Synthesis of organic silthianes containing functional groups at the silicon atom introduced by trans-silylation

Journal Article · Thu Jan 09 23:00:00 EST 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6811451

Mizhiritskii, M D

This paper studies the synthetic scope of silthiane compounds containing alkyl and phenyl substituents in order to prepare organic linear and cyclic silthianes with functional groups at the silicon atom. These include hydride, vinyl, ethynyl, aryl, chloromethyl, and alkoxl groups. As a result of the vigorous conditions for this reaction, organic silthianes with hydride and vinyl groups are obtained in low yield or are not obtained at all by this method. These products may be prepared by the reaction of the corresponding chlorosilanes with sodium hydrosulfide.

• Research Organization: Lensovet Leningrad Technological Institute
• OSTI ID: 6811451
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:7, PT. 2; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
AMINES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
ENERGY
HYDRIDES
HYDROGEN COMPOUNDS
INFRARED SPECTRA
KINETICS
METHYLATION
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
ORGANIC SULFUR COMPOUNDS
POLYMERIZATION
REACTION KINETICS
SILANES
SILICON COMPOUNDS
SILOXANES
SPECTRA
SYNTHESIS
YIELDS