boron tetragonal compounds
journal, September 1984
- Sagawa, M.; Fujimura, S.; Yamamoto, H.
- IEEE Transactions on Magnetics, Vol. 20, Issue 5
Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands
journal, October 2008
- Mishra, Shashank
- Coordination Chemistry Reviews, Vol. 252, Issue 18-20
Solvation coordination compounds of scandium chloride from the dehydration of scandium chloride hexahydrate
journal, November 2021
- Boyle, Timothy J.; Cramer, Roger E.; Fasulo, Francesca A.
- Polyhedron, Vol. 208
The mononuclear and dinuclear dimethoxyethane adducts of lanthanide trichlorides [LnCl3(DME)2]n, n=1 or 2, fundamental starting materials in lanthanide chemistry: preparation and structures
journal, March 2004
- Baisch, Ulrich; Dell`Amico, Daniela Belli; Calderazzo, Fausto
- Inorganica Chimica Acta, Vol. 357, Issue 5
Lanthanide complex formulations
patent, March 2020
- Thaning, Mikkel; Meijer, Andreas Richard
- US Patent Document 10,576,169
Lanthanide(III)chloride-tetrahydrofuran solvates: structural patterns within the series LnCl3(THF)n, where n = 2,3,3.5 and 4: crystal and molecular structures of [PrCl(μ-Cl)2(THF)2]n, [Nd(μ-Cl)3(H2O)(THF)]n and GdCl3(THF)4
journal, January 1997
- Willey, Gerald R.; Woodman, Timothy J.; Drew, Michael G. B.
- Polyhedron, Vol. 16, Issue 19
Synthese und Kristallstrukturen der Seltenerd-Komplexe [LaI2(THF)5]+I3?, [SmCl3(THF)4], [ErCl2(THF)5]+ [ErCl4(THF)2]?, [ErCl3(DME)2] und [Na(18-Krone-6)(THF)2]+ [YbBr4(THF)2]?
journal, September 1997
- Anfang, S.; Karl, M.; Faza, N.
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 623, Issue 9