Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof
Abstract
A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.
- Inventors:
-
- Orinda, CA
- Corning, NY
- Issue Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- OSTI Identifier:
- 873443
- Patent Number(s):
- 6160158
- Application Number:
- 09/026473
- Assignee:
- Regents of University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
- DOE Contract Number:
- AC03-76SF00098
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- fluorination; utilizing; thermodynamically; unstable; fluorides; fluoride; salts; method; fluorinating; carbon; compound; cationic; utilizes; agent; selected; nickel; liquid; anhydrous; hydrogen; desired; organic; undergo; reacted; contacting; chosen; reaction; vessel; time; period; temperature; thermodynamically unstable; organic compound; time period; reaction vessel; fluoride salt; agent selected; carbon compound; reaction time; hydrogen fluoride; nickel fluoride; nickel fluorides; anhydrous hydrogen; /999/
Citation Formats
Bartlett, Neil, Whalen, J Marc, and Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof. United States: N. p., 2000.
Web.
Bartlett, Neil, Whalen, J Marc, & Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof. United States.
Bartlett, Neil, Whalen, J Marc, and Chacon, Lisa. Sat .
"Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof". United States. https://www.osti.gov/servlets/purl/873443.
@article{osti_873443,
title = {Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof},
author = {Bartlett, Neil and Whalen, J Marc and Chacon, Lisa},
abstractNote = {A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2000},
month = {1}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Silver trifluoride: preparation, crystal structure, some properties, and comparison with AuF3
journal, May 1991
- Zemva, Boris; Lutar, Karel; Jesih, Adolf
- Journal of the American Chemical Society, Vol. 113, Issue 11
Some chemistry of high oxidation state transition metal fluorides in anhydrous HF
journal, June 1995
- Lucier, G.; Shen, C.; Casteel, W. J.
- Journal of Fluorine Chemistry, Vol. 72, Issue 2
New fluorination of organic compounds using thermodynamically unstable nickel fluorides
journal, January 1996
- Bartlett, Neil; Chambers, Richard D.; Roche, Alex J.
- Chem. Commun., Issue 9
Thermodynamically Unstable Fluorides of Nickel: NiF4 and NiF3 Syntheses and Some Properties
journal, October 1995
- Zemva, B.; Lutar, K.; Chacon, L.
- Journal of the American Chemical Society, Vol. 117, Issue 40
The room temperature conversion of nickel difluoride to hexafluoronickelate(IV) salts of alkali cations
journal, March 1998
- Whalen, J. M.; Lucier, G. M.; Chacón, L.
- Journal of Fluorine Chemistry, Vol. 88, Issue 2