Hydroxylation of lower alkanes, catalyzed by tetra(o-nitro-phenyl) porphyrin of trivalent iron

Journal Article · Mon Feb 01 00:00:00 EST 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:7044583

Belova, V S; Khenkin, A M; Shilov, A E

We have previously shown that the highest percent oxidation of hexane at the terminal methyl group by iodosobenzene (which was used in model studies as the oxygen atoms donor) was achieved by catalysis with a sterically hindered catalyst, 5,10,15,20-tetra(o-nitrophenyl)porphyrin iron chloride (TNPPFeCl). In the present paper we report our results of a study of the oxidation of methane, ethane, propane, hexane, and cyclohexane by iodosobenzene and TNPPFeCl catalysis in benzene.

• Research Organization: Institute of Chemical Physics Branch, Chernogolovka (USSR)
• OSTI ID: 7044583
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 28:4; Other Information: Translated from Kinet. Katal; 28: No. 4, 1016-1017(Jul-Aug 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALCOHOLS
PRODUCTION
ALKANES
HOMOGENEOUS CATALYSIS
HYDROXYLATION
OXIDATION
IRON COMPLEXES
CATALYTIC EFFECTS
PORPHYRINS
ACTIVATION ENERGY
BENZENE
CATALYSTS
CHEMICAL REACTION KINETICS
CYCLOHEXANE
CYCLOHEXANOL
ETHANE
ETHANOL
HEXANE
HEXANOLS
IODINATED AROMATIC HYDROCARBONS
MATERIALS TESTING
METHANE
METHANOL
PROPANE
PROPANOLS
AROMATICS
CARBOXYLIC ACIDS
CATALYSIS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKANES
ENERGY
HALOGENATED AROMATIC HYDROCARBONS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
KINETICS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
TESTING
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties