Synthesis of vinyl phosphites

Journal Article · Sat Sep 20 04:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5324740

Kabachnik, M M; Novikova, Z S; Neganova, E G; Lutsenko, I F

The authors investigated the reactions of phosphoriodidites and phosphinous iodides with a number of aldehydes and ketones in presence of tertiary amines (triethylamine, pyridine, N,N-diethylaniline), and they have shown that as a result of the reactions the corresponding vinyl esters of phosphorus acids are formed. The reactions of phosphoriodidites (and phosphorodiamidous iodides) with aliphatic aldehydes (acetaldehyde, propionaldehyde, butyraldehyde, and isobutyraldehyde) go at a molar reactant ratio of 1:1 in either at room temperature and are practically complete in 5-6 h. The yields of the alkenyl phosphites (phosphorodiamidites) were 45-70%. The compositions and structures of the compounds obtained were confirmed by elemental analysis and the IR and /sup 1/H and /sup 31/P NMR spectra.

• Research Organization: Moscow State Univ. (USSR)
• OSTI ID: 5324740
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:4; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALDEHYDES
AMINES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
DOUBLE RESONANCE METHODS
ESTERIFICATION
ESTERS
HALOGEN COMPOUNDS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
INFRARED SPECTRA
INORGANIC ACIDS
INTERMEDIATE COUPLING
IODINE COMPOUNDS
ISOTOPES
J-J COUPLING
KETONES
LIGHT NUCLEI
MONOMERS
MULTIPLETS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORIC ACID ESTERS
PHOSPHOROUS ACID
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
VINYL MONOMERS