Investigation of the radical products of alkane radiolysis by spin trapping

Journal Article · Fri Dec 01 04:00:00 EST 1978 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:5737973

Belevskii, V N; Isakova, O V; Bugaenko, L I

The formation of radicals in ..gamma..-irradiated C/sub 5/-C/sub 9/ alkanes, cyclohexane, and isooctane were studied by means of spin traps. The following spin traps were used: 2,4,6-tri-tert-butylnitrosobenzene (BNB), nitrosodurene (ND), C-phenyl-N-tert-butylnitrone (phi BN), and tert-nitrosobutane (TNB). The syntheses of the spin traps BNB, ND, phi BN, and TNB, were conducted by known methods. The solutions of the spin traps in the alkanes were kept under a vacuum of 5 x 10/sup -5/ torr and were irradiated at 5/sup 0/C or -40/sup 0/C. The radical adducts of these compounds were identified by EPR spectra. 3 figures.

• Research Organization: Moscow State Univ., USSR
• OSTI ID: 5737973
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Phys. Chem. (Engl. Transl.); (United States) Vol. 243:4-6; ISSN DKPCA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ADDUCTS
ALKANES
AROMATICS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CYCLOALKANES
CYCLOHEXANE
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ELECTRON SPIN RESONANCE
GAMMA RADIATION
HIGH VACUUM
HYDROCARBONS
IONIZING RADIATIONS
LOW TEMPERATURE
MAGNETIC RESONANCE
NITROSO COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PRESSURE DEPENDENCE
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADICALS
RADIOLYSIS
RESONANCE
TRAPPING
YIELDS