Reactions of 2-chloro-1-alkanimines with trialkyl phosphites and with triphenylphosphine

Journal Article · Sat Sep 20 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5324733

Sinitsa, A D; Krishtal', V S; Momot, V V; Maidanovich, N K; Kal'chenko, V I

The reactivity of 2-chloro-1-alkanimines toward trialkyl phosphites and triphenylphosphine is determined by the electronic properties of the substituents in the azomethine group. Donor substituents direct the reaction toward the formation of C-phosphorylation products. The introduction of electron-acceptor substituents on the nitrogen and carbon atoms of the azomethine group raises its reactivity considerably toward nucleophilic phosphorus(III) compounds and leads to products with a nitrogen-phosphorus bond. Phosphorus 31 NMR and chlorine 35 NQR spectra are analyzed.

• Research Organization: Institute of Organic Chemistry, Kiev (USSR)
• OSTI ID: 5324733
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:4; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTIVATION ENERGY
AZO COMPOUNDS
BINDING ENERGY
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE 35
CHLORINE ISOTOPES
COUPLING
COUPLING CONSTANTS
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
IMINES
INTERMEDIATE COUPLING
ISOTOPES
J-J COUPLING
KINETICS
LIGHT NUCLEI
MULTIPLETS
NMR SPECTRA
NUCLEAR QUADRUPOLE RESONANCE
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
REACTION KINETICS
RESONANCE
SPECTRA
STABLE ISOTOPES
SYNTHESIS