Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

Bartlett, Neil; Whalen, J Marc; Chacon, Lisa

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Title: Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

Abstract

A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.

Inventors:

Bartlett, Neil ^[1]; Whalen, J Marc ^[2]; Chacon, Lisa ^[2]

Orinda, CA
Corning, NY

Issue Date:: 2000-01-01

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

OSTI Identifier:: 873443

Patent Number(s):: 6160158

Application Number:: 09/026473

Assignee:: Regents of University of California (Oakland, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
C07B39/00 - Halogenation

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C17/04 - to unsaturated halogenated hydrocarbons
C07C17/10 - of hydrogen atoms
C07C253/30 - by reactions not involving the formation of cyano groups
C07C255/10 - containing cyano groups and halogen atoms, or nitro or nitroso groups, bound to the same acyclic carbon skeleton

Show less

DOE Contract Number:: AC03-76SF00098

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: fluorination; utilizing; thermodynamically; unstable; fluorides; fluoride; salts; method; fluorinating; carbon; compound; cationic; utilizes; agent; selected; nickel; liquid; anhydrous; hydrogen; desired; organic; undergo; reacted; contacting; chosen; reaction; vessel; time; period; temperature; thermodynamically unstable; organic compound; time period; reaction vessel; fluoride salt; agent selected; carbon compound; reaction time; hydrogen fluoride; nickel fluoride; nickel fluorides; anhydrous hydrogen; /999/

Citation Formats


                    Bartlett, Neil, Whalen, J Marc, and Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof.  United States: N. p., 2000. 
        Web.

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                    Bartlett, Neil, Whalen, J Marc, & Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof.  United States.

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                    Bartlett, Neil, Whalen, J Marc, and Chacon, Lisa. Sat .  
        "Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof".  United States.  https://www.osti.gov/servlets/purl/873443.

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@article{osti_873443,

  title        = {Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof},

  author       = {Bartlett, Neil and Whalen, J Marc and Chacon, Lisa},

  abstractNote = {A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2000},

  month        = {1}

}

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Works referenced in this record:

Silver trifluoride: preparation, crystal structure, some properties, and comparison with AuF3
journal, May 1991

Zemva, Boris; Lutar, Karel; Jesih, Adolf
Journal of the American Chemical Society, Vol. 113, Issue 11
https://doi.org/10.1021/ja00011a021

Some chemistry of high oxidation state transition metal fluorides in anhydrous HF
journal, June 1995

Lucier, G.; Shen, C.; Casteel, W. J.
Journal of Fluorine Chemistry, Vol. 72, Issue 2
https://doi.org/10.1016/0022-1139(94)00401-Z

New fluorination of organic compounds using thermodynamically unstable nickel fluorides
journal, January 1996

Bartlett, Neil; Chambers, Richard D.; Roche, Alex J.
Chem. Commun., Issue 9
https://doi.org/10.1039/CC9960001049

Thermodynamically Unstable Fluorides of Nickel: NiF4 and NiF3 Syntheses and Some Properties
journal, October 1995

Zemva, B.; Lutar, K.; Chacon, L.
Journal of the American Chemical Society, Vol. 117, Issue 40
https://doi.org/10.1021/ja00145a013

The room temperature conversion of nickel difluoride to hexafluoronickelate(IV) salts of alkali cations
journal, March 1998

Whalen, J. M.; Lucier, G. M.; Chacón, L.
Journal of Fluorine Chemistry, Vol. 88, Issue 2
https://doi.org/10.1016/S0022-1139(98)00105-5

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Similar Records

Title: Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

Abstract

Citation Formats

Silver trifluoride: preparation, crystal structure, some properties, and comparison with AuF3 journal, May 1991

Some chemistry of high oxidation state transition metal fluorides in anhydrous HF journal, June 1995

New fluorination of organic compounds using thermodynamically unstable nickel fluorides journal, January 1996

Thermodynamically Unstable Fluorides of Nickel: NiF4 and NiF3 Syntheses and Some Properties journal, October 1995

The room temperature conversion of nickel difluoride to hexafluoronickelate(IV) salts of alkali cations journal, March 1998

Silver trifluoride: preparation, crystal structure, some properties, and comparison with AuF3
journal, May 1991

Some chemistry of high oxidation state transition metal fluorides in anhydrous HF
journal, June 1995

New fluorination of organic compounds using thermodynamically unstable nickel fluorides
journal, January 1996

Thermodynamically Unstable Fluorides of Nickel: NiF4 and NiF3 Syntheses and Some Properties
journal, October 1995

The room temperature conversion of nickel difluoride to hexafluoronickelate(IV) salts of alkali cations
journal, March 1998