Small domain-size multiblock copolymer electrolytes
Abstract
New block polymer electrolytes have been developed which have higher conductivities than previously reported for other block copolymer electrolytes. The new materials are constructed of multiple blocks (>5) of relatively low domain size. The small domain size provides greater protection against formation of dendrites during cycling against lithium in an electrochemical cell, while the large total molecular weight insures poor long range alignment, which leads to higher conductivity. In addition to higher conductivity, these materials can be more easily synthesized because of reduced requirements on the purity level of the reagents.
- Inventors:
- Issue Date:
- Research Org.:
- Seeo, Inc., Hayward, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1325535
- Patent Number(s):
- 9450272
- Application Number:
- 13/862,442
- Assignee:
- Seeo, Inc. (Hayward, CA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- OE0000223
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Apr 14
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Pistorino, Jonathan, and Eitouni, Hany Basam. Small domain-size multiblock copolymer electrolytes. United States: N. p., 2016.
Web.
Pistorino, Jonathan, & Eitouni, Hany Basam. Small domain-size multiblock copolymer electrolytes. United States.
Pistorino, Jonathan, and Eitouni, Hany Basam. Tue .
"Small domain-size multiblock copolymer electrolytes". United States. https://www.osti.gov/servlets/purl/1325535.
@article{osti_1325535,
title = {Small domain-size multiblock copolymer electrolytes},
author = {Pistorino, Jonathan and Eitouni, Hany Basam},
abstractNote = {New block polymer electrolytes have been developed which have higher conductivities than previously reported for other block copolymer electrolytes. The new materials are constructed of multiple blocks (>5) of relatively low domain size. The small domain size provides greater protection against formation of dendrites during cycling against lithium in an electrochemical cell, while the large total molecular weight insures poor long range alignment, which leads to higher conductivity. In addition to higher conductivity, these materials can be more easily synthesized because of reduced requirements on the purity level of the reagents.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 20 00:00:00 EDT 2016},
month = {Tue Sep 20 00:00:00 EDT 2016}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Self-doped microphase separated block copolymer electrolyte
patent, March 2002
- Mayes, Anne M.; Sadoway, Donald R.; Banerjee, Pallab
- US Patent Document 6,361,901
Mechanically resilient polymeric films doped with a lithium compound
patent, February 2005
- Meador, Mary Ann B.; Kinder, James D.
- US Patent Document 6,855,433
Polyelectrolyte membrane and production method therefor
patent-application, October 2005
- Kinouchi, Masayuki; Hirano, Tetsuji; Hisano, Nobuharu
- US Patent Application 10/518026; 20050221193
Solid Electrolyte Material Manufacturable by Polymer Processing Methods
patent-application, March 2009
- Singh, Mohit; Gur, Ilan; Eitouni, Hany Basam
- US Patent Application 12/271829; 20090075176
High Elastic Modulus Polymer Electrolytes
patent-application, October 2009
- Balsara, Nitash Pervez; Singh, Mohi; Eitouni, Hany Basam
- US Patent Application 12/225934; 20090263725
Performance limitations of polymer electrolytes based on ethylene oxide polymers
journal, August 2000
- Buriez, Olivier; Han, Yong Bong; Hou, Jun
- Journal of Power Sources, Vol. 89, Issue 2, p. 149-155
Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes
journal, June 2007
- Singh, Mohit; Odusanya, Omolola; Wilmes, Gregg M.
- Macromolecules, Vol. 40, Issue 13
Morphology of PI–PEO block copolymers for lithium batteries
journal, August 2006
- Xue, Chenchen; Meador, Mary Ann B.; Zhu, Lei
- Polymer, Vol. 47, Issue 17, p. 6149-6155
Effect of Branching on Rod−Coil Block Polyimides as Membrane Materials for Lithium Polymer Batteries
journal, July 2003
- Meador, Mary Ann B.; Cubon, Valerie A.; Scheiman, Daniel A.
- Chemistry of Materials, Vol. 15, Issue 15