Synthesis and characterization of bis(fulvalene)dimolybdenum and its monocarbonyl

Journal Article · Wed May 11 00:00:00 EDT 1977 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00452a063· OSTI ID:7308826

Smart, J C; Curtis, C J

The synthesis of bis(fulvalene)dimolybdenum (1) and its monocarbonyl adduct, bis(fulvalene)dimolybdenum monocarbonyl (2) is reported. The synthesis of 1 utilized an in situ preparation of the bicyclopentadienide or fulvalene dianion, followed by reaction with molybdenum(II) acetate to yield the dinuclear complex as a slightly soluble, dark red, air-sensitive solid.

• Research Organization: Univ. of California, Berkeley
• OSTI ID: 7308826
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 99:10; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKENES
CARBONYLS
CHEMICAL PROPERTIES
CYCLOALKENES
HYDROCARBONS
MOLYBDENUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHYSICAL PROPERTIES
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS