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Title: Process for forming silicon carbide films and microcomponents

Patent ·
OSTI ID:872105

Silicon carbide films and microcomponents are grown on silicon substrates at surface temperatures between 900 K and 1700 K via C.sub.60 precursors in a hydrogen-free environment. Selective crystalline silicon carbide growth can be achieved on patterned silicon-silicon oxide samples. Patterned SiC films are produced by making use of the high reaction probability of C.sub.60 with silicon at surface temperatures greater than 900 K and the negligible reaction probability for C.sub.60 on silicon dioxide at surface temperatures less than 1250 K.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
DOE Contract Number:
W-7405-ENG-48
Assignee:
Regents of University of California (Oakland, CA)
Patent Number(s):
US 5861346
OSTI ID:
872105
Country of Publication:
United States
Language:
English

References (12)

Fullerene (C60) adsorption on Si surfaces journal April 1993
Growth of silicon carbide films via C60 precursors journal October 1994
Fabrication of SiC Films on Si(100) using a C60 molecular source journal June 1994
C58 production from dissociation of C60 by scattering from silica and highly oriented pyrolytic graphite journal September 1994
Synthesis of epitaxial β‐SiC by C 60 carbonization of silicon journal August 1995
Surface mobility of C 60 on SiO 2 journal September 1993
Sapphire (112¯0) surface: Structure and laser-induced desorption of aluminum journal March 1992
The chemisorption of C60 on Si(100)-(2 × 1) journal January 1993
Observation of C 60 cage opening on Si(111)‐(7×7) journal July 1993
Double domain solid C 60 on Si(111)7×7 journal March 1993
SiC microcomponents via reaction of C60 with silicon journal November 1994
Temperature effects of adsorption of C 60 molecules on Si(111)-(7×7) surfaces journal March 1994