Hydroxylation of lower alkanes, catalyzed by tetra(o-nitro-phenyl) porphyrin of trivalent iron

Journal Article · Sun Jan 31 23:00:00 EST 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:7044583

Belova, V S; Khenkin, A M; Shilov, A E

We have previously shown that the highest percent oxidation of hexane at the terminal methyl group by iodosobenzene (which was used in model studies as the oxygen atoms donor) was achieved by catalysis with a sterically hindered catalyst, 5,10,15,20-tetra(o-nitrophenyl)porphyrin iron chloride (TNPPFeCl). In the present paper we report our results of a study of the oxidation of methane, ethane, propane, hexane, and cyclohexane by iodosobenzene and TNPPFeCl catalysis in benzene.

• Research Organization: Institute of Chemical Physics Branch, Chernogolovka (USSR)
• OSTI ID: 7044583
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:4; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKANES
AROMATICS
BENZENE
CARBOXYLIC ACIDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKANES
CYCLOHEXANE
CYCLOHEXANOL
ENERGY
ETHANE
ETHANOL
HALOGENATED AROMATIC HYDROCARBONS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HEXANE
HEXANOLS
HOMOGENEOUS CATALYSIS
HYDROCARBONS
HYDROXY COMPOUNDS
HYDROXYLATION
IODINATED AROMATIC HYDROCARBONS
IRON COMPLEXES
KINETICS
MATERIALS TESTING
METHANE
METHANOL
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDATION
PORPHYRINS
PRODUCTION
PROPANE
PROPANOLS
REACTION KINETICS
TESTING
TRANSITION ELEMENT COMPLEXES