Structure of ((eta-C/sub 5/H/sub 5/)Fe(CO)/sub 2/(CS))PF/sub 6/, a comparison of M-CS and M-CO bonding
Journal Article
·
· Inorg. Chem.; (United States)
The complex ((eta-C/sub 5/H/sub 5/)Fe(CO)/sub 2/(CS))PF/sub 6/ was prepared, crystallized, and its structure determined by x-ray crystallographic analysis. The atomic coordinates, isotropic thermal parameters and selected bond distances and angles are tabulated. The structure of the complex was shown to be composed of discrete cationic ((C/sub 5/H/sub 5/Fe(CO)/sub 2/(CS)/sup +/) and anionic (PF/sub 6//sup -/) species, and the coordination of the iron was found to be octahedral. 23 references, 1 figure, 4 tables.
- Research Organization:
- Iowa State Univ., Ames
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 7043601
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 26:3; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Synthesis and structure of the new binuclear complex eta/sup 5/-C/sub 5/H/sub 5/(CO)/sub 2/Fe-eta/sup 1/-C/sub 5/H/sub 4/(CO)/sub 2/Fe-CH/sub 3/
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Journal Article
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Wed May 21 00:00:00 EDT 1986
· Inorg. Chem.; (United States)
·
OSTI ID:5582659
Synthesis and structure of the new binuclear complex eta/sup 5/-C/sub 5/H/sub 5/(CO)/sub 2/Fe-eta/sup 1/-C/sub 5/H/sub 4/(CO)/sub 2/Fe-CH/sub 3/
Journal Article
·
Wed Aug 20 00:00:00 EDT 1986
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
·
OSTI ID:6416836
Synthesis and crystal structure of a novel mixed valence iron compound, ((/eta//sup 5/-cyclopentadienyl)(/eta//sup 6/-tetralin)Fe(II))/sub 3/(Fe(III)(NCS)/sub 6/)
Journal Article
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Mon Aug 01 00:00:00 EDT 1988
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OSTI ID:6048504
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
BOND ANGLE
BOND LENGTHS
CARBON COMPOUNDS
CARBON SULFIDES
CARBONYLS
CHALCOGENIDES
CHEMICAL PREPARATION
COMPLEXES
CYCLOALKENES
CYCLOPENTADIENE
DATA
DIENES
DIMENSIONS
EXPERIMENTAL DATA
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
IRON COMPLEXES
LENGTH
MOLECULAR STRUCTURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHORUS COMPOUNDS
PHOSPHORUS FLUORIDES
POLYENES
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
ALKENES
BOND ANGLE
BOND LENGTHS
CARBON COMPOUNDS
CARBON SULFIDES
CARBONYLS
CHALCOGENIDES
CHEMICAL PREPARATION
COMPLEXES
CYCLOALKENES
CYCLOPENTADIENE
DATA
DIENES
DIMENSIONS
EXPERIMENTAL DATA
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
IRON COMPLEXES
LENGTH
MOLECULAR STRUCTURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHORUS COMPOUNDS
PHOSPHORUS FLUORIDES
POLYENES
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES