Synthesis of higher N-alkenylsulfamides using complex palladium catalysts

Journal Article · Fri Jun 20 00:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:6226154

Dzhemilev, U M; Kunakova, R V; Sirazova, M M

The authors have studied the telomerization of alkane- and arenesulfamides with linear and cyclic 1,3-dienes in the presence of a palladium catalyst system, Pd(acac)/sub 2/-PPh/sub 3/-AlEt/sub 3/; high-molecular-weight N-substituted unsaturated sulfamides, difficult to prepare by other means, are obtained. Introduction of bulky substituents to the N atom of alkanesulfamides drastically reduces their reactivity toward 1,3-dienes.

• Research Organization: Institute of Chemistry, Ufa, USSR
• OSTI ID: 6226154
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:12; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
ALKENES
AMIDES
CARBON 13
CARBON ISOTOPES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
DIENES
ELECTRON SPIN RESONANCE
EVEN-ODD NUCLEI
HYDROCARBONS
INFRARED SPECTRA
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
MASS SPECTRA
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PALLADIUM COMPLEXES
POLYENES
POLYMERIZATION
RESONANCE
SEPARATION PROCESSES
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TELOMERIZATION
TRANSITION ELEMENT COMPLEXES
ULTRAVIOLET SPECTRA
YIELDS