Telemerization of alkane- and arenesulfonamides with butadiene catalyzed by palladium complexes

Journal Article · Tue Aug 20 00:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00951283· OSTI ID:7059721

Dzhemilev, U M; Khalilov, L M; Kunakova, R V; Panasenko, A A; Sirazova, M M

The authors continue research on the telomerization of 1,3-dienes with compounds that contain labile H atoms by investigating the reaction of butadiene with alkane- and arenesulfonamides under the influence of a catalyst of the Pd-Ln type, which is widely used in processes involving the telomerization of conjugated 1,3-dienes. The expected telomerization products, viz., N-substituted unsaturated sulfonamides, could be of interest for the synthesis of new effective antimicrobial preparations and complexing agents. The catalyzed (by palladium complexes) telomerization of butadiene was realized with butane- and p-toluenesulfonamides, which leads to difficult-to-obtain N-substituted unsaturated sulfoamides in high yields.

• Research Organization: Institute of Chemistry, Bashkir Branch, Acad. of Sci., Ufa
• OSTI ID: 7059721
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Vol. 34:2,PT.2
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BUTADIENE
TELOMERIZATION
PALLADIUM COMPLEXES
CATALYTIC EFFECTS
SULFONAMIDES
CHEMICAL REACTION YIELD
CATALYSTS
ELECTRON SPIN RESONANCE
NMR SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
AMIDES
ANTI-INFECTIVE AGENTS
ANTIMICROBIAL AGENTS
CHEMICAL REACTIONS
COMPLEXES
DIENES
DRUGS
HYDROCARBONS
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
POLYENES
POLYMERIZATION
RESONANCE
SPECTRA
TRANSITION ELEMENT COMPLEXES
YIELDS
400201* - Chemical & Physicochemical Properties