Synthesis and crystal structure of a novel mixed valence iron compound, ((/eta//sup 5/-cyclopentadienyl)(/eta//sup 6/-tetralin)Fe(II))/sub 3/(Fe(III)(NCS)/sub 6/)
Journal Article
·
OSTI ID:6048504
The title compound was encountered in the course of preparing ((/eta//sup 5/-C/sub 5/H/sub 5/)(/eta//sup 6/-C/sub 10/H/sub 12/)Fe)SCN from ((/eta//sup 5/-C/sub 5/H/sub 5/)(/eta//sup 6/-C/sub 10/H/sub 12/)Fe)PF/sub 6/. The mixed valence iron compound crystallizes in the monoclinic space group P2/sub 1//c with four formula unite per unit cell. There are three crystallographically independent cations and two anions (each residing on a center of inversion) in the asymmetric unit. Lattice constants are a = 17.231(7), b = 18.167(6), c = 16.572(7) /angstrom/, and /beta/ = 97.86(4)/degree/. 23 references, 1 figure, 4 tables.
- Research Organization:
- Univ. of Alabama, University (USA)
- OSTI ID:
- 6048504
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
COMPLEXES
CRYSTAL STRUCTURE
DATA
DIENES
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
IRON COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
POLYENES
TETRALIN
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
AROMATICS
COMPLEXES
CRYSTAL STRUCTURE
DATA
DIENES
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
IRON COMPLEXES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
POLYENES
TETRALIN
TRANSITION ELEMENT COMPLEXES