Reactions of anhydrides of phosphonothioic acids with triethyl phosphite

Journal Article · Wed May 01 00:00:00 EDT 1985 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7202695

Andreev, N A; Grishina, O N

This paper investigates the properties of anhydrides of phosphorus acids by studying the reaction of the anhydride of cyclohexylphosphonothioic acid with triethyl phosphite by means of P 31 NMR spectroscopy. The reaction takes a complex course; reaction scarcely went at all in 1 hour at 120 C in chlorobenzene. The physical constants and IR and P 31 NMR spectra of the acid esters prepared in different ways proved to be identical. They are liquids, soluble in most organic solvents. The P 31 NMR spectra of O-ethyl hydrogen cyclohexyl-phosphonate and -phosphonothioate gives signals at 31 and 96 ppm respectively.

• Research Organization: A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan
• OSTI ID: 7202695
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 54:12,PT.1; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ANHYDRIDES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
ESTERS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
ISOTOPES
KINETICS
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
OXIDATION
PHOSPHONIC ACID ESTERS
PHOSPHOROUS ACID
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
REACTION KINETICS
REDUCTION
SOLUBILITY
SOLVENT PROPERTIES
SPECTRA
STABLE ISOTOPES