Phosphorylation of methylene quinones. IV. Reaction of fuchsone and naphthofuchsone with di- and trialkyl phosphites

Journal Article · Wed Aug 20 04:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5925884

Kopel'tsiv, Yu A; Kolesnikov, V T; Shermolovich, Yu G; Trotsenko, S I; Klep, V Z

The reaction of fuchsone and naphthofuchsone with dialkyl esters of phosphorus acid was found to follow the 1,6-addition scheme with the formation of dialkyl esters of 4-hydroxytriphenylmethylphosphonic and 4-hydroxynaphthyldiphenylmethylphosphonic acids, respectively. The structure of the reaction products was determined to depend on the nature of the alkyl substituents of the phosphites used. ESR, IR and phosphorus 31 NMR spectra are analyzed and chemical shifts and spin-spin coupling constants are determined.

• Research Organization: Lenin Komsomol L'vov Polytechnic Institute, USSR
• OSTI ID: 5925884
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:3; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AROMATICS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
ELECTRON SPIN RESONANCE
ESTERIFICATION
ESTERS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
INTERMEDIATE COUPLING
ISOTOPES
J-J COUPLING
KINETICS
LIGHT NUCLEI
MAGNETIC RESONANCE
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHONIC ACID ESTERS
PHOSPHOROUS ACID
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
QUINONES
REACTION KINETICS
RESONANCE
SPECTRA
STABLE ISOTOPES
YIELDS