Features of the hydrochlorination of vinylsilanes with several vinyl groups on the silicon atom
In the search for preparative methods for the synthesis of some potentially valuable organosilicon monomers, namely, chlorovinylsilanes with several vinyl groups on the silicon atom, the authors present a detailed study of the reaction of hydrogen chloride with vinylsilanes containing more than one vinyl group in the molecule and some of their derivatives. The reaction conditions and products of hydrogen chloride with various vinylsilanes are presented in a table. A comparison of the reactivities of various chloromethylvinylsilanes in the presence of trimethylvinylsilane by the method of competing reactions showed that the replacement of methyl groups by vinyl on silicon in the vinylsilane molecule raises the yields of the corresponding chlorosilanes only slightly, but the introduction of a chlorine atom on silicon in the place of methyl or vinyl leads to a shrp fall in the yield of the chlorosilane.
- Research Organization:
- State Research Institute of Chemistry and Tech. of Organometallic Compounds, Moscow
- OSTI ID:
- 7005710
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:6,PT.2; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINATION
COMPLEXES
ENERGY
HALOGENATION
HYDRIDES
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INORGANIC ACIDS
KINETICS
MONOMERS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS
SILANES
SILICON COMPLEXES
SILICON COMPOUNDS
SYNTHESIS
VINYL MONOMERS
YIELDS