Structural characterization of [({eta}{sup 2}-C{sub 60})RhH(CO)(PPh{sub 3}){sub 2}]: Product of the reaction of C{sub 60} with the hydrogenation catalyst [RhH(CO)(PPh{sub 3}){sub 3}]
- Univ. of California, Davis, CA (United States)
Reaction of [RhH(CO)(PPh{sub 3}){sub 3}] with C{sub 60} results in the formation of a green ({eta}{sup 2}-C{sub 60})RhH(CO)(PPh{sub 3}){sub 2}* which has been characterized by X-ray crystallography. Unlike ({eta}{sup 2}-C{sub 60})IrCl(CO)(PPh{sub 3}){sub 2}* which readily dissociates in solution, [({eta}{sup 2}-C{sub 60})RhH(CO)(PPh{sub 3}){sub 2}] is stable in solution and is subject to spectroscopic study. The hydride ligand remains attached to rhodium and does not transfer to the fullerene.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 75695
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 17 Vol. 32; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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