Hydroxylation of alkanes using sodium hypochlorite catalyzed by iron porphyrins

Journal Article · Sat Oct 01 00:00:00 EDT 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6084693

Sorokin, A B; Khenkin, A M

This communication presents data about the oxidation of alkanes to alcohols with hypochlorite in the presence of Fe(III) phenylporphyrin derivatives in the system water-benzene. We used as catalysts the following compounds: tetraphenylporphyrin iron chloride, tetramesitylporphyrin iron chloride, tetra(2-fluorophenyl)porphyrin from chloride, and tetra (2-ntrophenyl)porphyrin iron chloride. The reaction products were analyzed by gas-liquid chromatography. The efficiency of the reaction was determined by the structure of the porphyrin used.

• OSTI ID: 6084693
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 29:2; Other Information: Translated from Kinet. Katal.; 29: No. 2, 508(Mar-Apr 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKANES
HYDROXYLATION
IRON COMPLEXES
CATALYTIC EFFECTS
PORPHYRINS
ABSORPTION SPECTRA
ALCOHOLS
AQUEOUS SOLUTIONS
BENZENE
CHLORINE COMPOUNDS
CHROMATOGRAPHY
CYCLOHEXANE
EFFICIENCY
HEXANE
OXIDATION
SODIUM COMPOUNDS
ALKALI METAL COMPOUNDS
AROMATICS
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKANES
DISPERSIONS
HALOGEN COMPOUNDS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
MIXTURES
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SEPARATION PROCESSES
SOLUTIONS
SPECTRA
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties