ESR determination of the rate constant for the addition of CpW(CO)/sub 3/ to spin traps

Journal Article · Mon May 20 04:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:7251718

Gasonov, R G; Friedlina, R K

Rate constants are presented for the addition of CpW(CO)/sub 3/ radicals in (I) to 2,4,6-tri-tertbutyl-nitrosobenzene (BNB) and a-phenyl-N-tert-butylnitrone (PBN). The reaction of (CpW(CO)/sub 3/)/sub 2/ with PhCH/sub 2/C1 and the decomposition of CpW(CO)/sub 3/Me were studied by EST spectroscopy using BNB and PNB as spin traps.

• Research Organization: A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow
• OSTI ID: 7251718
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 33:11, PT. 2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
BENZENE
CARBONYLS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COUPLING CONSTANTS
DECOMPOSITION
ELECTRON SPIN RESONANCE
HYDROCARBONS
KINETICS
MAGNETIC RESONANCE
NITROSO COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RESONANCE
TRANSITION ELEMENT COMPOUNDS
TRAPS
TUNGSTEN COMPOUNDS