Telemerization of alkane- and arenesulfonamides with butadiene catalyzed by palladium complexes
The authors continue research on the telomerization of 1,3-dienes with compounds that contain labile H atoms by investigating the reaction of butadiene with alkane- and arenesulfonamides under the influence of a catalyst of the Pd-Ln type, which is widely used in processes involving the telomerization of conjugated 1,3-dienes. The expected telomerization products, viz., N-substituted unsaturated sulfonamides, could be of interest for the synthesis of new effective antimicrobial preparations and complexing agents. The catalyzed (by palladium complexes) telomerization of butadiene was realized with butane- and p-toluenesulfonamides, which leads to difficult-to-obtain N-substituted unsaturated sulfoamides in high yields.
- Research Organization:
- Institute of Chemistry, Bashkir Branch, Acad. of Sci., Ufa
- OSTI ID:
- 7059721
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:2,PT.2; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
AMIDES
ANTI-INFECTIVE AGENTS
ANTIMICROBIAL AGENTS
BUTADIENE
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COMPLEXES
DIENES
DRUGS
ELECTRON SPIN RESONANCE
HYDROCARBONS
MAGNETIC RESONANCE
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PALLADIUM COMPLEXES
POLYENES
POLYMERIZATION
RESONANCE
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SULFONAMIDES
TELOMERIZATION
TRANSITION ELEMENT COMPLEXES
YIELDS