Study of equilibria in solutions of buckminsterfullerene exohedral derivative, ({eta}{sup 2}-C{sub 60})Pd(PPh{sub 3}){sub 2}, using electrochemical methods and electronic spectroscopy
Journal Article
·
· Russian Chemical Bulletin
- M.V. Lomonosov Moscow State Univ. (Russian Federation); and others
Polarization curves of electrochemical oxidation and reduction, as well as electronic absorption spectra of the palladium complex of fullerene, C{sub 60}Pd(PPh{sub 3}){sub 2}, and its mixtures with Pd(PPh{sub 3}){sub 4} have been studied in toluene-acetonitrile (9:1) solutions. The experimental data can be explained by the assumption that equilibrium takes place between the initial complex, polymetallated compounds, C{sub 60}[Pd(PPh{sub 3}){sub 2}]{sub n} (n = 1-4), and free fullerene, C{sub 60}.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 171715
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 12 Vol. 43; ISSN RCBUEY; ISSN 1066-5285
- Country of Publication:
- United States
- Language:
- English
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