Photochemical studies of ((eta/sup 5/-C/sub 5/R/sub 5/)M(eta/sup 6/-COT))PF/sub 6/ and ((eta/sup 5/-C/sub 5/R/sub 5/)M(eta/sup 4/-1,5-COT)L)PF/sub 6/ complexes of iron and ruthenium
Journal Article
·
· Inorg. Chem.; (United States)
The photochemistry of a series of complexes of the form ((eta/sup 5/-C/sub 5/R/sub 5/)M(eta/sup 6/-COT))PF/sub 6/ and ((eta/sup 5/-C/sub 5/H/sub 5/)M(eta/sup 4/-COT)L)PF/sub 6/ (R = H, CH/sub 3/; M = Fe, Ru; COT = cyclooctatetraene; L = CO, P(OCH/sub 3/)/sub 3/) is examined to determined the potential for stepwise COT release through coordinatively unsaturated eta/sup 2/ and eta /sup 4/ intermediates. The cyclooctatetraene complexes were chosen because of the documented ability of COT to coordinate in both eta/sup 6/ and eta/sup 4/ configurations.
- Research Organization:
- Univ. of Minnesota, Minneapolis
- OSTI ID:
- 5582659
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:11; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Wed Apr 08 00:00:00 EDT 1987
· Inorg. Chem.; (United States)
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OSTI ID:6542221
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Thu Dec 31 23:00:00 EST 1992
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·
OSTI ID:6567417
Structure of ((eta-C/sub 5/H/sub 5/)Fe(CO)/sub 2/(CS))PF/sub 6/, a comparison of M-CS and M-CO bonding
Journal Article
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Tue Feb 10 23:00:00 EST 1987
· Inorg. Chem.; (United States)
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OSTI ID:7043601
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
EXPERIMENTAL DATA
INFORMATION
IRON COMPLEXES
MAGNETIC RESONANCE
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
REACTION INTERMEDIATES
RESONANCE
RUTHENIUM COMPLEXES
SPECTRA
TRANSITION ELEMENT COMPLEXES
400500* -- Photochemistry
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
EXPERIMENTAL DATA
INFORMATION
IRON COMPLEXES
MAGNETIC RESONANCE
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
REACTION INTERMEDIATES
RESONANCE
RUTHENIUM COMPLEXES
SPECTRA
TRANSITION ELEMENT COMPLEXES